HYDROUS PYROLYSIS IN THE SIMULATION OF COAL WASTE SELF-HEATING

Author(s):  
M.J. Fabiańska ◽  
D. Więcław ◽  
M. Misz-Kennan ◽  
E.A. Szram ◽  
J. Ciesielczuk ◽  
...  
2021 ◽  
Author(s):  
D. Więcław ◽  
K. Jurek ◽  
A. Kowalski ◽  
E. Bilkiewicz ◽  
M.J. Fabiańska ◽  
...  

2019 ◽  
Author(s):  
M.J. Fabiańska ◽  
M. Misz-Kennan ◽  
J. Ciesielczuk ◽  
E. Szram ◽  
A. Nadudvari

Geochemistry ◽  
2016 ◽  
Vol 76 (2) ◽  
pp. 211-226 ◽  
Author(s):  
Monika J. Fabiańska ◽  
Justyna Ciesielczuk ◽  
Magdalena Misz-Kennan ◽  
Łukasz Kruszewski ◽  
Adam Kowalski

Author(s):  
Ádám Nádudvari ◽  
Anna Abramowicz ◽  
Monika Fabiańska ◽  
Magdalena Misz-Kennan ◽  
Justyna Ciesielczuk

Abstract A self-heating intensity index (SHII) based on the highest (pixel max.) and lowest (pixel min.) values taken from satellite thermal maps of burning coal waste dumps are proposed. The index enables the classification of such fires in Ukrainian- and Polish coal waste dumps. Both in Ukraine and in Poland, varying thermal intensities during 1985–2019 are revealed, using the SHII and following thermal intensity threshold values, namely, extreme thermal activity (> 7), advanced (3–7), moderate (3–1.5), initial (1.5–1), no activity (< 1). The SHII shows decreasing thermal activity in the selected Ukrainian coal waste dumps during 2017–2019. It aids in reconstructing the thermal history of the dumps. Analysis of satellite images revealed a large number of burning coal waste dumps in the Donetsk Coal Basin (Ukraine) with high thermal activity. Such burning likely reflects large amounts of organic matter and sulphides in the dumped material subjected to self-heating and self-burning processes, lack of compaction of the coal waste and/or high methane contents. Comparison of SHII values calculated from satellite- and drone thermal-camera images were compared to show that SHII from drone thermal images have much higher values than those from satellite images; the former have better resolution. Thus, SHII from Landsat- and drone images should be used separately in dump heating studies.


Mineralogia ◽  
2015 ◽  
Vol 46 (1-2) ◽  
pp. 29-40 ◽  
Author(s):  
Ádám Nádudvari ◽  
Monika J. Fabiańska ◽  
Magdalena Misz-Kennan

AbstractSeveral types of coal waste (freshly-dumped waste, self-heated waste and waste eroded by rain water), river sediments and river water were sampled. The aim was to identify the types of phenols present on the dumps together with their relative abundances. Gas chromatography-mass spectrometry (GC-MS) analyses of a large number of samples (234) statistically underpin the phenol distributions in the sample sets. The largest average relative contents (1.17-13.3%) of phenols occur in the self-heated samples. In these, relatively high amounts of phenol, C1- and C2-phenols reflect the thermal destruction of vitrinite. In fresh coal waste, C2- and C3-phenols that originated from the bacterial/fungal degradation and oxidation of vitrinite particles are the most common (0.6 rel.%). Water-washed coal waste and water samples contain lower quantities of phenols. In the river sediments, the phenols present are the result of bacterial- or fungal decay of coaly organic matter or are of industrial origin.


Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 586
Author(s):  
Łukasz Kruszewski ◽  
Justyna Ciesielczuk

Little is known of the influence of fluxes on the nature and the intensity of burning in coal-waste heaps. To gain some insight, two siderite samples, one each from coal-mining waste heaps in Upper- and Lower Silesian Coal Basins (Poland), were heated under identical conditions in a thermal chamber coupled to a powder X-ray diffractometer. Differences in the behaviour of siderite phase and the products of its decomposition, mainly magnetite, wüstite, and olivine, are discussed. The waste heaps sampled underwent self-heating and self-ignition catalysed by fluxes. Though the samples are unlikely to be truly representative of the Silesian basins, the heterogeneous behaviour they displayed on heating merits description and explanation, as siderite is an important widely known flux in pyrometamorphic processes.


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