In Situ Synthesis of TiC-TiB2 Composites via High Energy Ball Milling and Pressureless Sintering

2013 ◽  
Vol 401-403 ◽  
pp. 635-638
Author(s):  
Ping Luo ◽  
Shi Jie Dong ◽  
Zhi Xiong Xie ◽  
Wei Yang ◽  
An Zhuo Yangli
Keyword(s):  
Ball Milling ◽  
Milled Powder ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Sintering Process ◽  
Composite Ceramics ◽  
X Ray Diffraction ◽  
Powder Mixtures ◽  
Energy Ball

TiC-TiB2 composite ceramics were successfully fabricated via planetary ball milling of 72 mass% Ti and 28 mass % B4C powders, followed by low temperature sintering process at 1200°C. The microstructure of the ball-milled powder mixtures and composite ceramics were characterized by Differential thermal analysis equipment (DTA), field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD). The results showed that the ball-milled powder mixtures (Ti and B4C powders) were completely transformed to TiC-TiB2 composite ceramics as the powders were milled for 60 h and sintered at 1200°C for 1 h. The formation mechanism of the TiC-TiB2 composite was discussed. The high energy ball milling and necessary sintering for the powder mixtures plays an important role in the formation of the composites.

Structural and Microstructural Properties of Si-C and Si-C-B Powders Obtained by High-Energy Ball Milling

2016 ◽  
Vol 869 ◽  
pp. 19-24
Author(s):  
Lucas Moreira Ferreira ◽  
D.S. Mégda ◽  
A.C. de Souza ◽  
Rodrigo Fernando Costa Marques ◽  
Erika Coaglia Trindade Ramos ◽  
...  
Keyword(s):  
Ball Milling ◽  
Structural Modification ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Fracture Mechanisms ◽  
Microstructural Properties ◽  
X Ray Diffraction ◽  
Powder Mixtures ◽  
X Ray ◽  
Energy Ball

This work evaluated on the structural modification during high-energy ball milling of the Si-50C, Si-42.9C-19.1B e Si-33.3C-44.4B (at.-%) powder mixtures from elemental powders. Electron images revealed on occurrence of continuous fracture mechanisms in brittle particles during their processing, which presented rounded particles lower than 10 μm. X-ray diffraction results of Si-50C powders indicated that the intensity of Si peaks was slightly reduced after milling for 17 h, which were moved to the direction of larger diffraction angles after 7 h of milling, suggesting that carbon atoms were dissolved into the Si lattice in order to form an extended solid solution. Following, these values were increased due to the discrete exothermic formation of the SiC compound. In Si-C-B powder mixtures, the SiC and B4C compounds were formed after milling for 7 h.

MECHANOCHEMICAL SYNTHESIS OF TIAL3/AL2O3 ULTRAFINE GRAINED COMPOSITE

2008 ◽  
Vol 22 (18n19) ◽  
pp. 2914-2923 ◽  
Author(s):  
M. M. VERDIAN ◽  
S. HESHMATI-MANESH
Keyword(s):  
Ball Milling ◽  
Titanium Oxide ◽  
Milled Powder ◽  
Xrd Analysis ◽  
High Energy ◽  
Reduction Reaction ◽  
High Energy Ball Milling ◽  
X Ray Diffraction ◽  
Ultrafine Grained ◽  
Energy Ball

The TiAl 3/ Al 2 O 3 metal-ceramic composite was synthesized using high energy ball milling, powder compaction and thermal treatment. Micron sized powders of titanium oxide ( TiO 2) and aluminum were subjected to high energy ball milling under an argon protected atmosphere. Milling of this powder mixture although reduced crystallites sizes to a nano scale, did not result in a reaction between the reactants. Further compaction of the milled powder and annealing, paved the way to a reduction reaction and led to the formation of an ultrafine grained composite structure. The reaction appeared to proceed through two-steps. Titanium oxide was first reduced to TiO and later on, TiO was reduced to Ti . The resulting Ti was alloyed with extra Al to produce TiAl 3 intermetallic in which alumina particles were dispersed. Also, mechanical activation was found to reduce the reaction temperature between Al and TiO 2. The morphology and phase composition of the milling products were evaluated by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis.

X-ray diffraction study of microstructural evolution of some ZrO2–Y2O3–MgO powder mixtures induced by high-energy ball milling

2004 ◽  
Vol 379 (1-2) ◽  
pp. 216-221 ◽  
Author(s):  
Nada Stubičar ◽  
Vladimir Bermanec ◽  
Mirko Stubičar ◽  
Darko Popović ◽  
Wolfgang A. Kaysser
Keyword(s):  
Diffraction Study ◽  
Ball Milling ◽  
Microstructural Evolution ◽  
High Energy ◽  
High Energy Ball Milling ◽  
X Ray Diffraction ◽  
Powder Mixtures ◽  
X Ray ◽  
Energy Ball

Effects of High-Energy Ball Milling Time on the Sintering Process of FeSe Superconductors

2016 ◽  
Vol 848 ◽  
pp. 657-663 ◽  
Author(s):  
Sheng Nan Zhang ◽  
Xiao Bo Ma ◽  
Ji Xing Liu ◽  
Jian Qing Feng ◽  
Cheng Shan Li ◽  
...  
Keyword(s):  
Phase Composition ◽  
Ball Milling ◽  
Optimal Parameter ◽  
High Energy ◽  
Superconducting Phase ◽  
High Energy Ball Milling ◽  
Superconducting Transition ◽  
Sintering Process ◽  
Energy Ball ◽  
Precursor Powders

FeSe superconducting bulks were prepared with high energy ball milling (HEBM) aided sintering process, within which process, tetragonal β-FeSe superconducting phase could be formed directly with one step sintering process, and the formation of hexagonal δ-FeSe non-superconducting phase was effectively avoided. The influences of HEBM time on the sintering process of FeSe bulks were systematically investigated. With different HEBM time, the phase composition and morphology of precursor powders changed correspondingly, which thus influenced the final phase composition and superconducting properties of FeSe superconducting bulks. Due to the formation of FeSe bulks with larger tetragonal phase content and higher superconducting transition temperature, HEBM time of 6.0 h was recognized as the optimal parameter. Shorter HEBM time could lead to the insufficient decrease of particle size and low density. While longer HEBM time caused the formation of amorphous hexagonal δ-FeSe, which crystallized during sintering process. Thus no more tetragonal FeSe could be obtained. The FeSe superconducting bulk with the critical temperature Tc(onset) of 8.0 K was obtained with the HEBM time of 6 h, and sintering temperature of 700 oC for 12 h.

An Investigation on the Mechanical Alloying of TiFe Compound by High-Energy Ball Milling

2010 ◽  
Vol 660-661 ◽  
pp. 329-334 ◽  
Author(s):  
Railson Bolsoni Falcão ◽  
Edgar Djalma Campos Carneiro Dammann ◽  
Cláudio José da Rocha ◽  
Ricardo Mendes Leal Neto
Keyword(s):  
Ball Milling ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Powder Mixtures ◽  
Milling Parameters ◽  
Process Route ◽  
Partial Formation ◽  
Energy Ball

This work reports the efforts to obtain TiFe intermetallic compound by high-energy ball milling of Ti and Fe powder mixtures. This process route has been used to provide a better hydrogen intake in this compound. Milling was carried out in a SPEX mill at different times. Strong adherence of material at the vial walls was seen to be the main problem at milling times higher than 1 hour. Attempts to solve this problem were accomplished by adding different process control agents, like ethanol, stearic acid, low density polyethylene, benzene and cyclohexane at variable quantities and keeping constant other milling parameters like ball to powder ration and balls size. Better results were attained with benzene and cyclohexane, but with partial formation of TiFe compound even after a heat treatment (annealing) of the milled samples.

The effect of high-energy ball milling on the electromechanical strain properties of Bi-based lead-free relaxor matrix ferroelectric composite ceramics

2017 ◽  
Vol 43 (10) ◽  
pp. 7516-7521 ◽  
Author(s):  
Hyoung-Su Han ◽  
Dae-Jun Heo ◽  
Thi Hinh Dinh ◽  
Chang-Heon Lee ◽  
Jin-Kyu Kang ◽  
...  
Keyword(s):  
Ball Milling ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Lead Free ◽  
Composite Ceramics ◽  
Energy Ball

Structure and Thermal Stability of Nanostructured Iron-doped Zirconia Prepared by High-energy Ball Milling

1999 ◽  
Vol 14 (4) ◽  
pp. 1343-1352 ◽  
Author(s):  
J. Z. Jiang ◽  
F. W. Poulsen ◽  
S. Mørup
Keyword(s):  
Ball Milling ◽  
Unit Cell Volume ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Iron Ions ◽  
Monoclinic Zirconia ◽  
Maximum Solubility ◽  
Powder Mixtures ◽  
Energy Ball ◽  
Thermal Stability Of

Fully stabilized cubic zirconia doped with iron oxide has been synthesized by high-energy ball milling from powder mixtures of monoclinic zirconia and hematite. It is found that the iron ions dissolved in cubic ZrO2 are in substitutional positions with a maximum solubility of approximately 18.5 mol% α–Fe2O3. The unit-cell volume of the cubic ZrO2 phase decreases with increasing iron content. During heating the cubic-to-tetragonal transition occurs at approximately 827 °C and the tetragonal-to-monoclinic transition seems to be absent at temperatures below 950 °C. During cooling the tetragonal-to-monoclinic transition occurs at 900–1100 °C.

Mössbauer, X-ray diffraction and magnetization studies of Fe–Mn–Al–Nb alloys prepared by high energy ball milling

2006 ◽  
Vol 168 (1-3) ◽  
pp. 1057-1063 ◽  
Author(s):  
Ligia E. Zamora ◽  
G. A. Perez Alcazar ◽  
J. M. Greneche ◽  
S. Suriñach
Keyword(s):  
Ball Milling ◽  
High Energy ◽  
High Energy Ball Milling ◽  
X Ray Diffraction ◽  
X Ray ◽  
Energy Ball
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