Study on the Advanced Treatment of Dyeing Wastewater by Photocatalytic-H2O2

2014 ◽  
Vol 1048 ◽  
pp. 503-506
Author(s):  
Hui Xia Lan ◽  
Ping Ma ◽  
Jian Zhang ◽  
Hui Jie Li ◽  
Heng Zhang ◽  
...  

The composition of dyeing wastewater is complicated, after biochemical treatment, the effluent COD is still unable to meet the emission standard. To achieve discharge standard that often require advanced treatment after biochemical. This paper investigated effect of pH, reaction time, ZnO dosage, dosage of H2O2on the effect of dyeing wastewater treatment by photocatalytic-H2O2, the results showed that the reaction time of 15 min, pH of 4, dosage of ZnO was 4 g/L, 30% H2O2dosage was 1 ml/L, the COD removal rate was highest, can reach more than 55%.

2019 ◽  
Vol 38 (3) ◽  
pp. 243
Author(s):  
Happy Mulyani ◽  
Gregorius Prima Indra Budianto ◽  
Margono Margono ◽  
Mujtahid Kaavessina

Industrial wastewater treatment using Sequencing Batch Reactor (SBR) can improve effluent quality at lower cost than that obtained by other biological treatment methods. Further optimization is still required to enhance effluent quality until it meets standard quality and to reduce the operating cost of treatment of high strength organic wastewater. The purpose of this research was to determine the effect of pretreatment (pH adjustment and prechlorination) and aeration time on effluent quality and COD removal rate in tapioca wastewater treatment using SBR. Pretreatment was done by (1) adjustment of tapioca wastewater pH to control (4.92), 7, and 8, and (2) tapioca wastewater prechlorination at pH 8 during hour using calcium hypochlorite in variation dosages 0, 2, 4, 6 mg/L Cl2, SBR operation was conducted according to following steps: (1) Filling of pre-treated wastewater into a bioreactor during 1 hour, and (2) aeration of the mixture of tapioca wastewater and activated sludge during 8 hours. Effluent sample was collected at every 2-hours aeration for COD analysis. COD removal rate mathematical formula was got by first deriving the best fit function between aeration time and COD. Optimum aeration time resulting in no COD removal rate. The value of COD effluent and its removal rate in optimum aeration time was used to determine the recommended of operation condition of pretreatment. Research result shows that chosen pH operation condition is pH 8. Prechorination can make effluent quality which meets standard quality and highest COD removal rate. The chosen Cl2 dosage is 6 mg/L.


2011 ◽  
Vol 347-353 ◽  
pp. 1949-1952 ◽  
Author(s):  
Liang Li ◽  
Bing Zhe Xu ◽  
Chang Yu Lin ◽  
Xiao Min Hu

Zidovudine wastewater is difficult to biodegradation due to high COD and toxicity. The synergetic treatment of Zidovudine wastewater by Ultrasonic and iron-carbon micro-electrolysis technology was studied. The influence of initial pH, reaction time, mass ratio of iron and carbon and mass ratio of iron and water on degradation rate of COD was researched. The result showed that the COD removal rate was only about 54.3% and the degradation speed is very slow when iron-carbon micro-electrolysis treated Zidovudine wastewater separately. However, when ultrasonic synergy micro-electrolysis to treat Zidovudine wastewater, the COD removal rate could was up to 85% and the reaction time was also decreased. Moreover, the BOD5 / COD rose from 0.15 to 0.35, which meant the wastewater became easily biodegradable.


2014 ◽  
Vol 1010-1012 ◽  
pp. 805-808
Author(s):  
Xiu Wen Wu ◽  
Ping Ma ◽  
Hui Xia Lan ◽  
Heng Zhang ◽  
Shan Hong Lan

The influence of H2O2、addition of Fe2+、pH、reaction time and temperature to advanced treatment effect of printing and dyeing wastewater with Fenton oxidation was studied. The results showed that when the addition of H2O2(the concentration was 30%) was 3mL/L,the addition of FeSO4·7H2O was 1.6g/L,pH was 4,the temperature was about 30°C,reacting time was 35min,the COD removal efficiency achieved above 55%,COD of effluent was below 45mg/L.


Archaea ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Shuo Wang ◽  
Jianzheng Li ◽  
Guochen Zheng ◽  
Guocheng Du ◽  
Ji Li

Hydrogen-producing acetogens (HPA) have a transitional role in anaerobic wastewater treatment. Thus, bioaugmentation with HPA cultures can enhance the chemical oxygen demand (COD) removal efficiency and CH4yield of anaerobic wastewater treatment. Cultures with high degradation capacities for propionic acid and butyric acid were obtained through continuous subculture in enrichment medium and were designated as Z08 and Z12. Bioaugmentation with Z08 and Z12 increased CH4production by glucose removal to 1.58. Bioaugmentation with Z08 and Z12 increased the COD removal rate in molasses wastewater from 71.60% to 85.84%. The specific H2and CH4yields from COD removal increased by factors of 1.54 and 1.63, respectively. Results show that bioaugmentation with HPA-dominated cultures can improve CH4production from COD removal. Furthermore, hydrogen-producing acetogenesis was identified as the rate-limiting step in anaerobic wastewater treatment.


2014 ◽  
Vol 1010-1012 ◽  
pp. 190-194
Author(s):  
Xiao Gang Chen ◽  
Ju Chi Kuang ◽  
Min Hua Chen

In the paper we first discussed the principle of wastewater treatment by iron-carbon micro electrolysis. And the experimental methods were stated clear soon afterwards. Then we designed the micro electrolysis orthogonal experiments. Discussion of influences of related factors on waste water treatment followed. The main factors are cerium ion additive quantity, ratio of La3+/Ce4+ and pH in wastewater. The experimental results show that 1) The sequence of factors influence on wastewater micro-electrolysis treatment is Ce4+ > pH > La3+ > iron/carbon ratio; 2) The lanthanum and cerium ions have a synergistic effect in the wastewater treatment, and cerium ion plays a main role; 3) When pH is 6, COD removal rate arrives at maximum 89%, however when the pH is in the case of too high or too low, the effect of sewage treatment is not good.


2011 ◽  
Vol 415-417 ◽  
pp. 438-441
Author(s):  
Jin Xia Yan ◽  
Dong Fang Li ◽  
Shao Feng Dong

The printing and dyeing wastewater was treated by internal electrolysis method. The results show the chromaticity removal rate was up to 98.53 percent and COD removal rate 85.98 percent under the optimum conditions of wastewater pH 4, reaction time 30 minutes, the electric conductivity 1450μm/cm, the value BOD5/COD increases from 0.34 to 0.51. Moreover, the pH, Fe2+ concentration and absorbance of wastewater changed in the process, the mechanism of that was also analyzed.


2012 ◽  
Vol 610-613 ◽  
pp. 2367-2371 ◽  
Author(s):  
Ming Zhong Hu ◽  
Zhen He Shi ◽  
Hong Yan Zhao

The effects of the oxidation of potassium ferrate and the flocculation on cresol wastewater water were evaluated. This research aimed at determining the optimum conditions for the COD removal rate duing cresol wastewater water process. The results showed that potassium ferrate dosage of 1.1g/L, the pH value of 5, reaction time 15min, m-cresol initial concentration of 200 mg/L were the optimum conditions. Under the optimum conditions, COD removal rate was over 67%.


2013 ◽  
Vol 295-298 ◽  
pp. 1307-1310
Author(s):  
Xi Tian ◽  
Ming Xin Huo ◽  
De Jun Bian ◽  
Sheng Shu Ai ◽  
Qing Kai Ren

The wastewater produced from the polytetrahydrofuran (PolyTHF) was treated with iron-carbon micro electrolysis process. This paper had studied the COD removal efficiency influences of primary PH value, reaction time, the quality ratio of the iron-carbon, the quality and volume ratio of Fe-wastewater. The results show that when pH value is 3, the quality ratio of the iron-carbon is 11 and the quality and volume ratio of Fe and wastewater is 17 with contact time of 90 min, the wastewater COD removal rate can reach as high as 95.0%.


Water ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 206
Author(s):  
Yicheng Wang ◽  
Yingkun Wang ◽  
Xi Lu ◽  
Wenquan Sun ◽  
Yanhua Xu ◽  
...  

An Mn/Ce@red mud (RM) catalyst was prepared from RM via a doping–calcination method. Scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were used to characterize the surface morphology, crystal morphology, and elemental composition of the Mn/Ce@RM catalyst, respectively. In addition, preparation and catalytic ozonation conditions were optimized, and the mechanism of catalytic ozonation was discussed. Lastly, a fuzzy analytic hierarchy process (FAHP) was adopted to evaluate the degradation of coal chemical biochemical tail water. The best preparation conditions for the Mn/Ce@RM catalyst were found to be as follows: (1) active component loading of 3%, (2) Mn/Ce doping ratio of 2:1, (3) calcination temperature of 550 °C, (4) calcination time of 240 min, and (5) fly ash floating bead doping of 10%. The chemical oxygen demand (COD) removal rate was 76.58% under this preparation condition. The characterization results suggested that the pore structure of the optimized Mn/Ce@RM catalyst was significantly improved. Mn and Ce were successfully loaded on the catalyst in the form of MnO2 and CeO2. The best operating conditions in the study were as follows: (1) reaction time of 80 min, (2) initial pH of 9, (3) ozone dosage of 2.0 g/h, (4) catalyst dosage of 62.5 g/L, and (5) COD removal rate of 84.96%. Mechanism analysis results showed that hydroxyl radicals (•OH) played a leading role in degrading organics in the biochemical tail water, and adsorption of RM and direct oxidation of ozone played a secondary role. FAHP was established on the basis of environmental impact, economic benefit, and energy consumption. Comprehensive evaluation by FAHP demonstrated that D3 (with an ozone dosage of 2.0 g/H, a catalyst dosage of 62.5 g/L, initial pH of 9, reaction time of 80 min, and a COD removal rate of 84.96%) was the best operating condition.


2013 ◽  
Vol 807-809 ◽  
pp. 1473-1478
Author(s):  
Juan Xie ◽  
Xin Qiang Wang ◽  
Cheng Tun Qu

In this paper, aqueous methanol (methanol concentration 1000 mg·l-1) degradation was studied by using UV/Fenton, and effect of methanol degradation was evaluated with COD removal rate. When pH was determined, H2O2 dosage, Fe2+ dosage and reaction time were investigated by single factor test, respectively. In the orthogonal experiment, UV/Fenton was used to deal with wastewater of 1000 mg·l-1methanol, the order of the influent factors on COD removal was: H2O2 dosage > reaction time > Fe2+ content. Under the optimal condition (6%H2O250 ml·l-1, Fe2+ 0.9 g·l-1, reaction time 60 min), 95.77% COD removal rate was obtained. In addition, a comparison of UV, Fenton regent and UV/Fenton system indicated that UV and Fe2+ had synergistic effect on catalytic decomposition of H2O2, and reaction time to obtain the highest COD removal was shorted 10 min when UV/Fenton was used.


Sign in / Sign up

Export Citation Format

Share Document