Microwave Dielectric Properties of (Ca0.8Sr0.2)x(Li0.5Nd0.5)1-xTiO3 Ceramics

2015 ◽  
Vol 1095 ◽  
pp. 583-589
Author(s):  
Yun Yang ◽  
Chang Lai Yuan ◽  
Guo Hua Chen ◽  
Fu Wei Peng ◽  
Tao Yang

Microwave dielectric properties and microstructures have been investigated in the x Ca0.8Sr0.2TiO3 − (1−x) Li0.5Nd0.5TiO3 ceramic system. In the entire composition range, a single solid solution in the ceramic system was formed with the orthorhombic perovskite structure. As the Ca0.8Sr0.2TiO3 content of the ceramic system increased from 0.1 to 0.3, the dielectric constant (εr) increased from 114 to 144, the product (Qf) of quality factor (Q) and frequency (f) from 995 to 1,121 GHz, and the temperature coefficient of resonant frequency (τf) value from-83 to 94 ppm/°C, respectively. Simultaneously, the observed polarizabilities and the theoretical polarizability increased with rise in the Ca0.8Sr0.2TiO3 content. The τf value increased linearly with the increasing unit-cell volume. For practical application, a near-zero τf in the 0.2Ca0.8Sr0.2TiO3 −0.8Li0.5Nd0.5TiO3 ceramic with a Qf value of 1,025 GHz and a εr value of 132 were obtained at the sintering temperature of 1300°C for 4 h.

2015 ◽  
Vol 1119 ◽  
pp. 451-455
Author(s):  
Yih Chien Chen ◽  
Chih Hung Li ◽  
Hua Xian Liu ◽  
Jing Yu Fu

The influence of sintering temperature on the microwave dielectric properties and microstructure of the (1-y)Nd0.96Yb0.04(Mg0.5Sn0.5)O3-yCa0.8Sr0.2TiO3 ceramic system were investigated with a view to their application in microwave devices. The (1-y)Nd0.96Yb0.04(Mg0.5Sn0.5)O3-yCa0.8Sr0.2TiO3 ceramic systems were prepared using the conventional solid-state method. The X-ray diffraction patterns of the (1-y)Nd0.96Yb0.04(Mg0.5Sn0.5)O3-yCa0.8Sr0.2TiO3 ceramic system shifted to higher angle as y increased. A dielectric constant of 38.2, a quality factor (Q×f) of 53,500 GHz, and a temperature coefficient of resonant frequency of-3 ppm/°Cwere obtained when the 0.4 Nd0.96Yb0.04(Mg0.5Sn0.5)O3–0.6Ca0.8Sr0.2TiO3 ceramic system was sintered at 1600 °C for 4h.


2006 ◽  
Vol 966 ◽  
Author(s):  
Hongtao Yu ◽  
Hua Hao ◽  
Hanxing Liu ◽  
Zhongqing Tian

ABSTRACTThe effect of CuO on the microstructure and microwave dielectric properties of the CaTiO3-Ca(Zn1/3Nb2/3)O3 ceramics prepared by the conventional solid-method has been investigated. Doped with the 0.5∼1.25wt% CuO powder, the system of which the sintering temperatures were lowered exhibited the orthorhombic perovskite. It can effectively promote the microwave dielectric properties of the 0.3CaTiO3-0.7Ca(Zn1/3Nb2/3)O3 system at lower sintering temperature at the level of 1.0wt% CuO additive. The quality factor increases from 10860 to 13900GHz and not any significant change was observed in the TCF value with fixed CuO additive at different sintering temperature.


2003 ◽  
Vol 783 ◽  
Author(s):  
Cheng-Liang Huang ◽  
Yuan-Bin Chen ◽  
Ching-Wen Lo

ABSTRACTThe microwave dielectric properties of (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 (0.1≤x≤1.0) have been investigated. The system forms a solid solution throughout the entire compositional range. The dielectric constant decreases from 152 to 27 as x varies from 0.1 to 1.0. In the (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 system, the microwave dielectric properties can be effectively controlled by varying the x value. A maximum quality factor Qxf=43000GHz (where f is the resonant frequency) was achieved for samples with x=0.9, although the dielectric properties varied with sintering temperature. The Qxf value of (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 almost increased up to 1500°C, after which it decreased. At 1400°C, 0.1CaTiO3-0.9Nd(Mg1/2Ti1/2)O3 ceramics gives a dielectric constant εr of 42, a Qxf value of 35000 (GHz) and a τf value of -10 (ppm/°C).


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 438
Author(s):  
Shuwei Yang ◽  
Bingliang Liang ◽  
Changhong Liu ◽  
Jin Liu ◽  
Caisheng Fang ◽  
...  

The (1–x)Ca0.61La0.26TiO3-xNd(Mg0.5Ti0.5)O3 [(1–x)CLT-xNMT, x = 0.35~0.60] ceramics were prepared via microwave sintering. The effects of sintering temperature and composition on the phase formation, microstructure, and microwave dielectric properties were investigated. The results show that the microwave sintering process requires a lower sintering temperature and shorter sintering time of (1–x)CLT-xNMT ceramics than conventional heating methods. All of the (1–x)CLT-xNMT ceramics possess a single perovskite structure. With the increase of x, the dielectric constant (ε) shows a downward trend; the quality factor (Qf) drops first and then rises significantly; the resonance frequency temperature coefficient (τf) keeps decreasing. With excellent microwave dielectric properties (ε = 51.3, Qf = 13,852 GHz, τf = −1.9 × 10−6/°C), the 0.65CLT-0.35NMT ceramic can be applied to the field of mobile communications.


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