Impact of Inorganic Salts on Degradation of Azo Dye Using Fe (III)-Modified PAN Fiber Complex as Heterogeneous Fenton Catalyst

2011 ◽  
Vol 197-198 ◽  
pp. 1180-1183 ◽  
Author(s):  
Zhi Chao Wang ◽  
Yong Chun Dong ◽  
Si Ming Dong ◽  
Miao Hong

Fe (III)-amidoximated PAN fiber complex was prepared and used as a heterogeneous photo-Fenton catalyst for the oxidative degradation of Reactive Red 195 in water. The nature and concentration effect of inorganic salts on the dye degradation was investigated. Moreover, UV-Vis spectrum was also used to examine the decomposition process of the dye in the presence of the salt. The results indicated that the existence of the inorganic salts limited the photocatalytic degradation of the dye in water. Na2SO4 shows more strong inhibition effect on dye degradation than the other salts at the same conditions. UV-Vis spectrum demonstrated that the decomposition of the aromatic rings in the dye molecules was also reduced in the presence of the salt.

2012 ◽  
Vol 602-604 ◽  
pp. 913-916
Author(s):  
Zhi Zhong Ding ◽  
Yong Chun Dong

Fe (III)-modified polytetrafluoroethylene (PTFE) fiber complex was prepared with poly acrylic acid grafted PTFE fiber and FeCl3 aqueous solution and used a novel heterogeneous Fenton catalyst for the photo-assisted degradation of Rhodamine B in water. The results indicated that Fe (III)-grafted PTFE) fiber complex can significantly enhance the dye degradation at a wide pH media under light irradiation. Increasing Fe content of the catalyst, H2O2 concentration and visible irradiation intensity leads to a fast degradation. Moreover, UV light irradiation is much more effective than visible light irradiation for promoting dye degradation.


2010 ◽  
Vol 49 (2) ◽  
pp. 498-505 ◽  
Author(s):  
A. Rodríguez ◽  
G. Ovejero ◽  
J. L. Sotelo ◽  
M. Mestanza ◽  
J. García

2012 ◽  
Vol 268-270 ◽  
pp. 225-228
Author(s):  
Zhen Bang Han ◽  
Jia Guo ◽  
Wei Li

The amidoximated Polyacrylonitrile (PAN) fiber was applied for the support to immobilize Fe(bpy)32+ through ionic bonds, and the obtained fibrous complex was used as heterogeneous Fenton catalyst for the degradation of Rhodamine B under visible light irradiation. The results indicated that increasing Fe(bpy)32+ concentration in solution led to higher Fe(bpy)32+ content on the prepared catalysts, and the amidoxime groups helped greatly for the immobilization of Fe(bpy)32+ via coordination effect. This catalyst exhibits an obvious absorption in the visible region and could effectively degrade Rhodamine B in the presence of H2O2 under visible light irradiation. In addition, no deactivation of the catalyst was observed even after five consecutive runs of dye degradation.


2013 ◽  
Vol 652-654 ◽  
pp. 245-249
Author(s):  
Xue Ting Zhao ◽  
Yong Chun Dong ◽  
Bo Wen Cheng ◽  
Wei Min Kang

Polyacrylonitrile (PAN) nanofibers were fabricated via electrospinning technique, and the modified Fe-polyacrylonitrile nanofibers photocatalysts(Fe-AO-n-PAN) were prepared by a reaction between PAN nanofibers (AO-n-PAN) containing amidoxime group and ferric chloride. Then Fe-AO-n-PAN were used as heterogeneous catalysts in the oxidative degradation reaction of C.I. Reactive Red 195(RR195) in water. This paper investigated the influences on the degree of the conversion from nitrile group to amidoxime group (CP%); analyzed the impacts on the Fe (III) ions content (QFe-PAN) in Fe-AO-n-PAN; and studied the effects of QFe-PANon the decoloration rate of the dye. The results indicated that the CP% value were greatly enhanced not only with concentration of NH2OH•HCl increasing, but also gradually with the prolongation of reaction time. In addition, the QFe-PANof Fe-AO-n-PAN increases with the rise of CFeand the CP% value. Finally, Fe-AO-n-PAN have remarkable catalytic activity on the degradation of RR 195, and higher QFe-PANcould promote the catalytic performance of Fe-AO-n-PAN.


2021 ◽  
Vol 11 (1) ◽  
pp. 67-73
Author(s):  
Manh Nguyen Ba ◽  
Trang Pham Thi Thu ◽  
Hoa Tran Thi ◽  
Giang Le Ha

Nanocomposite Zn-BTC/GO (BTC: benzene-1,3,5-tricarboxylic, GO: graphene oxide) was successfully synthesized by hydrothermal treatment with a microwave method. Samples were characterized by XRD, FTIR, EDS-mapping, BET, SEM, UV-vis DRS and XPS. SEM-image result showed nano Zn-BTC/GO particles size of 50-80 nm. Nanocomposite Zn-BTC/GO showed the a high surface area (1303 m2/g) and pore volume (1.08 cm3/g). The Zn-BTC/GO nanocomposite were tested for the photocatalytic degradation of reactive dye (Reactive Red 195) in an aqueous solution. The Zn-BTC/GO composites exhibited high photocatalytic activity. Thus, at the pH of 6.5 and the high initial concentration of 30 mg RR-195/L, removal efficiency reached the value of 96.16% after 60 min reaction. Moreover, nano Zn-BTC also showed high RR-195 removal efficiency after 3 catalytic regeneration. This contributes to sustainable development and green chemistry.


2018 ◽  
Vol 124 (2) ◽  
pp. 931-956 ◽  
Author(s):  
Gloria Murielle Rostandi Kpinsoton ◽  
Héla Karoui ◽  
Yohan Richardson ◽  
Blédja N’dri Stéphanie Koffi ◽  
Hamma Yacouba ◽  
...  

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