Mechanism Analysis of Indigenous Microbial Enhancement for Residue Oil Recovery

2011 ◽  
Vol 365 ◽  
pp. 305-311
Author(s):  
Fu Chang Shu ◽  
Yue Hui She ◽  
Zheng Liang Wang ◽  
Shu Qiong Kong

Biotechnological nutrient flooding was applied to the North block of the Kongdian Oilfield during 2001-2005. The biotechnology involved the injection of a water-air mixture made up of mineral nitrogen and phosphorous salts with the intent of stimulating the growth of indigenous microorganisms. During monitoring of the physico-chemical, microbiological and production characteristics of the North block of the Kongdian bed, it was revealed significant changes took place in the ecosystem as a result of the technological treatment. The microbial oil transformation was accompanied by an accumulation of carbonates, lower fatty acids and biosurfactants in water formations, which is of value to enhanced oil recovery. The microbial metabolites changed the composition of the water formation, favored the diversion of the injected fluid from closed, high permeability zones to upswept zones and improved the sweep efficiency. The results of the studies demonstrated strong hydrodynamic links between the injection wells and production wells. Microbiological monitoring of the deep subsurface ecosystems and the filtration properties of the fluids are well modified, producing 40000 additional tons of oil in the test areas.

2021 ◽  
Vol 73 (06) ◽  
pp. 65-66
Author(s):  
Judy Feder

This article, written by JPT Technology Editor Judy Feder, contains highlights of paper SPE 200460, “A Case Study of SACROC CO2 Flooding in Marginal Pay Regions: Improving Asset Performance,” by John Kalteyer, SPE, Kinder Morgan, prepared for the 2020 SPE Improved Oil Recovery Conference, originally scheduled to be held in Tulsa, 18–22 April. The paper has not been peer reviewed. As one of the first fields in the world to use carbon dioxide (CO2) in enhanced oil recovery (EOR), the Scurry Area Canyon Reef Operators Committee (SACROC) unit of the Kelly-Snyder field in the Midland Basin of Texas provides a unique opportunity to study, learn from, and improve upon the development of CO2 flood technology. The complete paper reviews the history of EOR at SACROC, discusses changes in theory over time, and provides a look at the field’s future. Field Overview and Development History The first six pages of the paper discuss the field’s location, geology, and development before June 2000, when Kinder Morgan acquired the SACROC unit and took over as operator. Between initial gas injection in 1972 and 2000, approximately 1 TCF of CO2 had been injected into the Canyon Reef reservoir. Since 2000, cumulative CO2 injection has sur-passed 7 TCF and yielded cumulative EOR of over 180 million bbl. The reservoir is a primarily limestone reef complex containing an estimated original oil in place (OOIP) of just under 3 billion bbl. The reservoir ranges from 200 ft gross thickness in the south to 900 ft in the north, where the limestone matrix averages 8% porosity and 20-md permeability. The Canyon Reef structure is divided into four major intervals, of which the Upper Canyon zone provides the highest-quality pay. The field was discovered in 1948 at a pressure of 3,122 psi. By late 1950, 1,600 production wells had been drilled and the reservoir pressure plummeted, settling as low as 1,700 psi. Waterflooding begun in 1954 enabled the field to continue producing for nearly 20 years, at which time the operators deter-mined that another recovery mechanism would be needed to maximize recovery and reach additional areas of the field. The complete paper discusses various CO2 injection programs that were developed and applied—including a true tertiary response from a miscible CO2 flood in 1981—along with their outcomes. Acquisition and CO2-Injection Redevelopment In June 2000 Kinder Morgan acquired the SACROC Unit and took over as operator. Approximately 6.7 billion bbl of water and 1.3 TCF of CO2 had been injected across the unit to that date, but the daily oil rate of 8,700 B/D was approaching the field’s economic limit. An estimated 40% of the OOIP had been produced through the combination of recovery methods that each previous operator had used. Expanding on the conclusions of its immediate predecessor, the operator initiated large-scale CO2-flood redevelopment in a selection of project areas. These redevelopments were based on several key distinctions differentiating them from previous injection operations.


1982 ◽  
Vol 22 (01) ◽  
pp. 69-78
Author(s):  
H. Kazemi ◽  
D.J. MacMillan

Abstract The work presented in this paper was undertaken to study the effect of pattern configuration on oil recovery by the Maraflood oil-recovery process. The patterns studied are the five-spot and the 4 × 1 line drive. These patterns are obtained by placing infill wells in an existing 10-acre (40 469-m2) waterflooded five-spot pattern to obtain the 2.5-acre (10 117-m2) patterns. The number of infill wells is the same for both the new five-spot and new line-drive configurations and is about three times the number of existing wells. Both patterns have been used successfully in field applications by Marathon before this study. For instance, a line-drive pattern was used in Project 119-R and a five-spot pattern was used in Project 219-R. This work shows that the line drive produces more tertiary oil than the five-spot under otherwise identical reservoir conditions. Breakthrough times and oil rates for line-drive production wells are nearly the same. Meanwhile, five-spot production wells have vastly differing oil breakthrough times and oil rates. Both of the latter effects result from a nonuniform distribution of waterflood residual oil saturation in the field. Our study also shows that if producing wells in each line-drive row are connected by a perfect vertical fracture and if the same is true of the injection wells, the line-drive efficiency will improve very little. Introduction The Maraflood oil-recovery process is a viable enhanced oil-recovery technique. An appraisal of this process and other surfactant-enhanced oil-recovery schemes was reported by Gogarty. Three significant field tests of the Maraflood process were reported by Earlougher et al. In addition, a large-scale field application of this process was presented recently by Howell et al. in field applications of the Maraflood process, both line-drive and five-spot configurations have been used. In our field experience, an existing five-spot waterflood pattern is convened to another five-spot or 4 × 1 line-drive configuration by adding infill wells. The new five-spot or line-drive pattern has an area-per-well spacing of one-fourth of the original waterflood spacing. In practice, the number of infill wells required for both cases is somewhat greater than three times the number of existing wells. As the total number of wells increases, this ratio approaches the theoretical limit of three. In addition to the preceding arrangements of infill wells, many others are possible. In some arrangements, fewer infill wells are required than in our five-spot and 4 × 1 line drive. In such cases, the area per well increases, which generally causes these problems:required injectivity per injection well increases and may not be attainable because of the high viscosity of the injected fluids andthe breakthrough time is delayed. As an example, consider the case where no infill wells are drilled. In addition to the two problems just listed, the micellar/polymer flooding scheme will sweep only those regions that already have been swept well by the waterflood. The regions left unswept by the waterflood also will be left essentially unswept by the micellar/polymer flood. This means that a substantial amount of oil is left in place. Therefore, these types of undesired patterns were not considered in this study. Patterns with more infill wells than those in this study were not considered because of current economic limitations. Because of the likelihood of economic and technical merits, we also considered the placement of long vertical fractures to connect existing waterflood wells in place of infill wells. The fractures were arranged to form a more effective line drive. We emphasize that the patterns studied in this paper are those usually used in micellar/polymer flooding applications. Muskat has reported breakthrough waterflood sweep efficiencies of 72% and 88% for five-spot and 4 × 1 line drive patterns when the mobility ratio is unity. Muskat's results are for ideal plug flow displacement of red water by blue water in a perfectly homogeneous reservoir. SPEJ P. 69^


2006 ◽  
Vol 9 (06) ◽  
pp. 664-673 ◽  
Author(s):  
Harry L. Chang ◽  
Xingguang Sui ◽  
Long Xiao ◽  
Zhidong Guo ◽  
Yuming Yao ◽  
...  

Summary The first large-scale colloidal dispersion gel (CDG) pilot test was conducted in the largest oil field in China, Daqing oil field. The project was initiated in May 1999, and injection of chemical slugs was completed in May 2003. This paper provides detailed descriptions of the gel-system characterization, chemical-slug optimization, project execution, performance analysis, injection facility design, and economics. The improvements of permeability variation and sweep efficiency were demonstrated by lower water cut, higher oil rate, improved injection profiles, and the increase of the total dissolved solids (TDS) in production wells. The ultimate incremental oil recovery (defined as the amount of oil recovered above the projected waterflood recovery at 98% water cut) in the pilot area would be approximately 15% of the original oil in place (OOIP). The economic analysis showed that the chemical costs were approximately U.S. $2.72 per barrel of incremental oil recovered. Results are presented in 15 tables and 8 figures. Introduction Achieving mobility control by increasing the injection fluid viscosity and achieving profile modification by adjusting the permeability variation in depth are two main methods of improving the sweep efficiency in highly heterogeneous and moderate viscous-oil reservoirs. In recent years (Wang et al. 1995, 2000, 2002; Guo et al. 2000), the addition of high-molecular-weight (MW) water-soluble polymers to injection water to increase viscosity has been applied successfully in the field on commercial scales. Weak gels, such as CDGs, formed with low-concentration polymers and small amounts of crosslinkers such as the trivalent cations aluminum (Al3+) and chromium (Cr3+) also have been applied successfully for in-depth profile modification (Fielding et al. 1994; Smith 1995; Smith and Mack 1997). Typical behaviors of CDGs and testing methods are given in the literature (Smith 1989; Ranganathan et al. 1997; Rocha et al. 1989; Seright 1994). The giant Daqing oil field is located in the far northeast part of China. The majority of the reservoir belongs to a lacustrine sedimentary deposit with multiple intervals. The combination of heterogeneous sand layers [Dykstra-Parsons (1950) heterogeneity indices above 0.5], medium oil viscosities (9 to 11 cp), mild reservoir temperatures (~45°C), and low-salinity reservoir brines [5,000 to 7,000 parts per million (ppm)] makes it a good candidate for chemical enhanced-oil-recovery processes. Daqing has successfully implemented commercial-scale polymer flooding (PF) since the early 1990s (Chang et al. 2006). Because the PF process is designed primarily to improve the mobility ratio (Chang 1978), additional oil may be recovered by using weak gels to further improve the vertical sweep. Along with the successes of PF in the Daqing oil field, two undesirable results were also observed:high concentrations of polymer produced in production wells owing to the injection of large amounts of polymer (~1000 ppm and 50% pore volume) andthe fast decline in oil rates and increase in water cuts after polymer injection was terminated. In 1997, a joint laboratory study between the Daqing oil field and Tiorco Inc. was conducted to investigate the potential of using the CDG process, or the CDG process with PF, to further improve the recovery efficiency, lower the polymer production in producing wells, and prolong the flood life. The joint laboratory study was completed in 1998 with encouraging results (Smith et al. 2000). Additional laboratory studies to further characterize the CDG gellation process, optimize the formulation, and investigate the degradation mechanisms were conducted in the Daqing field laboratories before the pilot test. A simplistic model was used to optimize the slug designs and predict incremental oil recovery. Initial designs called for a 25% pore volume (Vp) CDG slug with 700 ppm polymer and the polymer-to-crosslinker ratio (P/X) of 20 in a single inverted five-spot patten. Predicted incremental recovery was approximately 9% of OOIP.


1991 ◽  
Vol 14 (1) ◽  
pp. 347-352 ◽  
Author(s):  
P. L. Cutts

AbstractThe Maureen Oilfield is located on a fault-bounded terrace in Block 16/29a of the UK Sector of the North Sea, at the intersection of the South Viking Graben and the eastern Witch Ground Graben. The field was discovered in late 1972 by the 16/29-1 well, and was confirmed by three further appraisal wells. The reservoir consists of submarine fan sandstones of the Palaeocene Maureen Formation, deposited by sediment gravity flows sourced from the East Shetland Platform. The Palaeocene sandstones, ranging from 140 to 400 ft in thickness, have good reservoir properties, with porosities ranging from 18-25% and permeabilities ranging from 30-3000 md. Hydrocarbons are trapped in a simple domal anticline, elongated NW-SE, which was formed at the Palaeocene level by Eocene/Oligocene-aged movement of underlying Permian salt. The reservoir sequence is sealed by Lista Formation claystones. Geochemical analysis suggests Upper Jurassic Kimmeridge Clay shales have been the source of Maureen hydrocarbons. Estimated recoverable reserves are 210 MMBBL. Twelve production wells have been drilled on the Maureen Field. A further seven water injection wells have been drilled to maintain reservoir pressure.


2014 ◽  
Author(s):  
W.. Li ◽  
D. S. Schechter

Abstract Carbon dioxide (CO2) has been used commercially to recover oil from reservoirs by enhanced oil recovery (EOR) technologies for over 40 years. Currently, CO2 flooding is the second most applied EOR processes in the world behind steamflooding. Water alternating gas (WAG) injection has been a popular method to control mobility and improve volumetric sweep efficiency for CO2 flooding. The average improved recovery is about 9.7%, with a range of 6 to 20% for miscible WAG injection. Despite all the success of WAG injection, sweep efficiency during CO2 flooding is typically a challenge to reach higher oil recovery and better apply the technology. This paper proposes a new combination method called polymer alternating gas (PAG) to improve the volumetric sweep efficiency of the WAG process. The feature of this new method is that polymers are added to water during the WAG process to improve mobility ratio. In the PAG process, polymer flooding and immiscible/miscible CO2 injection are combined. To analyze the feasibility of PAG, models considering both miscible and polymer flooding processes are built to study the performance of PAG. In this paper, the sensitivity of polymer adsorption and concentration are studied. The feasibility of PAG in reservoirs with different permeabilities, different Dykstra-Parsons permeability variation coefficients (VDPs), and different fluids are also studied. A reservoir model from a typical section of the North Burbank Unit (NBU) is used to compare the performance between PAG, WAG, and polymer flooding. This study demonstrates that PAG can significantly improve recovery for immiscible/miscible flooding in homogeneous or heterogeneous reservoirs.


2016 ◽  
Vol 703 ◽  
pp. 251-255
Author(s):  
Peng Ye ◽  
Dong Zhang ◽  
Lian Bin Zhong ◽  
Guang Wang ◽  
Bin Fu ◽  
...  

This study gives the influence laws of abandoned channel, in-layer interlayer, sand body contact relationship on the development effect of the Alkaline Surfactant Polymer (ASP) flooding based on the data of the industry promotion block ( Pu I32、Pu I33 sedimentation), and give out corresponding adjustment strategy at the same time. The result shows that: The ‘abruptly abandoned’ channels have a bad connection with the main channel and possesses a far lower reservoir producing degree (16.1%) than the ‘gradually-abandoned’ channels (79.9%). The injection wells located upon the channel sand need high concentration inject fluid with lower injection rate to handle the polymer breakthrough; The injection wells located between the channels need lower concentration injection; The injection wells located upon the abandoned channels firstly need high concentration injection to achieve the profile control and then inject low concentration fluid to adjust low permeable sublayer; The production wells located upon abandoned channels need timely fracturing measures. By July 2014, water content of this area is 90.7%, oil recovery improved 18.08% and is expected to reach 22.0%. Similar the success experience we get from this area can guide the study of block geologic factors that affect development result and has important guiding significance to the implementation of pointed development adjustment.


2016 ◽  
Vol 19 (04) ◽  
pp. 655-663 ◽  
Author(s):  
Torsten Clemens ◽  
Markus Lüftenegger ◽  
Ajana Laoroongroj ◽  
Rainer Kadnar ◽  
Christoph Puls

Summary Polymer-injection pilot projects aim at reducing the uncertainty and risk of full-field polymer-flood implementation. The interpretation of polymer-pilot projects is challenging because of the complexity of the process and fluids moving out of the polymer-pilot area. The interpretation is increasingly more complicated with the heterogeneity of the reservoir. In the polymer pilot performed in the 8 Torton Horizon (TH) reservoir of the Matzen field in Austria, a polymer-injection well surrounded by a number of production wells was selected. A tracer was injected 1 week before polymer injection. The tracer showed that the flow field in the reservoir was dramatically modified with increasing amounts of polymer injected. Despite short breakthrough times of 4 to 10 weeks observed for the tracer, polymer breakthrough occurred only after more than 12 months although injection and production rates were not substantially changed. The tracer signal indicated that the reservoir is heterogeneous, with high flow velocities occurring along a number of flow paths with a limited volume that are strongly connecting the injection and production wells. By injecting polymers, the mobility of the polymer-augmented water was reduced compared with water injection, and led to flow diversion into adjacent layers. The tracer response showed that the speed of the tracer moving from injection to production wells was reduced with increasing amount of polymer injected. This response was used to assess the changes of the amount of water flowing from the injection well to production wells. After a match for the tracer curve was obtained, adsorption, residual resistance factor (RRF), and dispersivity were calculated. The results showed that, even for heterogeneous reservoirs without good conformance of the pilot, the critical parameters for polymer-injection projects can be assessed by analyzing tracer and polymer response. These parameters are required to determine whether implementation of polymer injection at field scale is economically attractive. Along the flow path that is connecting injection and production well, as shown by the tracer response, an incremental recovery of approximately 8% was achieved. The polymer retention and inaccessible pore volume (IPV) in the reservoir were in the same range as in corefloods. Incremental oil recovery caused by acceleration along the flow path was estimated at approximately 20% of the overall incremental oil production caused by polymer injection and 80% was attributed to improved sweep efficiency.


2020 ◽  
Author(s):  
Sudad H Al-Obaidi ◽  
Guliaeva NI ◽  
Khalaf FH

Most of the liquid oil of all types estimated today represents the category of heavy-oils. This leads to decrease in oil production and more extraction of water. Enhanced oil recovery is a method using sophisticated techniques that can deal with such sort of oils and alter the original properties of oil. Thermal Enhanced Oil Recovery (EOR) remains the most frequently used method for extraction of heavy oils. In this work, irreversible changesin rocks that lead to an increase in formation permeability have been studied and, as a result, to an increase in the production flow rate of production wells and for injection wells, an increase in their injectivity. New methods and technologies have been developed for the intensification of thermocyclic well treatments.A computer program based on mathematical model was developed, which allows predicting changes occurring in the well and near the well space. In this model, the main characteristics of the process of cyclic thermal impact on the bottom-hole zone can be used to predict field temperatures in the well and in the formation, as well as changes in the permeability of rocks. To improve the efficiency use of the model and increase the heating zone, a new method of thermal cycling impact on the bottom-hole zone of the well was developed.


1982 ◽  
Vol 22 (04) ◽  
pp. 463-471 ◽  
Author(s):  
Deborah S. Jordan ◽  
Don W. Green ◽  
Ronald E. Terry ◽  
G. Paul Willhite

Abstract Gelled polymers are being applied to modify the movement of injected fluids in the vicinity of injection and production wells in secondary and enhanced oil-recovery projects. One approach to gelation is to form a bulk gel in situ by injecting a slug of a polyacrylamide polymer solution containing chromium (VI) followed by a polymer slug containing a reducing agent such as sodium bisulfite. Upon mixing, CR(VI) is reduced to Cr(III), and in the subsequent reaction a gel is formed. The gelation time controls the volume of fluid that can be injected in the treatment and thus is an important variable in the process. Gelation time is known to be a function of the concentration of the reactants (chromium ion, reducing agent, and polymer) as well as the polymer type, and some data relating these variables to gelation time have been reported. Another variable affecting the reaction rate is temperature, but no data relating gelation time and temperature have been published. The purposes of the work described in this paper were to obtain experimental data on the effect of temperature on gelation time for typical polyacrylamide/Cr(III) gel systems over the range of temperatures commonly encountered in reservoirs and to develop a method of correlating the data. Gelation times were measured for five different polymers, including polymers with various degrees of hydrolysis and polymers with nonionic, anionic, and cationic character. The temperature range was 25 to 80 deg. C. Polymer, metal ion, and redox system concentrations and salinity also were varied. It was determined that, for a given polymer-reducing agent system at a specified concentration, the gelation time decreases as temperature is increased. The data were correlated in a manner analogous to the Arrhenius method of correlating chemical reaction rate data. That is, plots of the logarithm of gelation time vs. the reciprocal of the absolute reaction temperature were linear over the temperature range studied. By use of a simple nth-order reaction rate model, the slope of the Arrhenius-type plot was related to activation energy. These activation energies were found to vary only slightly for the polymer systems and concentrations investigated. The results have direct application in the design of gel treatments for injection or production wells. The correlation method provides a way of predicting the effect of temperature on the time required for a given system to gel. It is recognized that in field applications factors beyond the scope of data taken in this paper may affect the gelation process. Introduction The volumetric sweep efficiency of a secondary or enhanced oil-recovery process is a major factor in determining the amount of oil recoverable by that process. In waterflooding, low efficiency results in high WOR's that lead to high operating costs in handling produced water relatively early in a project. When the WOR becomes high enough that the project is no longer economically justified, the process is terminated, and a significant amount of oil may be left unrecovered. In enhanced oilrecovery methods that involve the injection of expensive chemicals, low efficiency is even more costly. Economics may not justify the initiation of such a treatment if the expected efficiency is not sufficiently high. Reservoir heterogeneity is the primary reason for poor sweep efficiency. Particularly common are permeability variations in the vertical direction. The injected fluids tend to flow in the zones of higher permeability, bypassing the oil in the tighter zones if the permeability differences are significant. The resulting low sweep efficiency could be improved if the high permeabilities could be reduced. SPEJ P. 463^


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