A Study of Corrosion Inhibition of Carbon Steel in Hydrochloric Acid Using BIMGCS12-3

2012 ◽  
Vol 427 ◽  
pp. 3-6 ◽  
Author(s):  
Yong Ming Sun ◽  
Hong Ling Chen
Keyword(s):  
Melting Point ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Inhibition ◽  
Elemental Analysis ◽  
Inhibition Efficiency ◽  
Raw Materials ◽  
Ammonium Bromide ◽  
Target Compound ◽  
H Nmr

Gemini benzimidazole cationic surfactant, propanediyl-α, ω-bis-(N-dodecyl benzimidazole ammonium bromide), referred as BIMGCS12-3, was synthesized from the raw materials of benzimidazole, dodecane bromide and dibromopropane. The structure of the target compound was confirmed by1H NMR, elemental analysis and melting point measurements. Its surface properties were determined and corrosion inhibition of carbon steel in 1M HCl was investigated by gravimetric measurements. BIMGCS12-3 exhibited excellent protection for carbon steel in the low concentration 20mg L-1and the inhibition efficiency for corrosion decreased with increment of temperature.

scholarly journals Electrochemical and Surface Morphological Studies of Carbon Steel Corrosion by a Novel Polynuclear Schiff Base in HCl Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul
Keyword(s):  
Weight Loss ◽  
Schiff Base ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Inhibition Efficiency ◽  
Morphological Studies

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.

scholarly journals Experimental and surface morphological studies of corrosion inhibition on carbon steel in HCl solution using some new hydrazide derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (22) ◽  
pp. 13497-13512
Author(s):  
Abd El-Aziz S. Fouda ◽  
Samir A. Abd El-Maksoud ◽  
Elsherbiny H. El-Sayed ◽  
Hazem A. Elbaz ◽  
Ashraf S. Abousalem
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Inhibitory Effect ◽  
Inhibition Mechanism ◽  
Morphological Studies ◽  
Hcl Solution

The inhibitory effect of three newly synthesized hydrazide derivatives on carbon steel corrosion in hydrochloric acid showed better inhibition efficiency (97.5%) and their inhibition mechanism is presented.

scholarly journals CORROSION INHIBITION OF CARBON STEEL IN HYDROCHLORIC ACID

2021 ◽  
Vol 21 (3) ◽  
pp. 197-212
Author(s):  
Falah Kaify Matloub
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Corrosion Inhibition ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Cathodic Reaction ◽  
Anodic Reaction ◽  
Organic Inhibitor ◽  
Better Than

The corrosion of carbon steel in 0.3 and 3% mass hydrochloric acid containing the concentration range 50-800 ppm of Thiourea (Th), Quinoline (Q), Dliethylamine (DEA) and Pyridine (P) were investigated using electrochemical methods. The investigation aims to mention the best organic inhibitor among several compounds to be used in synergic inhibitors. The inhibition efficiencies of thiourea and quinoline are better than pyridine and diethylamine in 0.3 mass% HCl. Thiourea is better than quinoline in 3 mass% HCl and its inhibition efficiency is 83.7%. Generally, the corrosion rate decreases with increasing inhibitors concentration. Diethylamine and pyridine are not effective. The polarization curves indicate that the used inhibitors influenced the cathodic reaction more than the anodic reaction and they are considered as a mixed type inhibitors

Adsorption and corrosion inhibition characteristics of two medicinal molecules

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Half Life ◽  
Thermodynamic Data ◽  
Inhibition Efficiency ◽  
Gravimetric Method ◽  
Corrosive Environment ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition characteristics of two medicinal molecules phenylalanine and rutin on mild steel in 1.0M Hydrochloric acid were evaluated using gravimetric method. Corrosion inhibition efficiency of 83.78 and 90.40 % was obtained respectively after seven days. However, phenylalanine showed weak accumulative higher corrosion inhibition efficiency. The presence of both molecules in the corrosive environment reduced the corrosion rate constant and increased the material half-life. Thermodynamic data calculated suggests a spontaneous adsorption of the molecules on the mild steel’s surface.

scholarly journals Experimental Theoretical Studies on Extract of Date Palm Seed as a Green Anti-Corrosion Agent in Hydrochloric Acid Solution

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3535
Author(s):  
Naba Jasim Mohammed ◽  
Norinsan Kamil Othman ◽  
Mohamad Fariz Mohamad Taib ◽  
Mohd Hazrie Samat ◽  
Solhan Yahya
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Active Sites ◽  
Immersion Time ◽  
Steel Surface ◽  
Date Palm ◽  
Inhibition Efficiency ◽  
Experimental Results ◽  
Plant Materials ◽  
Carbon Steel Surface

Extracts from plant materials have great potential as alternatives to inorganic corrosion inhibitors, which typically have harmful consequences. Experimental and theoretical methodologies studied the effectiveness of agricultural waste, namely, date palm seed extract as a green anti-corrosive agent in 0.5 M hydrochloric acid. Experimental results showed that immersion time and temperature are closely related to the effectivity of date palm seed as a corrosion inhibitor. The inhibition efficiency reduced from 95% to 91% at 1400 ppm when the immersion time was increased from 72 h to 168 h. The experimental results also indicated that the inhibition efficiency decreased as the temperature increased. The presence of a protective layer of organic matter was corroborated by scanning electron microscopy. The adsorption studies indicated that date palm seed obeyed Langmuir adsorption isotherm on the carbon steel surface, and Gibbs free energy values were in the range of −33.45 to −38.41 kJ·mol−1. These results suggested that the date palm seed molecules interacted with the carbon steel surface through mixture adsorption. Theoretical calculations using density functional theory showed that the capability to donate and accept electrons between the alloy surface and the date palm seed inhibitor molecules is critical for adsorption effectiveness. The HOMO and LUMO result indicated that the carboxyl (COOH) group and C=C bond were the most active sites for the electron donation-acceptance type of interaction and most auxiliary to the adsorption process over the Fe surface.

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