Soil Washing and Bioremediation of Tailing Dam Wastes

2012 ◽  
Vol 610-613 ◽  
pp. 2405-2409
Author(s):  
Li Mei Sun ◽  
Jiang Wu ◽  
Shuai Qi Meng

The paper presents that soil washing and bioremediation technologies were employed to treat the contaminated soil. Various works were conduced in parallel with each other and th results of the laboratouy studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tests at three concentration levels respectively. The tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Hightest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil samples. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particalarly Mn, decreased as the depth of samping increased. Heterogeneous bacteria and filamentous organism plate counts were conduced to evaluate the growth of the bacteria and filamentous organisms in the soil. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil’s porosity and bioremediating the soil, higher extractions of metals were achieved.

2015 ◽  
Vol 5 (3) ◽  
pp. 1-6 ◽  
Author(s):  
Zainab Siddiqui ◽  
◽  
S.M Ali Jawaid ◽  
Sandeep Vishen ◽  
Shreya Verma ◽  
...  

2020 ◽  
Vol 42 (4) ◽  
pp. 218-227
Author(s):  
Yeseul Gwon ◽  
Seong Ryeol Kim ◽  
Eun Jung Kim

Objectives : Soil washing process has been widely applied for remediation of contaminated soil with arsenic and heavy metals in Korea. The application of soil washing could change physical and chemical properties of soils and metal speciation in soil, which could affect the risk to the environment and human health. Thus, it is necessary to evaluate metal and arsenic speciation and their mobility in soil after soil remediation in order to evaluate effectiveness of soil remediation process and manage soil quality effectively. The purpose of this study is to evaluate the risk of arsenic in soil after remediation of arsenic contaminated soil via soil washing.Methods : Arsenic contaminated soil collected at the abandoned mine site was washing with oxalic acid. The arsenic contaminated soil was divided into 2,000-500 µm, 500-250 µm, 250-150 µm, 150-75 µm, 75-38 µm, < 38 µm particle size fractions. After soil washing for each soil particle size fraction, arsenic speciation via sequential extraction and bioaccessibility in the soils were evaluated. Results and Discussion : Generally, arsenic and metal concentrations were higher in the soil fractions with smaller particle sizes. But high arsenic concentration was observed at the large particle size fractions (>250 µm), which might be due to the presence of mineral phases containing arsenic such as arsenolite or pyrite in the large particle size fraction soils. Sequential extraction showed that arsenic in mine soils was majorly present as associated with amorphous oxides. After soil washing with oxalic acid, arsenic in soils associated with amorphous oxides was greatly decreased, whereas the arsenic fraction associated sulfide and organic matter was increased. Soil washing decreased the bioaccessible arsenic concentration (mg/kg) in soil, but increased the bioaccessibility (%) depending on the soil characteristics. Conclusions : Soil washing changed arsenic species in soils, which affected mobility and risk of arsenic in soil.


Author(s):  
Kanghee Cho ◽  
Eunji Myung ◽  
Hyunsoo Kim ◽  
Cheonyoung Park ◽  
Nagchoul Choi ◽  
...  

In this study, we investigated the feasibility of using a solution of sulfuric acid and phosphoric acid as an extraction method for soil-washing to remove Cu, Pb, Zn, and As from contaminated soil. We treated various soil particles, including seven fraction sizes, using sulfuric acid. In addition, to improve Cu, Pb, Zn, and As removal efficiencies, washing agents were compared through batch experiments. The results showed that each agent behaved differently when reacting with heavy metals (Cu, Pb, and Zn) and As. Sulfuric acid was more effective in extracting heavy metals than in extracting As. However, phosphoric acid was not effective in extracting heavy metals. Compared with each inorganic acid, As removal from soil by washing agents increased in the order of sulfuric acid (35.81%) < phosphoric acid (62.96%). Therefore, an enhanced mixture solution using sulfuric acid and phosphoric acid to simultaneously remove heavy metals and As from contaminated soils was investigated. Sulfuric acid at 0.6 M was adopted to combine with 0.6 M phosphoric acid to obtain the mixture solution (1:1) that was used to determine the effect for the simultaneous removal of both heavy metals and As from the contaminated soil. The removal efficiencies of As, Cu, Pb, and Zn were 70.5%, 79.6%, 80.1%, and 71.2%, respectively. The combination of sulfuric acid with phosphoric acid increased the overall As and heavy metal extraction efficiencies from the contaminated soil samples. With the combined effect of dissolving oxides and ion exchange under combined washings, the removal efficiencies of heavy metals and As were higher than those of single washings.


2013 ◽  
Vol 77 (2) ◽  
pp. 432-441 ◽  
Author(s):  
Xiaofang Guo ◽  
Zebin Wei ◽  
C. J. Penn ◽  
Tianfen Xu ◽  
Qitang Wu

2011 ◽  
Vol 356-360 ◽  
pp. 1566-1569
Author(s):  
Hui Zhou ◽  
Wei Yang ◽  
Miao Liu ◽  
Shi Liang Li ◽  
Qian Qian Li

The effects of the added EDTA and organic acids (oxalic acid, tartaric acid and acetic acid) on Cd desorption of Zhangshi Irrigation Area (ZIR)contaminated soil of Shenyang city was investigated by batch balance experiments, in which the concentrations of acids, pH and temperature were examined. The results showed that EDTA, oxalic acid, tartaric acid and acetic acid modified the desorption behaviors of Cd. And the desorption level was EDTA>tartaric acid >oxalic acid >acetic acid. Also, the desorption amount of Cd increased with the concentration ranges from 5 to 40mmol/L; the desorbed amount obviously reduced with elevating pH when the pH was below 6; the adsorption was facilitated and the desorption was weakened when the pH was above 6. In addition, the Cd desorption amount raised with the temperature increasing.


2010 ◽  
Vol 178 (1-3) ◽  
pp. 578-587 ◽  
Author(s):  
Weihua Zhang ◽  
Lizhi Tong ◽  
Yuan Yuan ◽  
Zhiyong Liu ◽  
Hao Huang ◽  
...  

2014 ◽  
Vol 955-959 ◽  
pp. 2014-2021 ◽  
Author(s):  
Pei Ya Liu ◽  
Huan Liu ◽  
Yu Jiao Li ◽  
Chang Xun Dong

Arsenic contaminated soil is a serious worldwide problem nowadays, and soil washing technique is one of hottest topics in the area of remediating arsenic contaminated soils, while treatment of the washing effluent is still an urgent problem. In this study, in order to select the best washing extractants for arsenic contaminated soil of the Xiangxi Autonomous Prefecture, nine kinds of extractants (citric acid, oxalic acid, malic acid, tartaric acid, H3PO4, KH2PO4, KOH, NH4Ac and ultra-pure water) were studied. Innovatively, a new material (calcined Mn-Fe Layered double hydroxide) was firstly introduced and fully applied to the adsorption of arsenic washing effluents. Results showed citric acid, oxalic acid and KH2PO4 were the optimal extractants for arsenic contaminated soil, considering the extraction rate and environmental perspective. When the concentrations were 200, 300, 300 mmol/ L , solution soil ratios were 10, 10, 20 mL/g , extraction times were 12,12,12 h, the citric acid, oxalic acid and KH2PO4, respectively, achieved the maximum extraction rate of 39%, 65% and 29%. Calcined Mn-Fe LDH used in this work was characterized by SEM and FT-IR, indicating the unique structure and high phase purity of the synthetic samples. For the 28mg/L arsenic effluent washing by citric acid, calcined Mn-Fe LDH showed the most effective capacity as adsorbent under neutral or weak base condition as well as 2 h absorption time.


Sign in / Sign up

Export Citation Format

Share Document