Effects of EDTA and Organic Acids on Cd Desorption from Zhangshi Irrigation Area Soil

2011 ◽  
Vol 356-360 ◽  
pp. 1566-1569
Author(s):  
Hui Zhou ◽  
Wei Yang ◽  
Miao Liu ◽  
Shi Liang Li ◽  
Qian Qian Li

The effects of the added EDTA and organic acids (oxalic acid, tartaric acid and acetic acid) on Cd desorption of Zhangshi Irrigation Area (ZIR)contaminated soil of Shenyang city was investigated by batch balance experiments, in which the concentrations of acids, pH and temperature were examined. The results showed that EDTA, oxalic acid, tartaric acid and acetic acid modified the desorption behaviors of Cd. And the desorption level was EDTA>tartaric acid >oxalic acid >acetic acid. Also, the desorption amount of Cd increased with the concentration ranges from 5 to 40mmol/L; the desorbed amount obviously reduced with elevating pH when the pH was below 6; the adsorption was facilitated and the desorption was weakened when the pH was above 6. In addition, the Cd desorption amount raised with the temperature increasing.

2011 ◽  
Vol 322 ◽  
pp. 21-24
Author(s):  
Guo Ling Cheng ◽  
Xue Bai ◽  
Qun Hui Wang

Seven kinds of natural organic acids were added to moderate artificial contaminated soil to investigate the effects of natural organic acids on growth of maize seedlings and phytoextraction of copper and lead by maize. The results show that the effects of organic acids on plant growth are different in Cu and Pb contaminated soil. The natural organic acids can change the dry matter distribution of the shoot and the root, oxalic acid and tartaric acid can increase the root biomass in different degrees. Oxalic acid and tartaric acid can significantly increase the concentrations and uptake of Cu and Pb in the shoots of maize, indicate that oxalic acid and tartaric acid are potential phytoextraction intensifiers in phytoremediation of Cu and Pb contaminated soil.


2015 ◽  
Vol 12 (2) ◽  
pp. 340-349
Author(s):  
Baghdad Science Journal

A new reversed phase- high performance liquid chromatographic (RP-HPLC) method with Ultraviolet-Visible spectrophotometry has been optimized and validated for the simultaneous extraction and determination of organic acids present in Iraqi calyces of Hibiscus Sabdraffia Linn. The method is based on using ultrasonic bath for extracting organic acids. Limit of detection in µg/ml of Formic acid, Acetic acid, Oxalic acid, Citric acid, Succinic acid, Tartaric acid, and Malic acid 126.8498×10-6, 113.6005×10-6, 97.0513×10-6, 49.7925×10-6, 84.0753×10-6, 92.6551×10-6, and 106.1633×10-6 ,respectively. The concentration of organic acids found in dry spacemen of calyces of Iraqi Hibiscus Sabdraffia Linn. under study: Formic acid, Acetic acid, Oxalic acid, Citric acid, Succinic acid, Tartaric acid, and Malic acid are 114.896 µg/g, 64.722 µg/g, 342.508 µg/g, 126.902 µg/g, 449.91 µg/g, 268.52 µg/g, and 254.07 µg/g respectively.


2020 ◽  
Vol 4 (Supplement_2) ◽  
pp. 761-761
Author(s):  
Miao Li ◽  
Kai Li ◽  
Hao Song

Abstract Objectives The natural fermentation broth of vegetables and fruits is produced by anaerobic fermentation of vegetables and fruits, so as to form a fermentation beverage with complex components. Some components in the fermentation broth can promote digestion and absorption, alleviate constipation and beautify the face. Fruit and vegetable fermentation can be added into baking products to make natural yeast bread with good flavor and long shelf life. The fermentation broth has broad market application prospects. The contents of organic acids may play an important role in the flavor and nutrition of the natural fermentation broth of vegetables and fruits, which are still under researching. Methods HPLC (High Performance Liquid Chromatography) was used to detect the contents of several kinds of organic acids, such as acetic acid, lactic acid, oxalic acid, citric acid, succinic acid, tartaric acid. Results The contents of acetic acid, lactic acid, oxalic acid, citric acid, succinic acid, tartaric acid in compound natural fermentation broth (grapefruit + apple + lemon) was 5.650 mg/mL, 0.171 mg/mL, 0.013 mg/mL, 0.213 mg/mL, 0.763 mg/mL, 0.628 mg/mL. Conclusions The contents of organic acids were significantly different among different natural fermentation liquors of vegetables and fruits due to different raw materials, formulations and fermentation time. Funding Sources Beijing Yiqing Holding Co., Ltd.


1989 ◽  
Vol 52 (11) ◽  
pp. 771-776 ◽  
Author(s):  
MOUSTAFA A. EL-SHENAWY ◽  
ELMER H. MARTH

Tests were done to determine the fate of Listeria monocytogenes at 13 or 35°C in Tryptose Broth (TB) with and without the pH adjusted to 5.6 or 5.0 using acetic, tartaric, lactic, or citric acid and containing 0.00, 0.05, 0.15, or 0.3% sodium benzoate. The bacterium grew in all controls (free of benzoate) under all conditions except only slight growth was detected at 13°C when the pH was adjusted to 5.0 using acetic or tartaric acid. When TB was acidified with acetic or tartaric acid and incubated at 35°C, the bacterium was inactivated or inhibited under all conditions except growth occurred at pH 5.6 with 0.05 or 0.15% sodium benzoate and at pH 5.0 with 0.05% benzoate. Incubation at 13°C with the same acids in TB was accompanied by inactivation or inhibition of the bacterium at all test conditions except in the presence of 0.05% sodium benzoate and pH 5.6 obtained by added acetic acid, and in the presence of 0.05 or 0.15% benzoate when tartaric acid was used to adjust the pH to 5.6. Acidifying TB with lactic or citric acid and incubating at 35°C resulted in growth at pH 5.0 and 5.6 regardless of concentration of benzoate except 0.3% which caused inhibition or inactivation at pH 5.6 or 5.0, respectively. Incubation at 13°C with the same acids in TB resulted in inactivation or inhibition of L. monocytogenes, except growth occurred at pH 5.6 when the medium contained 0.05 or 0.15% benzoate. Slight growth was observed in the presence of 0.05% benzoate at pH 5.0 when the medium was acidified by lactic or acetic acid.


Plants ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 884
Author(s):  
Shi Li ◽  
Sixiu Le ◽  
Xin Wang ◽  
Jiuyuan Bai ◽  
Rui Wang ◽  
...  

Cadmium (Cd) pollution in soil is becoming increasingly serious due to anthropogenic activities, which not only poses a threat to the ecological environment, but also causes serious damage to human health via the biological chain. Consequently, special concerns should be paid to develop and combine multiple remediation strategies. In this study, different subspecies of oilseed rape, Brassica campestris, Brassica napus and Brassica juncea were applied, combined with three organic acids, acetic acid, oxalic acid and citric acid, in a simulated Cd-contaminated soil. Various physiological and biochemical indexes were monitored in both plant seedling, growth period and mature stage. The results showed that organic acids significantly promoted the growth of Brassica campestris and Brassica juncea under Cd stress. The photosynthesis and antioxidant enzyme activities in Brassica campestris and Brassica juncea were induced at seedling stage, while that in Brassica napus were suppressed and disturbed. The enrichment of Cd in oilseed rape was also obviously increased. Brassica juncea contained relatively high resistance and Cd content in plant but little Cd in seed. Among the three acids, oxalic acids exhibited the most efficient promoting effect on the accumulation of Cd by oilseed rape. Here, a comprehensive study on the combined effects of oilseed rape and organic acids on Cd contaminated soil showed that Brassica juncea and oxalic acid possessed the best effect on phytoremediation of Cd contaminated soil. Our study provides an optimal way of co-utilizing oilseed rape and organic acid in phytoremediation of Cd contaminated soil.


2012 ◽  
Vol 610-613 ◽  
pp. 2405-2409
Author(s):  
Li Mei Sun ◽  
Jiang Wu ◽  
Shuai Qi Meng

The paper presents that soil washing and bioremediation technologies were employed to treat the contaminated soil. Various works were conduced in parallel with each other and th results of the laboratouy studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tests at three concentration levels respectively. The tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Hightest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil samples. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particalarly Mn, decreased as the depth of samping increased. Heterogeneous bacteria and filamentous organism plate counts were conduced to evaluate the growth of the bacteria and filamentous organisms in the soil. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil’s porosity and bioremediating the soil, higher extractions of metals were achieved.


2017 ◽  
pp. 25-33 ◽  
Author(s):  
Elizabeth Quevedo ◽  
Erlinda Dizon ◽  
Florinia Merca

“Batuan” fruit (Garcinia binucao [Blco.] Choisy), an indigenous acidulant grown in the Visayas State University, Baybay City, Leyte was analyzed for its organic acid profile at different stages of maturity for the development of potential food and non-food products. The analysis of organic acid content was done using Reverse Phase-High Performance Liquid Chromatography. Organic acids in the dried, powdered “batuan” fruit samples were extracted with the mobile phase (50mM KH2PO4/ H3PO4, pH2.8). The sample extracts and organic acid standards (oxalic acid, tartaric acid, malic acid, citric acid, fumaric acid, lactic acid, acetic acid, and succinic acid) were injected to RP-HPLC under isocratic elution with the mobile phase at a flow rate of 1.0mL min-1 and using UV-vis detection at 210nm. “Batuan” fruit samples contain oxalic acid, tartaric acid, malic acid, citric acid, fumaric acid, succinic acid, acetic acid, lactic acid, and a few unidentified organic acids. Among the organic acids present, citric acid accumulated the highest in the ripe “batuan” fruit; fumaric acid, the least. Results of this study show that “batuan” fruit could be a good natural source of acidulant for food and non-food applications.


2019 ◽  
Vol 70 (6) ◽  
pp. 2000-2003 ◽  
Author(s):  
Alexandru Cojocaru ◽  
Neculai Munteanu ◽  
Brindusa Alina Petre ◽  
Teodor Stan ◽  
Gabriel Ciprian Teliban ◽  
...  

The aim of the present study was to assess the influence of two varieties of rhubarb (Glanskin�s Perpetual and De Moldova) and two densities, 10.000 and 13.300 pl/ha on the content of macro (K, Ca, P, Mg, Fe and S), micro�elements (Al, Si and Mn), organic acids (tartaric, oxalic, citric, malic and ascorbic) and total production. The content of oxalic acid in the four versions ranged from 2.3 mg/mL juice in the case of Glanskin�s perpetual cultivation, with the density of 13.300 pl/ha at 3.8 mg/mL in the case of the Moldova variety at the same density. The content of tartaric acid varied in wide limits from 1.75 mg/mL juice to 6.5 mg/mL juice. The content of macro-elements varied within wide limits, the report being: Fe ] K ] Mg ]S ] P ] Ca. The largest production was obtained at the variety De Moldova with density of 13.300 pl/ha.


2011 ◽  
Vol 194-196 ◽  
pp. 802-805
Author(s):  
Zhan Sheng Wu ◽  
Xi Fang Sun ◽  
Chun Li

Effects of different bentonite clarificants on the main organic acids contents in wine were investigated during the clarification process. Citric acid (CA) concentration changed slightly during the first day with average elimination ratio (AER) of 0.57%, and tartaric acid (TA), malic acid (MA), lactic acid (LA) and succinic acid (SA) were varied with AER of 12.39%, 9.80%, 7.27% and 6.27%, respectively, while acetic acid (AA) has the biggest AER of 15.42%. The pH and titratable acidity were significantly dependent on the variation of CA and TA. The –OH group in organic acids could be combined with –Si-O or –AlO groups in bentonite surface by hydrogen bond, which could caused the decrease in concentration various organic acids.


Forests ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 203
Author(s):  
Xinrui He ◽  
Ting Wang ◽  
Kejun Wu ◽  
Peng Wang ◽  
Yuancai Qi ◽  
...  

Organic acids are critical as secondary metabolites for plant adaption in a stressful situation. Oxalic acid, tartaric acid, and malic acid can improve plant tolerance under waterlogged conditions. Two prominent woody species (Taxodium distichum-Swamp cypress and Salix matsudana-Chinese willow) have been experiencing long-term winter submergence and summer drought in the Three Gorges Reservoir. The objectives of the present study were to explore the responses of the roots of two woody species during flooding as reflected by root tissue concentrations of organic acids. Potted sample plants were randomly divided into three treatment groups: control, moderate submergence, and deep submergence. The concentrations of oxalic acid, tartaric acid, and malic acid in the main root and lateral roots of the two species were determined at four stages. The results showed that T. distichum and S. matsudana adapted well to the water regimes of the reservoir, with a survival rate of 100% during the experiment period. After experiencing a cycle of submergence and emergence, the height and base diameter of the two species showed increasing trends. Changes in base diameter showed insignificant differences between submergence treatments, and only height was significant under deep submergence. The concentrations of three organic acids in the roots of two species were influenced by winter submergence. After emergence in spring, two species could adjust their organic acid metabolisms to the normal level. Among three organic acids, tartaric acid showed the most sensitive response to water submergence, which deserved more studies in the future. The exotic species, T. distichum, had a more stable metabolism of organic acids to winter flooding. However, the native species, S. matsudana, responded more actively to long-term winter flooding. Both species can be considered in vegetation restoration, but it needs more observations for planting around 165 m above sea level, where winter submergence is more than 200 days.


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