Synthesis of Biodegradable Hydroxy-Functionalized Poly(oligo(ethylene Oxide) Monomethyl Ether Methacrylate) (HO-POEOMA) Polymer by Inverse Miniemulsion ATRP

Radical Polymerization ◽

Monomethyl Ether ◽

Spectroscopic Studies ◽

Chain Structure ◽

Atom Transfer ◽

Inverse Miniemulsion

The biodegradable hydroxy-functionalized poly(oligo(ethylene oxide) monomethyl ether methacrylate) (HO-POEOMA) polymer is synthesized by inverse miniemulsion atom transfer radical polymerization (ATRP). The chain structure and component of such polymer is characterized by spectroscopic studies (1HNMR, IR and GPC).

Supplemental Activator and Reducing Agent Atom Transfer Radical Polymerization of 2-Hydroxyethyl Acrylate from High Molar Mass Poly(ethylene oxide) Macroinitiator in Dilute Solution

Macromolecular Chemistry and Physics ◽

10.1002/macp.201500093 ◽

2015 ◽

Vol 216 (13) ◽

pp. 1405-1414 ◽

Cited By ~ 4

Author(s):

Erwan Nicol ◽

René-Ponce Nzé

Keyword(s):

Ethylene Oxide ◽

Radical Polymerization ◽

Molar Mass ◽

Reducing Agent ◽

Atom Transfer ◽

Dilute Solution ◽

High Molar Mass ◽

Poly Ethylene Oxide ◽

Atom transfer radical polymerization in inverse miniemulsion: A versatile route toward preparation and functionalization of microgels/nanogels for targeted drug delivery applications

Polymer ◽

10.1016/j.polymer.2009.06.045 ◽

2009 ◽

Vol 50 (19) ◽

pp. 4407-4423 ◽

Cited By ~ 100

Author(s):

Jung Kwon Oh ◽

Sidi A. Bencherif ◽

Krzysztof Matyjaszewski

Keyword(s):

Drug Delivery ◽

Radical Polymerization ◽

Targeted Drug Delivery ◽

Atom Transfer ◽

Inverse Miniemulsion ◽

Targeted Drug ◽

Drug Delivery Applications

Preparation of Well-Defined Poly[(ethylene oxide)-block-(sodium 2-acrylamido-2-methyl-1-propane sulfonate)] Diblock Copolymers by Water-Based Atom Transfer Radical Polymerization

Macromolecular Rapid Communications ◽

10.1002/marc.200700758 ◽

2007 ◽

Vol 28 (23) ◽

pp. 2277-2277 ◽

Cited By ~ 1

Author(s):

Dilyana Paneva ◽

Laetitia Mespouille ◽

Nevena Manolova ◽

Philippe Degée ◽

Iliya Rashkov ◽

...

Keyword(s):

Ethylene Oxide ◽

Radical Polymerization ◽

Diblock Copolymers ◽

Atom Transfer ◽

Water Based ◽

Poly Ethylene Oxide ◽

Solvent induced morphologies of poly(methyl methacrylate-b-ethylene oxide-b-methyl methacrylate) triblock copolymers synthesized by atom transfer radical polymerization

Polymer ◽

10.1016/j.polymer.2007.10.009 ◽

2007 ◽

Vol 48 (25) ◽

pp. 7279-7290 ◽

Cited By ~ 24

Author(s):

Daniel J. Siegwart ◽

Wei Wu ◽

Monisha Mandalaywala ◽

Magi Tamir ◽

Traian Sarbu ◽

...

Keyword(s):

Ethylene Oxide ◽

Methyl Methacrylate ◽

Radical Polymerization ◽

Triblock Copolymers ◽

Atom Transfer ◽

Poly Methyl Methacrylate

The study of synthesis of poly(ethylene oxide)-b-poly(N,N-dimethylacrylamide) by atom transfer radical polymerization and self-assembly in selective solvents

nano Online ◽

10.1515/nano.0013.00025 ◽

2016 ◽

Author(s):

Runmiao Yang ◽

Ronghua Shi ◽

Dan Zhou ◽

Yanmei Wang ◽

Yanchun Han

Keyword(s):

Ethylene Oxide ◽

Radical Polymerization ◽

Self Assembly ◽

Atom Transfer ◽

Selective Solvents ◽

Poly Ethylene Oxide ◽

Chloro-telechelic poly(ethylene oxide)s as initiators for the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate

Polymer ◽

10.1016/s0032-3861(98)00551-5 ◽

1999 ◽

Vol 40 (12) ◽

pp. 3555-3563 ◽

Cited By ~ 38

Author(s):

Birte Reining ◽

Helmut Keul ◽

Hartwig Höcker

Keyword(s):

Ethylene Oxide ◽

Methyl Methacrylate ◽

Radical Polymerization ◽

Atom Transfer ◽

Poly Ethylene Oxide ◽

The study of synthesis of poly(ethylene oxide)-b-poly(N,Ndimethylacrylamide) by atom transfer radical polymerization and self-assembly in selective solvents

e-Polymers ◽

10.1515/epoly.2007.7.1.844 ◽

2007 ◽

Vol 7 (1) ◽

Author(s):

Yang Runmiao ◽

Shi Ronghua ◽

Zhou Dan ◽

Wang Yanmei ◽

Han Yanchun

Keyword(s):

Ethylene Oxide ◽

Radical Polymerization ◽

Self Assembly ◽

Copolymer Composition ◽

Atom Transfer ◽

Nmr Studies ◽

Selective Solvents ◽

Poly Ethylene Oxide ◽

AbstractPoly(ethylene oxide)-b-poly(N, N-dimethylacrylamide) (PEO-b-PDMA) was synthesized by successive atom transfer radical polymerization (ATRP) of N,N-dimethylacrylamide (DMA) monomer using PEO-Br macro initiators as initiator, CuBr and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazamacrocyclotetra decane (Me6[14]aneN4) as catalyst and ligand.PEO-Br macroinitiator was synthesized by esterification of PEO with 2-bromoisobutyryl bromide. GPC and 1H NMR studies show that the plot of ln([DMA]0/[DMA]) against the reaction time is linear, and the molecular weight of the resulting PDMA increased linearly with the conversion. Within 3 h, the polymerization can reach almost 60% of conversion. PEO-b-PDMA copolymer with low polydispersity index (Mw/Mn≈1.1) is obtained. Self-assembly of PEO-b-PDMA in selective solvents is also studied. It could self-assemble into micelles in methanol/acetone (1/10, v/v) solution. TEM analyses of the PEO-b- PDMA micelles with narrow size distribution revealed that their size and shape depend much on the copolymer composition.