The Study of CaO-SiO2-B2O3-Al2O3-La2O3 Glass Ceramics as Sealant for Planar Intermediate Temperature Solid Oxide Fuel Cells

2013 ◽  
Vol 750-752 ◽  
pp. 558-561
Author(s):  
Jie Yu ◽  
Jian Jun Yang ◽  
Wen Hui Ma ◽  
Bo Yu ◽  
Rui Li ◽  
...  

CaO-SiO2-B2O3-Al2O3-La2O3 system sealants with different B/Si ratios of 0.38~0.82 were prepared by high-temperature melting method for intermediate temperature solid oxide fuel cell (ITSOFC). The glass transition temperature (Tg) and softening temperature (Ts) of the sealant were analyzed by TG-DSC. The complex phases of the sealants detected by XRD were consistent with the calculation results generally. The resistivity of the sealants tested by electrochemical workstation was above 65 kΩ·cm2, and the wetting angle was also calculated. The prepared sealants basically meet the sealing requirement for ITSOFC.

2013 ◽  
Vol 750-752 ◽  
pp. 562-565
Author(s):  
Biao Qian ◽  
Jian Jun Yang ◽  
Jie Yu ◽  
Wen Hui Ma ◽  
Bo Yu ◽  
...  

The CaO-SiO2-B2O3-Al2O3-La2O3 sealants with different alumina contents were fabricated by high-temperature melting method for intermediate temperature solid oxide fuel cell (ITSOFC). The glass transition temperature (Tg) and crystal temperature (Ts) of the sealant with different alumina content was characterized by TG-DSC. And the composition phase of the sealant was detected by XRD. The resistivity of sealant tested by electrochemical workstation was higher than 22 kΩ·cm2, which met the requirement for ITSOFC. Through the detecting of the wetting angle, the adhesion of sealant and anode materials was very good, and the single cell sealed with alumina tube successfully.


Author(s):  
A. A. Solovyev ◽  
A. V. Shipilova ◽  
I. V. Ionov ◽  
E. A. Smolyanskiy ◽  
A. V. Nikonov ◽  
...  

2021 ◽  
pp. 160444
Author(s):  
S.U. Costilla-Aguilar ◽  
M.I. Pech-Canul ◽  
M.J. Escudero ◽  
R.F. Cienfuegos-Pelaes ◽  
J.A. Aguilar-Martínez

2020 ◽  
Vol 450 ◽  
pp. 227722 ◽  
Author(s):  
Chunming Xu ◽  
Kening Sun ◽  
Xiaoxia Yang ◽  
Minjian Ma ◽  
Rongzheng Ren ◽  
...  

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