Anti-Oxidation Coatings for Steel Billets at High Temperature

2013 ◽  
Vol 791-793 ◽  
pp. 448-451 ◽  
Author(s):  
Ying Xu ◽  
Peng Wang ◽  
Jian Lu
Keyword(s):  
High Temperature ◽  
Oxidation Mechanism ◽  
Resistance Property ◽  
Oxidation Loss

A new kind of anti-oxidation coating for steel billets at high temperature was prepared. The resistance property of the coatings for oxidation was investigated. The result indicated that the coatings could decrease the oxidation loss at 1300¡æ. The anti-oxidation mechanism of the coatings on the surface of steel billets at high temperature was proposed at the same time.

High Temperature Oxidation Mechanism of Ti3SiC2-64vol%SiC Ceramics

2009 ◽  
Vol 24 (4) ◽  
pp. 821-826
Author(s):  
Hui-Yi TANG ◽  
De-Gui ZHU ◽  
Bo LIU ◽  
Hong-Liang SUN
Keyword(s):  
High Temperature ◽  
High Temperature Oxidation ◽  
Oxidation Mechanism ◽  
Temperature Oxidation ◽  
Sic Ceramics

Analysis on Failure of Oxide Layer of T91 High Temperature Superheater Tube

2014 ◽  
Vol 1070-1072 ◽  
pp. 505-511
Author(s):  
Shan Shan Zhang ◽  
Guang Chen ◽  
Chang Ming Li ◽  
Da Hu
Keyword(s):  
High Temperature ◽  
Dissolved Oxygen ◽  
Oxide Layer ◽  
Outer Layer ◽  
Oxidation Mechanism ◽  
Middle Layer ◽  
Compact Structure ◽  
Protective Properties ◽  
Superheater Tube ◽  
Temperature Operating

The reason why the failure protective properties of the oxide layer of T91 high temperature superheater tube were analyzed in this study. The microstructure of the oxide layer of T91 high temperature superheater tube was observed by scanning electron microscope (SEM) and the morphological features of it was also analyzed. The concentrations of alloy elements in the section of internal tube were quantitatively analyzed using Energy Dispersive System (EDS). The results showed that the oxide layer of T91 tube can be divided into three layers: inner layer, middle layer and outer layer. The inner layer was formed by chromium rich oxide with compact structure. The middle layer was made up by porous oxide with loose structure. The outer layer was identified as Fe2O3. When the content of dissolved oxygen in steam was excessive, the apparent peeling marks will be appeared in the oxide layer of T91 high temperature superheater tube and the distribution of alloy elements in the oxide layer will present obvious proliferation, migration and enrichment phenomenon. Two different mechanisms (steam oxidation mechanism and oxygen oxidation mechanism) will exercise different influences on the structure and protective properties of the oxide layer: when steam contained dissolved oxygen, the oxide layer will be peroxidated by steam and the structure of oxide layer will be broken; When the tube was over-temperature operating, the oxide layer will be oxidated by oxygen.

A Stochastic Model of Oxidation Mechanism on High Temperature Corrosion of Stainless Steel

2006 ◽  
Author(s):  
Huajun Chen ◽  
Yitung Chen ◽  
Hsuan-Tsung Hsieh
Keyword(s):  
High Temperature ◽  
Oxide Layer ◽  
Present Model ◽  
Oxidation Mechanism ◽  
High Temperature Corrosion ◽  
Iron Species ◽  
Corrosive Liquid ◽  
Model Mapping ◽  
Wagner Theory

To interpret the role of diffusion and reaction process, a cellular automaton model, which combines the surface growth and internal oxidation, was developed to explain the oxidation mechanism of stainless steels in high temperature corrosive liquid metal environment. In this model, three main processes, which include the corrosion of the substrate, the diffusion of iron species across the oxide layer and precipitation of iron on the oxide layer, are simulated. The diffusion process is simulated by random walk model. Mapping between present model and Wagner theory has been created. The gross features concerning the evolution of the involved process were founded.

Oxidation Mechanism of ZrB2-SiC Tested in a Solar Furnace above 2200°C

2010 ◽  
Vol 65 ◽  
pp. 124-129
Author(s):  
Anne-Sophie Andreani ◽  
Francis Rebillat ◽  
Angéline Poulon-Quintin
Keyword(s):  
High Temperature ◽  
Oxidation Mechanism ◽  
Complex Oxide ◽  
Heating System ◽  
Solar Furnace ◽  
Large Temperature ◽  
Material Surface ◽  
Large Set ◽  
Silica Layer ◽  
The Impact

The solar furnace is a heating system based on concentrated sunrays on the material surface. It is an original method for testing ultra-high-temperature ceramics (UHTC) at very high temperature (above 2200°C) in air with an exposure time of several minutes. In this study, the solar flux is 15.5 MW.m-2 with a homogeneous exposed surface of 10 mm2. A large temperature-time composition parameters space is covered producing a large set of oxidized samples. Massive cylindrical specimens of UHTC materials are prepared by spark plasma sintering at 1900°C under a pressure of 100 MPa for 5 minutes. Then, samples are tested in air from 1750°C up to 2400°C with dwell times varied from 1 to 5 min. During oxidation of ZrB2-SiC (20%vol) material, the formed and known complex oxide scale identified from literature is easily reproduced using this method. It consists of a thin outer silica layer and zirconia columnar layer with a region of SiC depleted zone in ZrB2 phase. The impact of the reduction of Si content is quantified and the coating ZrB2-20%vol SiC is tested as protection on C-C composite.

Microstructural Evolution during High-Temperature Oxidation of Ti2AlN Ceramics

2010 ◽  
Vol 65 ◽  
pp. 106-111
Author(s):  
Bai Cui ◽  
Rafael Sa ◽  
Daniel Doni Jayaseelan ◽  
Fawad Inam ◽  
Michael J. Reece ◽  
...  
Keyword(s):  
High Temperature ◽  
Microstructural Evolution ◽  
High Temperature Oxidation ◽  
Oxidation Mechanism ◽  
X Ray Diffraction ◽  
Temperature Oxidation ◽  
X Ray ◽  
Oxidation In Air ◽  
Α Al2o3 ◽  
Increasing Temperature

Microstructural evolution of Ti2AlN ceramics during high-temperature oxidation in air has been revealed by X-ray diffraction (XRD), field emission gun scanning electron microscopy (FEGSEM), and energy-dispersive spectroscopy (EDS). After oxidation below 1200 °C, layered microstructures formed on Ti2AlN surfaces containing anatase, rutile, and α-Al2O3. Above 1200 °C, more complex layered microstructures formed containing Al2TiO5, rutile, α-Al2O3, and continuous void layers. With increasing temperature, anatase gradually transformed to rutile, and TiO2 reacted with α-Al2O3 to form Al2TiO5. Based on these microstructural observations, an oxidation mechanism for Ti2AlN ceramics is proposed.

S042011 Clarification for the Oxidation mechanism of ZrB_2-SiC-ZrC at the Ultra High Temperature Region

2012 ◽  
Vol 2012 (0) ◽  
pp. _S042011-1-_S042011-4
Author(s):  
Yutaro ARAI ◽  
Yasuo KOGO ◽  
Masashi ISHIKAWA ◽  
Shu-Qi GUO ◽  
Ken GOTO ◽  
...  
Keyword(s):  
High Temperature ◽  
Temperature Region ◽  
Oxidation Mechanism ◽  
High Temperature Region ◽  
Ultra High Temperature
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