Research on Processing Conditions of CBS Transparent Glass-Ceramics

2013 ◽  
Vol 873 ◽  
pp. 733-736
Author(s):  
Yi Min Wang ◽  
Hong Bo Zhang ◽  
Chun Hui Su ◽  
Qin Lei Wei
Keyword(s):  
Heat Treatment ◽  
Luminescence Property ◽  
Room Temperature ◽  
Glass Ceramics ◽  
Nucleating Agent ◽  
Processing Conditions ◽  
Transparent Glass ◽  
Melting Method ◽  
Heat Treatment Regime ◽  
Precursor Glass

On the basis of experimental verification, the optimum processing conditions of CaO-B2O3-SiO2(CBS) system transparent glass-ceramics were obtained. Composition of main raw powders (wt%) was:CaO 38%,SiO240%,B2O312%.The precursor glass was prepared by melting method and annealed at 560°C for 2h and cooled to room temperature at a speed of 5°C/min.The best nucleating agent is P2O5. The appropriate heat treatment regime to precursor glass was determined to be 2h at 600°C for nucleation and 3h at 780°C for crystallizition.Under this condition,the transmittion of glass-ceramics at the range of visable light is 72% in average and Sm3+keep good luminescence property doped in this host material.

Preparation and Characterization of Sm3+ Doped CBS Transparent Glass-Ceramics

2011 ◽  
Vol 418-420 ◽  
pp. 796-799
Author(s):  
Yi Min Wang ◽  
Hong Bo Zhang ◽  
Chun Hui Su ◽  
Dong Dong Fan
Keyword(s):  
Room Temperature ◽  
Glass Ceramics ◽  
Treatment Schedule ◽  
Laser Material ◽  
Transparent Glass ◽  
Melting Method ◽  
Strong Luminescence ◽  
Heat Treatment Schedule ◽  
Precursor Glass

Sm3+ doped transparent glass-ceramics of CaO-B2O3-SiO2 (CBS) system were prepared and characterized.The precursor glass was prepared by melting method and annealed at 450°C for 2h and cooled to room temperature at a speed of 5°C/min.The appropriate heat treatment schedule to precursor glass was determined to be 2h at 600°C for nucleation and 3h at 810°C for crystallizition.The transmittion of glass-ceramics at the range of visable light is 68% in average. Five main emission bands of Sm3+ are centered around 564nm,605nm,646nm,679nm and 789nm,which correspond to the 4G 5/2→6H 5/2,4G 5/2→6H 7/2,4G 5/2→6H 9/2,4G 5/2→6H 11/2 and 4G 5/2→6H 13/2 transitions.Very strong luminescence at around 599nm is observed in glass-ceramics,This indicates glass-ceramics to be a better host for Sm3+ than precursor glass and a hopeful laser material.

Preparation and Characterization of Na2O-Y2O3-P2O5-SiO2 Transparent Glass Ceramics

2018 ◽  
Vol 281 ◽  
pp. 692-698 ◽  
Author(s):  
Meng Jie Zhao ◽  
Xiang Yu Zou ◽  
Qin Lei Wei ◽  
Shuo Meng ◽  
Hong Bo Zhang ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Refractive Index ◽  
Glass Ceramic ◽  
Visible Region ◽  
Glass Ceramics ◽  
Scanning Calorimetry ◽  
Transparent Glass ◽  
Diffraction Patterns ◽  
The Impact ◽  
Precursor Glass

Transparent glass ceramics containing Na3.6Y1.8(PO4)3 crystals were successfully synthesized using high temperature melting quenching and subsequent heat treatment of the precursor glass with a composition 15Na2CO3-3Y2O3-45SiO2-31H3BO3- 5.4P2O5-0.6Sb2O3 (mol%). The impact of heat treatment is investigated in detail. The glass sample was tested by differential scanning calorimetry analysis to determine the heat treatment system. The ideal heat-treated condition is at 650°C for 2 h. The structure and morphology properties were systematically analyzed by recording X-ray diffraction patterns and scanning electron microscopy images, which indicate that Na3.6Y1.8(PO4)3 crystal were precipitated homogeneously among the glass matrix. The microstructural of precursor glass and glass ceramic were compared by analyzing FTIR spectra, indicating the formation of phosphate groups in glass ceramic. The refractive index of glass ceramics samples were measured. In the visible region, the transmittance of glass ceramics is up to 85%. Moreover, the relationship between the refractive index of the sample and the transmittance is discussed.

scholarly journals Optimization of heat treatment of glass-ceramics made from blast furnace slag

2020 ◽  
Vol 39 (1) ◽  
pp. 539-544
Author(s):  
Yi-Ci Wang ◽  
Pei-Jun Liu ◽  
Guo-Ping Luo ◽  
Zhe Liu ◽  
Peng-Fei Cao
Keyword(s):  
Heat Treatment ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Orthogonal Experiment ◽  
Glass Ceramics ◽  
Iron And Steel ◽  
Heat Treatment Regime ◽  
Main Crystalline Phase ◽  
Optimum Heat ◽  
Furnace Slag

AbstractCaO–MgO–Al2O3–SiO2 glass-ceramics with diopside as the main crystalline phase were prepared by melting blast furnace slag obtained from Baotou Iron and Steel Company. The effect of heat treatment on the crystallization behavior of glass-ceramics, containing a large proportion of melted blast furnace slag, was studied by means of differential thermal analysis and scanning electron microscopy. The optimum heat-treatment regime was obtained by orthogonal experimental results for glass-ceramics in which blast furnace slag comprised 70% of the composition and 1% Cr2O3 and 4% TiO2 were used as nucleating agents. The nucleation temperature was 750°C for 2.5 h and the crystallization temperature was 930°C for 1 h. Under this regime, the performance of the glass-ceramic was better than that of other groups in the orthogonal experiment.

Formation of NaNbO3 Crystals in Dielectric Glass and Glass-Ceramics of a Na2O-Nb2O5-Al2O3-SiO2 System

2008 ◽  
Vol 55-57 ◽  
pp. 229-232 ◽  
Author(s):  
S. Thongsaeng ◽  
Anuson Niyompan ◽  
Rungnapa Tipakontitikul ◽  
Kamonpan Pengpat
Keyword(s):  
Heat Treatment ◽  
Treatment Time ◽  
Glass Ceramics ◽  
Glass Production ◽  
Nucleating Agent ◽  
Aluminum Silicate ◽  
Phase Identification ◽  
Dielectric Glass ◽  
Xrd Patterns ◽  
Glass Compositions

Dielectric glass and glass-ceramics were derived from Na2O-Nb2O5-Al2O3-SiO2 system. Small amount of TiO2 were also introduced into glass compositions to study crystallization behavior of the glass with present of this nucleating agent. Conventional melt-quenching technique was employed for a glass production and the selected bulk glass samples were subjected to the heat-treatment process at appropriate temperature. After six different glass compositions were produced, and by observation with necked eyes, all obtained glass samples are in light brown color and some samples were opaque due to crystallization took place during quenching. Phase identification through XRD patterns show that there were 3 phases, NaNbO3, NaNbO8 and a sodium aluminum silicate compound, found in those opaque glass samples. NaNbO3 is a predominant phase in all samples. Fortunately, clear transparent glass was obtained from the composition with no TiO2 addition. Heat treatment of this glass did not induce phase change, three aforementioned phases still present. Increasing heat treatment time promoted a higher of observed intensity of NaNbO3. But the NaNbO3 crystalline size was not significantly developed with time. The dielectric response of the NaNbO3 crystals in the glass-ceramics samples are influenced by presence of other crystalline phases.

Manufacture of the Glass-Ceramics from the Lead-Zinc Tailings by Sintering

2014 ◽  
Vol 955-959 ◽  
pp. 2818-2823
Author(s):  
Xue Lian Ou ◽  
Yan Ping Guo ◽  
Gao Hui Zhong ◽  
Bao Qing Li ◽  
Ying Chen ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Crystalline Phase ◽  
Bending Strength ◽  
Orthogonal Experiment ◽  
Glass Ceramics ◽  
Nucleating Agent ◽  
Weight Losses ◽  
Glass Aggregate ◽  
Lead Zinc ◽  
Crystallization Heat

The glass-ceramics of CaO-Al2O3-SiO2system were prepared by sintering using lead-zinc tailings. Orthogonal experiment was carried out to optimize the ratio of lead-zinc tailings, chemical composition of basic-glass and other chemical materials in the system. Crystallization heat treatment conditions were confirmed by the differential thermal analysis (DTA) curve of glass aggregate. Crystalline phase, crystal morphology and mechanical property of the glass-ceramics samples were studied by means of X-ray diffraction (XRD), scanning electron microscope (SEM), hardness and bending strength test. The results indicated that the optimized ratio of the samples was lead-zinc tailings 25%, quartz 46.63%, calcite 21.05%, Al2O310.19% and nucleating agent TiO21%. The optimized crystallization heat treatment was that basic glass was first heated to 800 °C at 10 °C/min, then 800°C-900 °C at 5 °C/min and held still at 900 °C for 2 h. After that, the basic glass was heated to 1230 °C at 1-1.5 °C/min,held for 1h. At last, the glass-ceramics was obtained after the cooling-down of the system. The main crystalline phase of microcrystal glass-ceramics are diopside. The hardness and bending strength were 9.14 GPa and 213.6 MPa, respectively. The glass-ceramics had excellent chemical durability in acid and alkali solution, with weight losses of 0.17% and 0.68%, respectively.

Study on the Preparation and Properties of Piezoelectric Glass-Ceramic Sr0.5Ba0.5Nb2O6

2013 ◽  
Vol 669 ◽  
pp. 204-207
Author(s):  
Shan Jiang ◽  
Jing Wen Lv ◽  
Tao Zheng
Keyword(s):  
Particle Size ◽  
Glass Ceramic ◽  
Crystalline Phase ◽  
Room Temperature ◽  
Glass Ceramics ◽  
Molar Ratio ◽  
Spectral Transmittance ◽  
Melting Method ◽  
Ceramic Samples ◽  
Analytical Reagents

Series of ferroelectric glass-ceramic samples of Sr0.5Ba0.5Nb2O6 were synthesized by melting method. Firstly, analytical reagents were melted for 30 minutes at 1440°C after being grinded evenly according to a certain molar ratio, then annealed for 10 hours from 550°C to room temperature, finally it was sustained for 4 hours at constant temperature about 700°C. The hardness and transmittance parameters of SBN glass-ceramic were tested. Results indicated the sample had the best property when the amount of Nb2O5 was 10mol%, whose hardness reached 506 kg/mm2, and spectral transmittance was higher than 35% . XRD spectra of this sample indicated this SBN glass-ceramics contained a large number of Sr0.5Ba0.5Nb2O6 crystalline phase and a small amount of Sr0.3Ba0.7Nb2O6 phase. The particle size was about 50 nm.

Impact of heat treatment on the Mn2+ doped transparent glass ceramics containing NaZnPO4 nanocrystals

2017 ◽  
Vol 189 ◽  
pp. 172-175 ◽  
Author(s):  
Bo-Yang Wang ◽  
Rui Zhang ◽  
Wen-Feng Zhu ◽  
Guo-Hua Chen
Keyword(s):  
Heat Treatment ◽  
Glass Ceramics ◽  
Transparent Glass
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