Application of Electronic Nose for Detection of Wine-Aging Methods

2014 ◽  
Vol 875-877 ◽  
pp. 2206-2213 ◽  
Author(s):  
Yang Ji Wei ◽  
Li Li Yang ◽  
Ying Ping Liang ◽  
Jing Ming Li
Keyword(s):  
Electronic Nose ◽  
Principal Components ◽  
Euclidean Distance ◽  
Principal Component ◽  
Red Wines ◽  
Total Contribution ◽  
Distance Correlation ◽  
Linear Discrimination ◽  
Wine Aging

This study reports the application of an electronic nose for the identification and classification of red wines aged three different methods. The signals of the different wines detected by the 10 sensors present in the E-nose are significantly different from each other. The response to the signal generates a typical chemical fingerprint of the volatile compounds present in the wines. Principal Component Analysis can be applied for the dimensionality reduction of the collected signal. Since the total contribution rate of the first three principal components is up to 97.27%, different wines can be distinguished from each other by the three principal components. Euclidean distance, correlation analysis, Mahalanobis distance and linear discrimination analysis can offer 100% accuracy for known samples, and the accuracy rate can reach 88.9% for the 18 test samples. In addition, numerous advantages exist compared with sensory analysis in both authentication and quality control of wines.

scholarly journals Deteksi Formalin Pada Buah Tomat (Lycopersicum esculentum Mill) Dengan Teknologi Hidung Elektronik (Electronic Nose)

2019 ◽  
Vol 4 (2) ◽  
pp. 359-366
Author(s):  
Irfan Maibriadi ◽  
Ratna Ratna ◽  
Agus Arip Munawar
Keyword(s):  
Principal Component Analysis ◽  
Electronic Nose ◽  
Principal Component ◽  
Component Analysis ◽  
Lycopersicum Esculentum ◽  
Olfactory Ability ◽  
Pca Method ◽  
The Difference ◽  
Electronic Nose Technology

Abstrak,  Tujuan dari penelitian ini adalah mendeteksi kandungan dan kadar formalin pada buah tomat dengan menggunakan instrument berbasis teknologi Electronic nose. Penelitian ini menggunakan buah tomat yang telah direndam dengan formalin dengan kadar 0.5%, 1%, 2%, 3%, 4%, dan buah tomat tanpa perendaman dengan formalin (0%). Jumlah sampel yang digunakan pada penelitian ini adalah sebanyak 18 sampel. Pengukuran spektrum beras menggunakan sensor Piezoelectric Tranducer. Klasifikasi data spektrum buah tomat menggunakan metode Principal Component Analysis (PCA) dengan pretreatment nya adalah Gap Reduction. Hasil penelitian ini diperoleh yaitu: Hidung elektronik mulai merespon aroma formalin pada buah tomat pada detik ke-8.14, dan dapat mengklasifikasikan kandungan dan kadar formalin pada buah tomat pada detik ke 25.77. Hidung elektronik yang dikombinasikan dengan metode principal component analysis (PCA) telah berhasil mendeteksikandungan dan kadar formalin pada buah tomat dengan tingkat keberhasilan sebesar 99% (PC-1 sebesar 93% dan PC-2 sebesar 6%). Perbedaan kadar formalin menjadi faktor utama yang menyebabkan Elektronik nose mampu membedakan sampel buah tomat yang diuji, karena semakin tinggi kadar formalin pada buah tomat maka aroma khas dari buah tomat pun semakin menghilang, sehingga Electronic nose yang berbasis kemampuan penciuman dapat membedakannya.Detect Formaldehyde on Tomato (Lycopersicum esculentum Mill) With Electronic Nose TechnologyAbstract, The purpose of this study is to detect the contents and levels of formalin in tomatoes by using instruments based on Electronic nose technology. This study used tomatoes that have been soaked in formalin with a concentration of 0.5%, 1%, 2%, 3%, 4%, 5% and tomatoes without soaking with formalin (0%). The samples in this study were 18 samples. The measurements of the intensity on tomatoes aroma were using Piezoelectric Transducer sensors. The classification of tomato spectrum data was using the Principal Component Analysis (PCA) method with Gap Reduction pretreatment. The results of this study were obtained: the Electronic nose began to respond the smell of formalin on tomatoes at 8.14 seconds, and it could classify the content and formalin levels in tomatoes at 25.77 seconds. Electronic nose combined with the principal component analysis (PCA) method have successfully detected the content and levels of formalin in tomatoes with a success rate at 99% (PC-1 of 93% and PC-2 of 6%). The difference of grade formalin levels is the main factor that causes Electronic nose to be able to distinguish the tomato samples tested, because the higher of formalin content in tomatoes, the distinctive of tomatoes aroma is increasingly disappearing. Thereby, the Electronic nose based on  the olfactory ability can distinguish them. 

scholarly journals Multivariate characterisation of Italian monovarietal red wines using MIR spectroscopy

OENO One ◽  
2019 ◽  
Vol 53 (4) ◽  
Author(s):  
Giuseppina P. Parpinello ◽  
Arianna Ricci ◽  
Panagiotis Arapitsas ◽  
Andrea Curioni ◽  
Luigi Moio ◽  
...  
Keyword(s):  
Principal Component ◽  
Rapid Screening ◽  
Support Vector ◽  
Red Wines ◽  
Grape Variety ◽  
Absorption Bands ◽  
Linear Discriminant ◽  
Mir Spectroscopy ◽  
Grape Varieties

Aim: The aim of this study was to investigate the application of mid-infrared (MIR) spectroscopy combined with multivariate analysis, to provide a rapid screening tool for discriminating among different Italian monovarietal red wines based on the relationship between grape variety and wine composition in particular phenolic compounds.Methods and results: The MIR spectra (from 4000 to 700 cm‒1) of 110 monovarietal Italian red wines, vintage 2016, were collected and evaluated by selected multivariate data analyses, including principal component analysis (PCA), linear discriminant analysis (DA), support vector machine (SVM), and soft intelligent modelling of class analogy (SIMCA). Samples were collected directly from companies across different regions of Italy and included 11 grape varieties: Sangiovese, Nebbiolo, Aglianico, Nerello Mascalese, Primitivo, Raboso, Cannonau, Teroldego, Sagrantino, Montepulciano and Corvina. PCA showed five wavelengths that mainly contributed to the PC1, including a much-closed peak at 1043 cm‒1, which correspond to the C–O stretch absorption bands that are important regions for glycerol, whereas the ethanol peaks at around 1085 cm‒1. The band at 877 cm‒1 are related to the C–C stretching vibration of organic molecules, whereas the asymmetric stretching for C–O in the aromatic –OH group of polyphenols is within spectral regions from 1050 to 1165 cm‒1. In particular, the (1175)–1100–1060 cm‒1 vibrational bands are combination bands, involving C–O stretching and O–H deformation of phenolic rings. The 1166–1168 cm‒1 peak is attributable to in-plane bending deformations of C–H and C–O groups of polyphenols, respectively, for which polymerisation may cause a slight peak shift due to the formation of H-bridges.The best result was obtained with the SVM, which achieved an overall correct classification for up to 72.2% of the training set, and 44.4% for the validation set of wines, respectively. The Sangiovese wines (n=19) were split into two sub-groups (Sang-Romagna, n=12 and Sang-Tuscany, n=7) considering the indeterminacy of its origins, which is disputed between Romagna and Tuscany. Although the classification of three grape varieties was problematic (Nerello Mascalese, Raboso and Primitivo), the remaining wines were almost correctly assigned to their actual classes.Conclusions: MIR spectroscopy coupled with chemometrics represents an interesting approach for the classification of monovarietal Italian red wines, which is important in quality control and authenticity monitoring.Significance and impact of the study: Authenticity is a main issue in winemaking in terms of quality evaluation and adulteration, in particular for origin certified/protected wines, for which the added marketing value is related to the link of grape variety with the area of origin. This study is part of the D-wine project “The diversity of tannins in Italian red wines”.

Raman Analysis Reveals Biochemical Differences in Plasma of Crohn’s Disease Patients

2020 ◽  
Vol 14 (11) ◽  
pp. 1572-1580
Author(s):  
Carlo Morasso ◽  
Marta Truffi ◽  
Renzo Vanna ◽  
Sara Albasini ◽  
Serena Mazzucchelli ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Crohn’S Disease ◽  
Crohn's Disease ◽  
Aromatic Amino Acids ◽  
Principal Component ◽  
Plasma Samples ◽  
Spectra Analysis ◽  
Linear Discrimination ◽  
Β Sheet

Abstract Backgrounds and Aims There is no accurate and reliable circulating biomarker to diagnose Crohn’s disease [CD]. Raman spectroscopy is a relatively new approach that provides information on the biochemical composition of samples in minutes and virtually without any sample preparation. We aimed to test the use of Raman spectroscopy analysis of plasma samples as a potential diagnostic tool for CD. Methods We analysed by Raman spectroscopy dry plasma samples obtained from 77 CD patients [CD] and 45 healthy controls [HC]. In the dataset obtained, we analysed spectra differences between CD and HC, as well as among CD patients with different disease behaviours. We also developed a method, based on principal component analysis followed by a linear discrimination analysis [PCA-LDA], for the automatic classification of individuals based on plasma spectra analysis. Results Compared with HC, the CD spectra were characterised by less intense peaks corresponding to carotenoids [p <10–4] and by more intense peaks corresponding to proteins with β-sheet secondary structure [p <10–4]. Differences were also found on Raman peaks relative to lipids [p = 0.0007] and aromatic amino acids [p <10–4]. The predictive model we developed was able to classify CD and HC subjects with 83.6% accuracy [sensitivity 80.0% and specificity 85.7%] and F1-score of 86.8%. Conclusions Our results indicate that Raman spectroscopy of blood plasma can identify metabolic variations associated with CD and it could be a rapid pre-screening tool to use before further specific evaluation.

scholarly journals Application of Spectroscopic UV-Vis and FT-IR Screening Techniques Coupled with Multivariate Statistical Analysis for Red Wine Authentication: Varietal and Vintage Year Discrimination

Molecules ◽  
2019 ◽  
Vol 24 (22) ◽  
pp. 4166 ◽  
Author(s):  
Elisabeta-Irina Geană ◽  
Corina Teodora Ciucure ◽  
Constantin Apetrei ◽  
Victoria Artem
Keyword(s):  
Discriminant Analysis ◽  
Principal Component ◽  
Total Variance ◽  
Red Wines ◽  
Linear Discriminant ◽  
Vis Spectroscopy ◽  
Ft Ir ◽  
Wine Authentication ◽  
Analytical Approaches

One of the most important issues in the wine sector and prevention of adulterations of wines are discrimination of grape varieties, geographical origin of wine, and year of vintage. In this experimental research study, UV-Vis and FT-IR spectroscopic screening analytical approaches together with chemometric pattern recognition techniques were applied and compared in addressing two wine authentication problems: discrimination of (i) varietal and (ii) year of vintage of red wines produced in the same oenological region. UV-Vis and FT-IR spectra of red wines were registered for all the samples and the principal features related to chemical composition of the samples were identified. Furthermore, for the discrimination and classification of red wines a multivariate data analysis was developed. Spectral UV-Vis and FT-IR data were reduced to a small number of principal components (PCs) using principal component analysis (PCA) and then partial least squares discriminant analysis (PLS-DA) and linear discriminant analysis (LDA) were performed in order to develop qualitative classification and regression models. The first three PCs used to build the models explained 89% of the total variance in the case of UV-Vis data and 98% of the total variance for FR-IR data. PLS-DA results show that acceptable linear regression fits were observed for the varietal classification of wines based on FT-IR data. According to the obtained LDA classification rates, it can be affirmed that UV-Vis spectroscopy works better than FT-IR spectroscopy for the discrimination of red wines according to the grape variety, while classification of wines according to year of vintage was better for the LDA based FT-IR data model. A clear discrimination of aged wines (over six years) was observed. The proposed methodologies can be used as accessible tools for the wine identity assurance without the need for costly and laborious chemical analysis, which makes them more accessible to many laboratories.

scholarly journals Using numerical classification of profiles based on Vis-NIR spectra to distinguish soils from the Piracicaba Region, Brazil

2014 ◽  
Vol 38 (2) ◽  
pp. 372-385 ◽  
Author(s):  
Rodnei Rizzo ◽  
José A. M. Demattê ◽  
Fabrício da Silva Terra
Keyword(s):  
Spectral Data ◽  
Principal Components ◽  
Visual Analysis ◽  
Numerical Technique ◽  
Correlation Coefficients ◽  
Principal Component ◽  
Soil Classification ◽  
Numerical Classification ◽  
Similarity Coefficients

Considering that information from soil reflectance spectra is underutilized in soil classification, this paper aimed to evaluate the relationship of soil physical, chemical properties and their spectra, to identify spectral patterns for soil classes, evaluate the use of numerical classification of profiles combined with spectral data for soil classification. We studied 20 soil profiles from the municipality of Piracicaba, State of São Paulo, Brazil, which were morphologically described and classified up to the 3rd category level of the Brazilian Soil Classification System (SiBCS). Subsequently, soil samples were collected from pedogenetic horizons and subjected to soil particle size and chemical analyses. Their Vis-NIR spectra were measured, followed by principal component analysis. Pearson's linear correlation coefficients were determined among the four principal components and the following soil properties: pH, organic matter, P, K, Ca, Mg, Al, CEC, base saturation, and Al saturation. We also carried out interpretation of the first three principal components and their relationships with soil classes defined by SiBCS. In addition, numerical classification of the profiles based on the OSACA algorithm was performed using spectral data as a basis. We determined the Normalized Mutual Information (NMI) and Uncertainty Coefficient (U). These coefficients represent the similarity between the numerical classification and the soil classes from SiBCS. Pearson's correlation coefficients were significant for the principal components when compared to sand, clay, Al content and soil color. Visual analysis of the principal component scores showed differences in the spectral behavior of the soil classes, mainly among Argissolos and the others soils. The NMI and U similarity coefficients showed values of 0.74 and 0.64, respectively, suggesting good similarity between the numerical and SiBCS classes. For example, numerical classification correctly distinguished Argissolos from Latossolos and Nitossolos. However, this mathematical technique was not able to distinguish Latossolos from Nitossolos Vermelho férricos, but the Cambissolos were well differentiated from other soil classes. The numerical technique proved to be effective and applicable to the soil classification process.

scholarly journals A Comparison of Various Algorithms for Classification of Food Scents Measured with an Ion Mobility Spectrometry

Sensors ◽  
2021 ◽  
Vol 21 (2) ◽  
pp. 361
Author(s):  
Georgy Minaev ◽  
Philipp Müller ◽  
Katri Salminen ◽  
Jussi Rantala ◽  
Veikko Surakka ◽  
...  
Keyword(s):  
Discriminant Analysis ◽  
Euclidean Distance ◽  
Principal Component ◽  
Support Vector ◽  
Quadratic Discriminant Analysis ◽  
Raw Data ◽  
Misclassification Rates ◽  
Hidden Layer ◽  
Storage Times

The present aim was to compare the accuracy of several algorithms in classifying data collected from food scent samples. Measurements using an electronic nose (eNose) can be used for classification of different scents. An eNose was used to measure scent samples from seven food scent sources, both from an open plate and a sealed jar. The k-Nearest Neighbour (k-NN) classifier provides reasonable accuracy under certain conditions and uses traditionally the Euclidean distance for measuring the similarity of samples. Therefore, it was used as a baseline distance metric for the k-NN in this paper. Its classification accuracy was compared with the accuracies of the k-NN with 66 alternative distance metrics. In addition, 18 other classifiers were tested with raw eNose data. For each classifier various parameter settings were tried and compared. Overall, 304 different classifier variations were tested, which differed from each other in at least one parameter value. The results showed that Quadratic Discriminant Analysis, MLPClassifier, C-Support Vector Classification (SVC), and several different single hidden layer Neural Networks yielded lower misclassification rates applied to the raw data than k-NN with Euclidean distance. Both MLP Classifiers and SVC yielded misclassification rates of less than 3% when applied to raw data. Furthermore, when applied both to the raw data and the data preprocessed by principal component analysis that explained at least 95% or 99% of the total variance in the raw data, Quadratic Discriminant Analysis outperformed the other classifiers. The findings of this study can be used for further algorithm development. They can also be used, for example, to improve the estimation of storage times of fruit.

scholarly journals Deteksi Bubuk Kopi Luwak Murni dan Bubuk Kopi Luwak Campuran Dengan Teknologi Hidung Elektronik

2019 ◽  
Vol 4 (3) ◽  
pp. 105-114
Author(s):  
Mubarak Hulda ◽  
Fachruddin Fachruddin ◽  
Agus Arip Munawar
Keyword(s):  
Principal Component Analysis ◽  
Electronic Nose ◽  
Principal Component ◽  
Component Analysis ◽  
Powder Spectrum ◽  
Pca Method ◽  
Coffee Powder ◽  
Electronic Nose Technology ◽  
Spectrum Data

Abstrak. Kopi luwak merupakan kopi yang berasal dari hasil konsumsi hewan luwak (musang) yang  telah mengalami fermentasi di dalam pencernaan luwak selam 12 jam. Kopi luwak merupakan komoditi yang sangat diminati dan bernilai jual tinggi. Tujuan dari penelitian ini untuk membedakan bubuk kopi luwak murni dan bubuk kopi luwak campuran dengan memanfaatkan instrumen berbasis teknologi hidung elektronik (electronic nose). Penelitian ini menggunakan bubuk kopi luwak murni dan bubuk kopi arabika yang dicampurkan dengan perbandingan (50:50, 60:40. 70:30, 80:20 dan 90:10). Jumlah sampel yang digunakan pada penelitian ini adalah sebanyak 10 sampel. Pengukuran intensitas sinyal aroma bubuk kopi menggunakan sensor piezoelectric tranducers. Klasifikasi data spektrum bubuk kopi menggunakan metode Principal Component Analysis (PCA) dengan pretreatment nya adalah Gap Reduction. Hasil penelitian ini diperoleh yaitu: Hidung elektronik mulai merespon aroma bubuk kopi pada detik ke-5.64, dan dapat mengklasifikasikan bubuk kopi pada detik ke 11.09. Hidung elektronik yang dikombinasikan dengan metode principal component analysis (PCA) telah berhasil mendeteksi bubuk kopi luwak murni dan bubuk kopi luwak campuran dengan tingkat keberhasilan sebesar 100% (PC-1 sebesar 100% dan PC-2 sebesar 0%).Deteksi Murni Powder Kopi Luwak dan Campuran Kopi Luwak Bubuk Menggunakan Teknologi Hidung ElektronikAbstract. Civet coffee is coffee that comes from the consumption of civet animals (ferrets) that have undergone fermentation in the digestion of mongoose for 12 hours. Civet coffee is a commodity that is very popular and has a high selling value. The purpose of this study is to distinguish pure civet coffee powder and mixed civet coffee powder by using an instrument based on electronic nose technology. This study used pure civet coffee powder and arabica coffee powder mixed with comparisons (50:50, 60:40. 70:30, 80:20 and 90:10). The number of samples used in this study were 10 samples. The measurement of the intensity of coffee powder’s smell signals using piezoelectric tranducers. The classification of coffee powder spectrum data using the Principal Component Analysis (PCA) method with its pretreatment is Gap Reduction. The results of this study were obtained: The electronic nose starts responding to the smell of coffee powder at 5.85 seconds, and can classify coffee powder in 11.09 seconds. The electronic nose combined with the principal component analysis (PCA) method has succeeded in detecting pure civet coffee powder and mixed Civet coffee powder with a success rate of 100 % (PC-1 of 100% and PC-2 of 0%).     

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