Study on Ginger Extract Performance as Corrosion Inhibitor in Acid and Neutral Environments

2014 ◽  
Vol 896 ◽  
pp. 331-334 ◽  
Author(s):  
Budi Agung Kurniawan ◽  
Andhi Pradana ◽  
Sulistijono ◽  
Sutarsis

Study about organic inhibitor has been performed to analyze effect of ginger extract concentration (Zingiber officinaler) to corrosion characteristic of API 5L grade steel under 3.5% NaCl and 0.1M HCl. Amount of 100 to 500 ppm inhibitor injected into each solution and electrochemistry tests were performed. Ginger extract has been prepared previously with maceration method and tested with FTIR to identify type compound in it. Tafel test result showed that corrosion rate of steel decreased in accordance with the increase of inhibitors concentration. Corrosion rate decreased to 12.13 mpy at 500 ppm inhibitor under NaCl solution, with efficiency 54.79%. While in HCl, corrosion rate showed similar trend, with corrosion rate 8.19 mpy at 500 ppm, with efficiency 81.66%. EIS result showed that impedance increased with the increase of inhibitors concentration, while FTIR result showed that ginger extract inhibitor contain 2-Methoxy-4-propylphenol which is known as antioxidant compound. According to XRD test, Fe2O3 and Fe3O4 compound were identified on steel surface. Ginger extract might worked better in acid environment since it decrease corrosion rate significantly compared to neutral solution.

2020 ◽  
Vol 21 (1) ◽  
pp. 86
Author(s):  
Ramlah Ramlah ◽  
Mohammad Wijaya ◽  
Diana Eka Pratiwi

ABSTRAK Penelitian ini merupakan penelitian eksperimen yang bertujuan untuk mengetahui pengaruh variasi konsentrasi inhibitor ekstrak daun beluntas (Pluchea indica Less.) terhadap laju korosi baja karbon dan karakteristik permukaan baja karbon sebelum dan sesudah direndam dalam media NaCl 3,5% tanpa dan dengan adanya inhibitor. Media korosif NaCl 3,5% direaksikan dengan ekstrak daun beluntas untuk memperlambat proses oksidasi Fe dengan variasi konsentrasi 0 ppm, 500 ppm, 1000 ppm, 1500 ppm dan 2000 ppm dan direndam selama 2, 4 dan 6 hari. Pengukuran laju korosi dilakukan dengan metode Weight loss dan polarisasi potensiodinamik. Karakterisasi baja karbon dilakukan menggunakan instrumen Fourier Transform Infra Red (FT-IR) dan Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS). Metode Weight loss dan polarisasi potensiodinamik menunjukkan nilai laju korosi terkecil pada perendaman selama 6 hari dengan konsentrasi inhibitor 2000 ppm yaitu masing-masing sebesar 1,5451 mmpy dan 1,5514 mmpy dengan efisiensi inhibisi sebesar 91%. Hasil penelitian menunjukkan bahwa semakin besar konsentrasi ekstrak dan semakin lama perendaman maka laju korosi semakin kecil dan efisiensi inhibisi semakin besar. Analisis FT-IR menunjukkan gugus fungsi yang teradsorpsi ke permukaan baja karbon yaitu O-H, C=C dan –CO-. Selain itu pada daerah sidik jari mengindikasikan ikatan Fe-O yang merupakan kompleks antara logam dengan senyawa ekstrak. Hasil analisis SEM-EDS menunjukkan bahwa pada permukaan baja karbon yang direndam dalam larutan NaCl 3,5% tanpa adanya inhibitor terbentuk retakan yang lebih banyak dibandingkan permukaan baja karbon yang direndam dalam larutan NaCl 3,5% dengan adanya ekstrak daun beluntas. Persentase Fe untuk baja karbon yang direndam tanpa adanya inhibitor sebesar 70,88% sedangkan untuk baja karbon yang direndam dengan adanya inhibitor sebesar 77,83%. Kata kunci: Laju Korosi, Baja Karbon, NaCl 3,5%, Inhibitor, Ekstrak Daun Beluntas ABSTRACT This research is an experiment research aimed to determine the effect of variations concentration of beluntas leaf extract on the corrosion rate of carbon steel and characteristics surface before and after immersed in 3,5% NaCl solution without and presence of inhibitors. Corrosive reacted with beluntas leaf extract to slow the process of oxidation Fe with various concentrations of 0 ppm, 500 ppm, 1000 ppm, 1500 ppm and 2000 ppm and immersion 2, 4 and 6 days. Measurement of corrotion rate by weight loss and potentiodynamic polarization method. Characterization of carbon steel used Fourier Transform Infra Red (FTIR) and Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS). Weight loss and potentiodynamic polarization methode showed that the smallest corrosion rate at 6 days immersion with an extract concentration of 2000 ppm, each of 1,5451 mmpy and 1,5514 mmpy with an efficiency of 91%. The results showed that the greater the extract concentration and the longer immersion the smaller the corrosion rate and the greater the eficciency. The fuctional groups adsorbed to the aurface of carbon steel are O-H, C=C and –CO-. Also in the fingerprint area indicate Fe-O bond is a complex between metal and extract compounds. The results of SEM-EDS analysis showed that on the carbon steel surface immersed in 3,5% NaCl solution without inhibitor formed more cracks than carbon steel surface immersed in 3,5% NaCl solution in the presence of beluntas leaf extract. Percentace of Fe for carbon steel immersed without an inhibitor is 70,88% while fore carbon steel immersed in the presence of an inhibitor of 77,83%. Keywords: Corrosion Rate, Carbon Steel, 3,5% NaCl, Inhibitor, Beluntas Leaf Extract


2018 ◽  
Author(s):  
Shaimah Rinda Sari ◽  
Eli Novita Sari ◽  
Yoel Rizky ◽  
Sulistijono ◽  
Yunita Triana

2013 ◽  
Vol 683 ◽  
pp. 396-399
Author(s):  
Zhi Guo Wang ◽  
Zhen Li ◽  
Xiao Yan Liu ◽  
Yi Hua Dou

P110 Steel Flow-induced corrosion Electrochemical Method Abstract. Electrochemical measurements have been used to investigate the flow-induced corrosion behaviors of P110 oil tube in 3.5wt% NaCl solution. The corrosion rates were calculated by linear polarization resistance method and weak polarization method respectively. The results demonstrated that corrosion rate of P110 steel increases sharply with the flow velocity increase when the impact angle is 30°, but it reach the first plateau when the fluid velocity changes from 5.6 m/s to 7.8 m/s and the corrosion rate increases sharply again when the velocity beyond 7.8 m/s. After that, corrosion rate decrease when the velocity is more than 10.0m/s. It is demonstrated that the corrosion rate of steel P110 is controlled by cathode reaction of oxygen diffusion in the 3.5 wt % NaCl solution when the flow velocity is over 10.0m/s.


2020 ◽  
Vol 991 ◽  
pp. 191-197
Author(s):  
Adji Swandito ◽  
Viktor Malau

Corrosion is the main problem in the processing of crude oil containing soap emulsion by using acetic acid based demulsifier. This study aims to analyze corrosion of API 5L Gr B steel pipe in the solution of 90% brine and 10% crude oil with addition of 2000 ppm of acetic acid based demulsifier at various concentration of amine based organic inhibitor. Corrosion testing was conducted using weight loss coupon. SEM and EDS analysis were performed to investigate corroded specimen. The weight loss results indicate that amine based organic inhibitor made the steel resistant to corrosion with an inhibitor effectiveness of up to 96.67% at a concentration of 40 ppm. SEM observation following with EDS analysis identifying the presence of inhibitor and corrosion product protection layer.


1970 ◽  
Vol 25 ◽  
pp. 53-61
Author(s):  
Minu Basnet ◽  
Jagadeesh Bhattarai

The corrosion behavior of the sputter-deposited nanocrystalline W-Cr alloys wasstudied in 0.5 M NaCl and alkaline 1 M NaOH solutions at 25°C, open to air usingimmersion tests and electrochemical measurements. Chromium metal acts synergisticallywith tungsten in enhancing the corrosion resistance of the sputter-deposited W-Cr alloys soas to show higher corrosion resistance than those of alloy-constituting elements in both 0.5M NaCl and 1 M NaOH solutions. In particular, the nanocrystalline W-Cr alloys containing25-91 at% chromium showed about one order of magnitude lower corrosion rates (that is,about 1-2 × 10-3 mm.y-1) than those of tungsten and chromium metals even for prolongedimmersion in 0.5 M NaCl solution at 25°C. On the other hand, the corrosion rate of thesputter-deposited W-Cr alloys containing 25-75 at % chromium was decreased significantlywith increasing chromium content and showed lowest corrosion rates (that is, 1.5-2.0 × 10-3 mm.y-1) after immersed for prolonged immersion in 1 M NaOH solution. The corrosion ratesof these nanocrystalline W-(25-75)Cr alloys are nearly two orders of magnitude lower thanthat of tungsten and more than one order of magnitude lower corrosion rate than that ofsputter-deposited chromium metal in 1 M NaOH solution. The corrosion-resistant of all theexamined sputter-deposited W-Cr alloys in 0.5 M NaCl solution is higher than in alkaline 1M NaOH solution at 25°C. Open circuit potentials of all the examined W-Cr alloys areshifted to more noble direction with increasing the chromium content in the alloys afterimmersion for 72 h in both 0.5 M NaCl and 1 M NaOH solutions at 25°C, open to air.Keywords: Sputter deposition, nanocrystalline W-Cr alloys, corrosion test, electrochemicalmeasurement, NaCl and NaOH solutions.DOI:  10.3126/jncs.v25i0.3300Journal of Nepal Chemical Society Volume 25, 2010 pp 53-61


2009 ◽  
Vol 620-622 ◽  
pp. 153-156 ◽  
Author(s):  
Kyung Chul Park ◽  
Byung Ho Kim ◽  
Jong Jin Jeon ◽  
Yong Ho Park ◽  
Ik Min Park

In the present work, the effect of Sn addition on the corrosion behavior of Mg–5Al–1Zn alloys was investigated. Microstructure, potentiodynamic polarization and immersion tests were carried out in 3.5% NaCl solution of pH 7.2 to estimate the corrosion behavior of AZ51 alloys with and without Sn addition. Mg17Al12 and Mg2Sn phases were mainly precipitated in inter-dendrite structures. With increasing the Sn content, the volume fraction of the Mg2Sn phase was increased and coarsening tendency was observed. The corrosion resistance was increased by Sn addition. Especially, the AZ51-5wt.%Sn alloy characterized the superior corrosion resistance among the four alloys. The Sn is known for a high hydrogen overvoltage and the secondary phases effectively formed the network structure, resulting in a drastically decreasing corrosion rate of AZ51 alloy.


2008 ◽  
Vol 580-582 ◽  
pp. 89-92
Author(s):  
Joon Sik Park ◽  
B.Y. Jung ◽  
Hiroshi Yajima ◽  
Jong Bong Lee

In this study, the effect of thickness on the fracture toughness of the steel plate with the thickness of 80mm has been investigated by the wide plate tensile test and ESSO test. The fracture toughness for crack initiation and propagation was evaluated quantitatively for the full thickness specimen. It was found that EH-36 grade steel with the thickness of 80mmt showed the KIC value of 164kgf/mm1.5 at -145°C. Also, large-scale ESSO test result showed that the steel with the thickness of 80mm had 520kgf/mm1.5 at -10°C. Although it was known that the fracture toughness decreases with the increase of the plate thickness, EH-36 grade steel with the thickness of 80mm had enough values of fracture toughness to prevent the crack initiation and arrest the brittle crack propagation.


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