Electrospinning Carboxymethyl Cellulose Lithium (CMC-Li) Nano Composite Material for High-Rate Lithium-Ion Battery

2014 ◽  
Vol 924 ◽  
pp. 69-72 ◽  
Author(s):  
Lei Qiu ◽  
Zi Qiang Shao ◽  
Ming Long Liu ◽  
Yan Hua Liu

New cellulose derivative CMC-Li was synthesized, and nanometer fiber composite material was applied to lithium-ion battery and coated with AQ by electrospinning. Under the protection of inert gas, modified AQ/ carbon nanofibers (CNF) /Li nanometer composite material was obtained by carbonization in 280OC as lithium battery anode materials for the first time. The morphologies and structure performance of materials were characterized by using IR, SEM, CV and EIS, respectively. Specific capacity was increased to226.4 mAh.g-1after modification for the first discharge at the rate of 2C. Performance of cell with CMC-Li with the high degree of substitution (DS) was superior to that with low DS. Cellulose materials were applied to lithium battery to improve battery performance by electrospinning.

Molecules ◽  
2021 ◽  
Vol 26 (22) ◽  
pp. 6950
Author(s):  
Seokwon Lee ◽  
Seokhun Kwon ◽  
Kangmin Kim ◽  
Hyunil Kang ◽  
Jang Myoun Ko ◽  
...  

Carbon nanowall (CNW) and carbon nanotube (CNT) were prepared as anode materials of lithium-ion batteries. To fabricate a lithium-ion battery, copper (Cu) foil was cleaned using an ultrasonic cleaner in a solvent such as trichloroethylene (TCE) and used as a substrate. CNW and CNT were synthesized on Cu foil using plasma-enhanced chemical vapor deposition (PECVD) and water dispersion, respectively. CNW and CNT were used as anode materials for the lithium-ion battery, while lithium hexafluorophosphate (LiPF6) was used as an electrolyte to fabricate another lithium-ion battery. For the structural analysis of CNW and CNT, field emission scanning electron microscope (FE-SEM) and Raman spectroscopy analysis were performed. The Raman analysis showed that the carbon nanotube in composite material can compensate for the defects of the carbon nanowall. Cyclic voltammetry (CV) was employed for the electrochemical properties of lithium-ion batteries, fabricated by CNW and CNT, respectively. The specific capacity of CNW and CNT were calculated as 62.4 mAh/g and 49.54 mAh/g. The composite material with CNW and CNT having a specific capacity measured at 64.94 mAh/g, delivered the optimal performance.


2017 ◽  
Vol 5 (27) ◽  
pp. 13950-13956 ◽  
Author(s):  
Yanan Xu ◽  
Chang Xu ◽  
Qinyou An ◽  
Qiulong Wei ◽  
Jinzhi Sheng ◽  
...  

Novel NASICON-type carbon-coated LiTi2(PO4)3 microflowers (LTP-F/C) as a hybrid magnesium–lithium-ion battery (MLIB) cathode is presented for the first time.


2021 ◽  
Author(s):  
Ziqiang Yu ◽  
Zhiqiang Zhao ◽  
Tingyue Peng

Lithium ion battery (LIB), advantageous in high specific capacity, long cycling life and eco-friendly, has been widely used in many fields. The dwindling reserves, however, limit the further development. Sharing...


Author(s):  
Nabil Khossossi ◽  
Deobrat Singh ◽  
Amitava Banerjee ◽  
Wei Luo ◽  
Ismail Essaoudi ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1984
Author(s):  
Yu-Hsun Nien ◽  
Chih-Ning Chang ◽  
Pao-Lin Chuang ◽  
Chun-Han Hsu ◽  
Jun-Lun Liao ◽  
...  

In recent years, portable electronic devices have flourished, and the safety of lithium batteries has received increasing attention. In this study, nanofibers were prepared by electrospinning using different ratios of nylon 66/polyacrylonitrile (PAN), and their properties were studied and compared with commercial PP separators. The experimental results show that the addition of PAN in nylon 66/PAN nanofibrous film used as separator of lithium-ion battery can enhance the porosity up to 85%. There is also no significant shrinkage in the shrinkage test, and the thermal dimensional stability is good. When the Li/LiFePO4 lithium battery is prepared by nylon 66/PAN nanofibrous film used as separator, the capacitor can be maintained at 140 mAhg−1 after 20 cycles at 0.1 C, and the coulombic efficiency is still maintained at 99%, which has excellent electrochemical performance.


Nanoscale ◽  
2021 ◽  
Author(s):  
Haimei Li ◽  
Xianglong Li ◽  
Denghui Wang ◽  
Siyuan Zhang ◽  
Wenqiang Xu ◽  
...  

A silicon nanoplate-decorated graphite design is developed for lithium battery anodes via a simple ball milling process. The resultant silicon-graphite electrodes show high cyclic stability with high capacity, superior rate...


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