Synthesis of Dimethyl Carbonate over Activated Carbon Supported Cu Based Catalysts
2014 ◽
Vol 953-954
◽
pp. 1242-1245
Keyword(s):
The supported chloride-free copper based catalyst was prepared by deposition-precipitation method and used to catalyze the direct vapor-phase oxycarbonylation of methanol to dimethyl carbonate (DMC). The effect of reductive agent and copper salt precursor on catalyst structure and catalytic performance were investigated, the catalysts were characterized by XRD, H2-TPR techniques. Using Cu (CH3COO)2 as precursor, glucose as reductive agent, when loading amount was 17.1%, the Cu2O/AC catalyst shows the best performance for DMC synthesis. Under the condition of CO/MeOH/O2=5/11/1, SV=6625h-1, the average STY of DMC in 9 hrs running was 71.96mg/(g·h), and selectivity of DMC was 83.13%.
2003 ◽
Vol 243
(2)
◽
pp. 323-331
◽
Keyword(s):
2015 ◽
Vol 15
(10)
◽
pp. 8330-8335
◽
2021 ◽
2014 ◽
Vol 934
◽
pp. 60-64
◽
Keyword(s):
2014 ◽
Vol 32
(6)
◽
pp. 1011-1016
Keyword(s):
2020 ◽
Vol 18
(5-6)
◽