The Present Situation of Combined SO2/NOX Removal Technology from Flue Gas

2014 ◽  
Vol 955-959 ◽  
pp. 2366-2369
Author(s):  
Yan Zhang ◽  
Hai Wei Xie

The mainly pollutant from coal-fired power plants are SO2 and NOX. Equipments of desulphurization and denitrification step by step are expensive and have a lower efficiency. Comparing with them, Combined Removal of SO2 and NOX technology have great advantages, such as, the simplified complication, better operation property, lower cost and less using area. So Combined Removal of SO2 and NOX in one system become the keystone in the research of cleaning technology .On the base of looking up a lot of references, this paper makes a detailed introduction about Combined Removal of SO2 and NOX technology lately in China and other countries, including the removal principle, the mainly advantages and defects, the present situation and the application of technology. The contrast of economic and technical standard is given .Through analysis, synthesis and comparison of two kinds of technology-Combined Removal of SO2/NOX in boiler and in flue gas, the key of research in future is found out. These contents can reference in improvement and exploiture of technology later.

2019 ◽  
Vol 118 ◽  
pp. 01036
Author(s):  
Xiuru Liu ◽  
Yiqing Sun ◽  
Fangming Xue ◽  
Jingcheng Su ◽  
jiangjiang Qu ◽  
...  

SO3 is one of pollutants in flue gas of coal power plants. It mainly derived from coal combustion in boiler and selective catalytic reduction denitrification system. The content of SO3 in flue gas were influenced by the combustion mode, sulfur content in fuel, composition of denitrification catalyst and fly ash. SO3 and water vapour generated H2SO4 droplets. Sulfate secondary particles in atmosphere could cause haze, acid rain and other disastrous weather. High concentration of SO3 could cause blockage and corrosion and affect the safe operation of the units. The generation mechanism of SO3 was discussed. The latest research progress on control and removal technology of SO3 was summarized. The study in this paper provides a reference for pollutant treatment in coal-fired power plants.


2019 ◽  
Vol 120 ◽  
pp. 03002
Author(s):  
Yang Zhang ◽  
Xiaoying Xin ◽  
Da Hu ◽  
Wentao Zhu ◽  
Yue Zhu

Along with the rapid progress of flue gas ultra-low emission reconstruction in coal-fired power plants in recent years, the stability and reliability problems in the operation of the project have emerged, among which the denitrification problem is the most acute. Given the present situation of the NOx ultra-low emission in coal-fired power plants, several typical problems about stability and reliability have been analyzed and discussed, including flow fields uniformity, low load denitrification, in-line meter accuracy, catalyst life on the basis of extensive and thorough investigation. Relevant guidance and countermeasures are proposed to provide further reference for the following denitrification projects and operations.


TAPPI Journal ◽  
2014 ◽  
Vol 13 (8) ◽  
pp. 65-78 ◽  
Author(s):  
W.B.A. (SANDY) SHARP ◽  
W.J. JIM FREDERICK ◽  
JAMES R. KEISER ◽  
DOUGLAS L. SINGBEIL

The efficiencies of biomass-fueled power plants are much lower than those of coal-fueled plants because they restrict their exit steam temperatures to inhibit fireside corrosion of superheater tubes. However, restricting the temperature of a given mass of steam produced by a biomass boiler decreases the amount of power that can be generated from this steam in the turbine generator. This paper examines the relationship between the temperature of superheated steam produced by a boiler and the quantity of power that it can generate. The thermodynamic basis for this relationship is presented, and the value of the additional power that could be generated by operating with higher superheated steam temperatures is estimated. Calculations are presented for five plants that produce both steam and power. Two are powered by black liquor recovery boilers and three by wood-fired boilers. Steam generation parameters for these plants were supplied by industrial partners. Calculations using thermodynamics-based plant simulation software show that the value of the increased power that could be generated in these units by increasing superheated steam temperatures 100°C above current operating conditions ranges between US$2,410,000 and US$11,180,000 per year. The costs and benefits of achieving higher superheated steam conditions in an individual boiler depend on local plant conditions and the price of power. However, the magnitude of the increased power that can be generated by increasing superheated steam temperatures is so great that it appears to justify the cost of corrosion-mitigation methods such as installing corrosion-resistant materials costing far more than current superheater alloys; redesigning biomassfueled boilers to remove the superheater from the flue gas path; or adding chemicals to remove corrosive constituents from the flue gas. The most economic pathways to higher steam temperatures will very likely involve combinations of these methods. Particularly attractive approaches include installing more corrosion-resistant alloys in the hottest superheater locations, and relocating the superheater from the flue gas path to an externally-fired location or to the loop seal of a circulating fluidized bed boiler.


2013 ◽  
Vol 39 (6) ◽  
pp. 515-534 ◽  
Author(s):  
Chuanwen Zhao ◽  
Xiaoping Chen ◽  
Edward J. Anthony ◽  
Xi Jiang ◽  
Lunbo Duan ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3860
Author(s):  
Mária Hagarová ◽  
Milan Vaško ◽  
Miroslav Pástor ◽  
Gabriela Baranová ◽  
Miloš Matvija

Corrosion of boiler tubes remains an operational and economic limitation in municipal waste power plants. The understanding of the nature, mechanism, and related factors can help reduce the degradation process caused by corrosion. The chlorine content in the fuel has a significant effect on the production of gaseous components (e.g., HCl) and condensed phases on the chloride base. This study aimed to analyze the effects of flue gases on the outer surface and saturated steam on the inner surface of the evaporator tube. The influence of gaseous chlorides and sulfates or their deposits on the course and intensity of corrosion was observed. The salt melts reacted with the steel surface facing the flue gas flow and increased the thickness of the oxide layer up to a maximum of 30 mm. On the surface not facing the flue gas flow, they disrupted the corrosive layer, reduced its adhesion, and exposed the metal surface. Beneath the massive deposits, a local overheating of the inner surface of the evaporator tubes occurred, which resulted in the release of the protective magnetite layer from the surface. Ash deposits reduce the boiler’s thermal efficiency because they act as a thermal resistor for heat transfer between the flue gases and the working medium in the pipes. The effect of insufficient feedwater treatment was evinced in the presence of mineral salts in the corrosion layer on the inner surface of the tube.


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