Manganese Oxide Photodeposited onto Titanium Dioxide as a New Environmental Catalyst

2005 ◽  
Vol 480-481 ◽  
pp. 117-122 ◽  
Author(s):  
Ayumu Tateoka ◽  
Yoshika Sekine ◽  
Takamasa Tsuda ◽  
Takanobu Ohashi
Keyword(s):  
Carbon Dioxide ◽  
Titanium Dioxide ◽  
Manganese Oxide ◽  
Organic Compounds ◽  
Uv Irradiation ◽  
Room Temperature ◽  
Complex Oxide ◽  
Environmental Catalysis ◽  
Environmental Catalyst ◽  
Formaldehyde In Air

Authors have successfully synthesized a new environmental catalysis which reacted with harmful formaldehyde in air at room temperature. Although manganese oxide is practically used for a major ingredient of formaldehyde removing materials, intermediates such as formate formed on the surface reduced the removal efficiency. Then, manganese oxide was photodeposited onto the surface of titanium dioxide particles which could decompose certain organic compounds with UV irradiation. It was confirmed that the complex oxide decomposed formaldehyde into carbon dioxide at room temperature. Moreover, UV irradiation enhanced the production of the carbon dioxide.

Creation of 3-dimensional carbon nanostructures from UV irradiation of carbon dioxide at room temperature

2012 ◽  
Vol 72 ◽  
pp. 1-6
Author(s):  
Ortrud Aschenbrenner ◽  
Takahiro Fukuda ◽  
Takashi Hasumura ◽  
Toru Maekawa ◽  
Vladimir M. Gun’ko ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Uv Irradiation ◽  
Carbon Nanostructures ◽  
Room Temperature ◽  
3 Dimensional

The Study of Photoreversibility, Photopolimerization and Photocleavage Properties of Polyurethane Coumarin by Means of Electronic Spectrometry and AFM Methods

2017 ◽  
Vol 68 (7) ◽  
pp. 1632-1635
Author(s):  
Silviu Gurlui ◽  
Emil Buruiana ◽  
Ioan Gabriel Sandu ◽  
Mitachi Strat
Keyword(s):  
Uv Irradiation ◽  
Room Temperature ◽  
Dimethyl Formamide ◽  
Photon Excitation ◽  
Photochemical Properties ◽  
Film State

The spectroscopic and photochemical properties of polyurethane coumarin (PUC) in dimethyl sulf-oxide (DMSO), thetra hydro furan (THF), dimethyl formamide (DMF) and film state were investigated at room temperature under one photon excitation. The results show that under irradiation of l ] 310 nm photodimerization process are increased and under UV irradiation with l[ 260 nm, photocleavage of polymer have been evidenced, too.

scholarly journals Conversion of Methanol on Rutile TiO2 (110) and Tungsten Oxide Clusters: 2. The Role of Defects and Electron Transfer in Bifunctional Oxidic Photocatalysts

2021 ◽  
Author(s):  
Lars Mohrhusen ◽  
Jessica Kräuter ◽  
Katharina Al-Shamery
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Metal Oxide ◽  
Tungsten Oxide ◽  
Organic Compounds ◽  
Uv Irradiation ◽  
Organic P ◽  
Rutile Tio2 ◽  
Metal Oxide Surfaces

The photochemical conversion of organic compounds on tailored transition metal oxide surfaces by (UV) irradiation has found wide applications ranging from the production of chemicals to the degradation of organic...

scholarly journals Properties of Silicone Rubber-Based Composites Reinforced with Few-Layer Graphene and Iron Oxide or Titanium Dioxide

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1550
Author(s):  
Vineet Kumar ◽  
Anuj Kumar ◽  
Minseok Song ◽  
Dong-Joo Lee ◽  
Sung-Soo Han ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Titanium Dioxide ◽  
Iron Oxide ◽  
Stress Relaxation ◽  
Silicone Rubber ◽  
Room Temperature ◽  
Relaxation Rates ◽  
Layer Graphene ◽  
Few Layer Graphene ◽  
Mechanical Actuation

The increasing demand for polymer composites with novel or improved properties requires novel fillers. To meet the challenges posed, nanofillers such as graphene, carbon nanotubes, and titanium dioxide (TiO2) have been used. In the present work, few-layer graphene (FLG) and iron oxide (Fe3O4) or TiO2 were used as fillers in a room-temperature-vulcanized (RTV) silicone rubber (SR) matrix. Composites were prepared by mixing RTV-SR with nanofillers and then kept for vulcanization at room temperature for 24 h. The RTV-SR composites obtained were characterized with respect to their mechanical, actuation, and magnetic properties. Fourier-transform infrared spectroscopy (FTIR) analysis was performed to investigate the composite raw materials and finished composites, and X-ray photoelectron spectroscopy (XPS) analysis was used to study composite surface elemental compositions. Results showed that mechanical properties were improved by adding fillers, and actuation displacements were dependent on the type of nanofiller used and the applied voltage. Magnetic stress-relaxation also increased with filler amount and stress-relaxation rates decreased when a magnetic field was applied parallel to the deformation axes. Thus, this study showed that the inclusion of iron oxide (Fe3O4) or TiO2 fillers in RTV-SR improves mechanical, actuation, and magnetic properties.

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