Kinetics-Controllable Hetero-Precipitation Process on the Nanoscale Solid-Liquid Interface of Spherical Particles

2011 ◽  
Vol 688 ◽  
pp. 45-50
Author(s):  
Xiao Feng Wu ◽  
Yu Chao Liao ◽  
Ren Liang Yue ◽  
Yun Fa Chen
Keyword(s):  
Shell Thickness ◽  
Spherical Particles ◽  
Composite Particles ◽  
Precipitation Process ◽  
Square Root ◽  
Initial Concentration ◽  
First Order ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

Based on the growth kinetics of the SiO2particles, we studied the kinetic hetero-precipitation process on the interface of polystyrene (PS) microscale particles. The nanoscale SiO2shell thickness increased with increasing time and was proportional to the square root of the initial concentration of TEOS precursor while governed by hetero-precipitation process. Moreover, the hetero-precipitation process followed the first-order growth mechanism of silica onto the surface of templating PS pariticles. Properly controlling the reagent concentrations could alleviate and even avoid, to a certain extent, aggregation among PS@SiO2particles that could otherwise have an adverse effect on the properties and applications of those composite particles and the corresponding SiO2hollow products.

An Organodiselenide Containing Electrolyte Enables Sulfurized Polyacrylonitrile Cathodes with Fast Redox Kinetics in Li-S batteries

2021 ◽  
Author(s):  
Wei Zhang ◽  
Qiang Wu ◽  
Ziqi Zeng ◽  
Chuang Yu ◽  
Shijie Cheng ◽  
...  
Keyword(s):  
Liquid Interface ◽  
Electrolyte Additive ◽  
Redox Kinetics ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

A soluble organoselenide compound, phenyl diselenide (PDSe), is employed as a soluble electrolyte additive to enhance the kinetics of sulfurized polyacrylonitrile cathode, in which radical exchange in the solid-liquid interface...

Experimental Investigation of Fluid Flow and Phase Moving Interface During the Solidification of Binary Mixture in Trapezoidal Cavity

Volume 3 ◽  
2004 ◽  
Author(s):  
C. Ghenai ◽  
R. K. Duggirala ◽  
C. X. Lin ◽  
M. A. Ebadian
Keyword(s):  
Ammonium Chloride ◽  
Binary Solution ◽  
Solidification Process ◽  
Convection Flow ◽  
Initial Concentration ◽  
Moving Interface ◽  
Image Velocimetry ◽  
Convection Patterns ◽  
Solid Liquid Interface ◽  
Solid Liquid

This experimental study focuses on the solidification of a ammonium chloride-water (NH4Cl-H2O) solution in a trapezoidal cavity with one and two vertical cooling walls. The effect of the initial concentration of ammonium chloride (sub-eutectic: f < 19.8% and eutectic f = 19.8%, where f is the percentage in weight) and boundary temperatures (Tcold = −30°C to −10°C) on the solidification process is examined. Particle Image Velocimetry (PIV) is used in this study to measure the velocity fields in the melt during the solidification process. The temperatures distributions at discrete locations in the solution and the boundary walls were measured by 32 thermocouples. The convection flow patterns; the ice shape and thickness; the velocity of the moving liquid/solid interface; and the temperature distribution were obtained. The convection patterns obtained for different initial concentrations showed significant differences. The results showed that the process of solidification is slower with an increase in the initial concentration levels of the binary solution. The growth rate of the frozen layer, the velocity of the moving solid-liquid interface and the temperature in the melt was significantly reduced when increasing the initial concentration of ammonium chloride.

Adsorption Kinetics of Grape Seed Procyanidins on Macroporous Adsorbent Resin

2011 ◽  
Vol 396-398 ◽  
pp. 592-595 ◽  
Author(s):  
Ying Hua Song
Keyword(s):  
Adsorption Kinetics ◽  
Adsorption Process ◽  
Grape Seed ◽  
Macroporous Resin ◽  
Initial Concentration ◽  
Adsorption Mechanisms ◽  
First Order ◽  
Intra Particle Diffusion ◽  
Effects Of Temperature ◽  
Kinetics Of

Experiments were carried out to study the adsorption kinetics of grape seed procyanidins onto macroporous resin HZ818 from aqueous solutions.The effects of temperature,initial concentration and agitation on the adsorption kinetics have been investigated.Both the Lagergren-first-order equation and intra-particular diffusion model were used to describe the adsorption mechanisms. And the adsorption process were affected both by film diffusion and by intra-particle diffusion.The intra-particle diffusion rate constants increase with an increase in temperature,initial concentration and agitation speed.

scholarly journals Hydrolysis and Photolysis Kinetics, and Identification of Degradation Products of the Novel Bactericide 2-(4-Fluorobenzyl)-5-(Methylsulfonyl)-1,3,4-Oxadiazole in Water

2018 ◽  
Vol 15 (12) ◽  
pp. 2741 ◽  
Author(s):  
Xingang Meng ◽  
Lingzhu Chen ◽  
Yuping Zhang ◽  
Deyu Hu ◽  
Baoan Song
Keyword(s):  
Degradation Product ◽  
High Performance ◽  
Degradation Products ◽  
Degradation Mechanism ◽  
The Novel ◽  
Initial Concentration ◽  
First Order ◽  
First Order Kinetics ◽  
Kinetics Of ◽  
High Resolution Mass Spectrometer

Hydrolysis and photolysis kinetics of Fubianezuofeng (FBEZF) in water were investigated in detail. The hydrolysis half-lives of FBEZF depending on pH, initial concentration, and temperature were (14.44 d at pH = 5; 1.60 d at pH = 7), (36.48 h at 1.0 mg L−1; 38.51 h at 5.0 mg L−1; and 31.51 h at 10.0 mg L−1), and (77.02 h at 15 °C; 38.51 h at 25 °C; 19.80 h at 35 °C; and 3.00 h at 45 °C), respectively. The photolysis half-life of FBEZF in different initial concentrations were 8.77 h at 1.0 mg L−1, 8.35 h at 5.0 mg L−1, and 8.66 h at 10.0 mg L−1, respectively. Results indicated that the degradation of FBEZF followed first-order kinetics, as the initial concentration of FBEZF only had a slight effect on the UV irradiation effects, and the increase in pH and temperature can substantially accelerate the degradation. The hydrolysis Ea of FBEZF was 49.90 kJ mol−1, which indicates that FBEZF belongs to medium hydrolysis. In addition, the degradation products were identified using ultra-high-performance liquid chromatography coupled with an Orbitrap high-resolution mass spectrometer. One degradation product was extracted and further analyzed by 1H-NMR, 13C-NMR, 19F-NMR, and MS. The degradation product was identified as 2-(4-fluorobenazyl)-5-methoxy-1,3,4-oxadiazole, therefore a degradation mechanism of FBEZF in water was proposed. The research on FBEZF can be helpful for its safety assessment and increase the understanding of FBEZF in water environments.

THE KINETICS OF THE INHIBITED AUTOXIDATION OF TETRALIN

1964 ◽  
Vol 42 (10) ◽  
pp. 2324-2333 ◽  
Author(s):  
J. A. Howard ◽  
K. U. Ingold
Keyword(s):  
Isotope Effect ◽  
Chain Transfer ◽  
Square Root ◽  
Deuterium Isotope Effect ◽  
First Order ◽  
Oxidation Rates ◽  
First Order Kinetics ◽  
A Value ◽  
Root Relation ◽  
Kinetics Of

The kinetics of the inhibition of the autoxidation of tetralin by 2,6-di-t-butyl-4-methylphenol, phenol, and 4-methoxyphenol have been investigated at 65 °C. The highly hindered 2,6-di-t-butyl-4-methylphenol follows simple first order kinetics and exhibits a normal deuterium isotope effect (kH/kD = 10). The kinetics with phenol are complicated by the fact that the phenoxy radical can abstract a hydrogen atom from both tetralin and its hydroperoxide. This leads to oxidation rates which are inversely proportional to the square root of the phenol concentration. The deuterium isotope effect has about the value to be expected in view of this square root relation. The kinetics with 4-methoxyphenol result from chain transfer and from chain termination by the coupling of 4-methoxyphenoxy radicals. The isotope effect varies between zero and a value that approaches the upper limit of about 10 at low inhibitor concentrations.

Effect of solute on the growth rate and the constitutional undercooling ahead of the advancing interface during solidification of an alloy and the implications for nucleation

2006 ◽  
Vol 21 (10) ◽  
pp. 2470-2479 ◽  
Author(s):  
X. Yao ◽  
A.K. Dahle ◽  
C.J. Davidson ◽  
D.H. StJohn
Keyword(s):  
Growth Rate ◽  
Driving Force ◽  
Supercooled Liquid ◽  
Solute Concentration ◽  
Constitutional Undercooling ◽  
Initial Concentration ◽  
Cu Alloys ◽  
Effects Of Temperature ◽  
Solid Liquid Interface ◽  
Solid Liquid

A framework is presented for modeling the nucleation in the constitutionally supercooled liquid ahead of the advancing solid/liquid interface. The effects of temperature gradient, imposed velocity, slope of liquidus, and initial concentration have been taken into account in this model by considering the effect of interface retardation, which is caused by solute buildup at the interface. Furthermore, the effect of solute concentration on the chemical driving force for nucleation has been considered in this model. The model is used for describing the nucleation of Al–Si and Al–Cu alloys. It was found that the solute of Si has a significant impact on the chemical driving force for nucleation in Al–Si alloys whereas Cu has almost no effect in Al–Cu alloys.

Adsorption Kinetics of Polyvinyl Acetate Adsorbed at the Solid-Liquid Interface

1991 ◽  
Vol 248 ◽  
Author(s):  
H. Terashima ◽  
K. Kanehashi ◽  
N. Imai
Keyword(s):  
Slow Rate ◽  
Polyvinyl Acetate ◽  
Adsorption Equilibrium ◽  
Initial Rate ◽  
Unit Area ◽  
Liquid Interface ◽  
Kinetics Of Adsorption ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

AbstractThe kinetics of adsorption of polyvinyl acetate at the solid-liquid interface has been studied to verify the correctness of a description in a paper [Peterson and Kwel, J.Phys.Chem. 65, 1330(1961)] : “the initial rate of adsorption of polyvinyl acetate was found to be rapid”. This is inconsistent with the widely accepted knowledge that polymer adsorption is a slow process. Polyvinyl acetate (Mw = 124,800) was adsorbed from benzene (0.001 to 0.05 mg ml−1) onto mica at 295.5 K. The adsorbed amount per unit area i.e. adsorbance has been determined as a function of incubation time using an ultramicrobalance [Mettler UM3]. The results obtained show that the adsorbance rises rapidly at the beginning of adsorption and then reaches an apparent plateau, where the adsorbance still increases at negligibly slow rate in comparison with the initial rate. The Peterson and Kwei's results have been confirmed to be correct. We regarded the plateau as an adsorption equilibrium and constructed adsorption isotherms, in which the Peterson and Kwei's results were incorporated. These isotherms are found to be less dependent on concentration in the dilute region concerned. This dependency is in agreement with the prediction of the Scheutjens and Fleer theory based on the loop-train-tail model.

Sign in / Sign up

Export Citation Format

Share Document