The Effect of Aluminium and Nickel on some Spectral Lines of Alkaline-Earth Metals in the Course of ICP-AES Analysis

2013 ◽  
Vol 752 ◽  
pp. 259-267
Author(s):  
Olivér Bánhidi
Keyword(s):  
Alkaline Earth ◽  
Earth Element ◽  
Alkaline Earth Metals ◽  
Spectral Lines ◽  
Wide Concentration Range ◽  
Special Effect ◽  
Low Concentration ◽  
Alkaline Earth Element ◽  
Sharp Difference ◽  
Significant Difference

In this paper a special effect of aluminium and nickel on the spectral lines of alkaline-earth metals being present in low concentration was studied. During the study a sharp difference could be obtained in the behaviour of atomic and ionic lines, therefore among the lines investigated both atomic and ionic ones were included. The effect of Ni and Al was investigated in a wide concentration range in case of Be, Mg, Ca and Sr. In case of each of the four alkaline-earth element a significant difference in the depression of the signal could be observed with increasing Al or Ni concentration among atomic and ion lines.

scholarly journals Thermodynamic Stability Areas of Polyvanadates of Alkaline Earth Metals

2019 ◽  
Vol 2019 ◽  
pp. 1-6 ◽  
Author(s):  
Igor Povar ◽  
Inga Zinicovscaia ◽  
Oxana Spinu ◽  
Boris Pintilie
Keyword(s):  
Thermodynamic Stability ◽  
Metal Ion ◽  
Alkaline Earth ◽  
Heterogeneous Systems ◽  
Earth Metal ◽  
Thermodynamic Characteristics ◽  
Alkaline Earth Metals ◽  
Alkaline Earth Metal ◽  
Solution Ph ◽  
Alkaline Earth Element

A thermodynamic method of the global Gibbs energy variation calculation for describing heterogeneous equilibria of transformations of calcium, strontium, and barium polyvanadates, that occur in systems MeO-V2O5-H2O, where Me is the alkaline earth element, has been developed and used. Its quintessence consists in the thermodynamic analysis of the real conditions of various processes on the basis of their total thermodynamic characteristics. On the basis of the selected thermodynamic data for involved species, the thermodynamic stability areas of solid polyvanadates towards the solution pH and vanadium and alkaline earth metal ion concentrations in heterogeneous mixtures have been established, taking into account the complex formation reactions in multicomponent heterogeneous systems. The existing experimental data confirm the results on the thermodynamic stability of polyvanadates obtained in this paper.

Exploring Ni(Mn1/3Cr2/3)2O4 spinel-based electrodes for solid oxide cells

2020 ◽  
Vol 8 (7) ◽  
pp. 3988-3998 ◽  
Author(s):  
Nanqi Duan ◽  
Minrui Gao ◽  
Bin Hua ◽  
Meng Li ◽  
Bo Chi ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Alkaline Earth ◽  
Earth Element ◽  
Solid Oxide ◽  
Electrolysis Cell ◽  
Oxide Fuel ◽  
Composite Electrodes ◽  
Oxygen Ion ◽  
Alkaline Earth Element ◽  
Solid Oxide Electrolysis Cell

The alkaline earth element- and cobalt-free Ni(Mn1/3Cr2/3)2O4 spinel is used to form composite electrodes with an oxygen ion conductive phase for symmetrical solid oxide cells, and applied successfully in both solid oxide fuel cell and solid oxide electrolysis cell modes.

Structural diversity of volatile mixed ligand complexes of alkaline earth element hexafluoroacetylacetonates with triglyme and related polyglymes

Polyhedron ◽  
2017 ◽  
Vol 134 ◽  
pp. 246-256 ◽  
Author(s):  
Dmitry M. Tsymbarenko ◽  
Artem M. Makarevich ◽  
Alexander E. Shchukin ◽  
Irina P. Malkerova ◽  
Andrey S. Alikhanyan ◽  
...  
Keyword(s):  
Alkaline Earth ◽  
Earth Element ◽  
Structural Diversity ◽  
Mixed Ligand ◽  
Mixed Ligand Complexes ◽  
Alkaline Earth Element
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