Multifunctionalities of Nanocarbon Materials Filled Cement-Based Composites

2014 ◽  
Vol 809-810 ◽  
pp. 144-154
Author(s):  
Li Qing Zhang ◽  
Su Fen Dong ◽  
Yun Yang Wang ◽  
Bao Guo Han

Materials combined with a small amount of nanomaterials offer new possibilities in developing of multifunctional composites. Nanocarbon materials (NCMs) such as carbon nanotubes/ nanofibres, and nanographite platelets have excellent intrinsic physical properties and improvement effect to matrix materials at nanoscale. They are promising fillers for improving the mechanical property and durability of cement-based materials and introducing functional properties to cement-based materials. This paper presents a comprehensive introduction about multifuntionlities of NCMs filled cement-based composites including mechanical properties, durability, electrical properties, thermal properties, electromagnetic properties, sensing property and etc.

2013 ◽  
Vol 86 (3) ◽  
pp. 423-448 ◽  
Author(s):  
Liliane Bokobza

ABSTRACT The reinforcement of elastomeric materials by addition of mineral fillers represents one of the most important aspects in the field of rubber science and technology. The improvement in mechanical properties arises from hydrodynamic effects depending mainly on the amount of filler and the aspect ratio of the particles and also on polymer–filler interactions depending on the surface characteristics of the filler particles and the chemical nature of the polymer. The past few years have seen the extensive use of nanometer-scale particles of different morphologies on account of the small size of the filler and the corresponding increase in the surface area that allow a considerable increase in mechanical properties even at very low filler loading. Among these nanoparticles, spherical particles (such as silica or titania) generated in situ by the sol-gel process and carbon nanotubes are typical examples of materials used as a nanosize reinforcing additive. Specific features of filled elastomers are discussed through the existing literature and through results of the author's research based on poly(dimethylsiloxane) filled with spherical silica or titania particles and on styrene–butadiene rubber filled with multiwall carbon nanotubes. The reinforcing ability of each type of filler is discussed in terms of morphology, state of dispersion (investigated by transmission electron microscopy, atomic force microscopy, small-angle neutron scattering), and mechanical and electrical properties. In addition, the use of molecular spectroscopies provides valuable information on the polymer–filler interface. Spherical silica and titania spherical particles are shown to exhibit two distinct morphologies, two different polymer–filler interfaces that influence the mechanical properties of the resulting materials. The superiority of carbon nanotubes over carbon black for mechanical reinforcement and electrical conduction is mainly attributed to their large aspect ratio rather than to strong polymer–filler interactions. The use of hybrid fillers (carbon nanotubes in addition to carbon black or silica, for example) has been shown to give promising results by promoting an enhancement of mechanical and electrical properties with regard to each single filler.


2008 ◽  
Vol 32 ◽  
pp. 9-12
Author(s):  
Shirley Zhiqi Shen ◽  
Stuart Bateman ◽  
Qiang Yuan ◽  
Mel Dell'Olio ◽  
Januar Gotama ◽  
...  

This paper presents the effects of incorporating carbon nanotubes (CNT) into nylon 6 on thermal properties and fire performance of woven glass reinforced CNT/nylon 6 nanocomposite laminates. Incorporation of CNT in nylon 6 improved the thermal stabilities, thermal conductivity and fire performance of laminates without compromising their mechanical properties. The thermal conductivity of laminates with 2 wt% CNT increased up to 42% compared to that without CNT. The ignition time and peak HRR time was delayed approx. 31% and 118%, respectively, in laminates with 4 wt% CNT in nylon 6 over that without CNT.


2011 ◽  
Vol 299-300 ◽  
pp. 802-805
Author(s):  
Jing Long Gao ◽  
Yan Hui Liu

In this work, the carbon nanotubes(CNTs) were reinforced with polypropylene(PP)matrix resins to improve the electrical and thermal properties of PP/ CNTs composites in different contents of 0,1, 3,and 5 wt.%. The surface, volume resistivity and crystallization type of the composites were investigated. As a result, the maximum degradation rate temperature of the composite is improved 30 °C, the surface resistivity and volume resistivity of composite are 5 ×106, 7 ×105,respectively, for the optimum composition of composite (CNTs 3 wt.%). The integrated XRD pattern of the composites shows the typical α-form PP crystals.


2013 ◽  
Vol 643 ◽  
pp. 37-42 ◽  
Author(s):  
Jiu Li ◽  
Xue Jing Song ◽  
Rong Jie Yang

In this investigation, dodecyl dimethyl(vinylbenzyl)ammonium chloride is applied to modify properties of polyethylene, and it is greatly focused on influences of it on the thermal properties and mechanical properties of this polymer. The results demonstrate that addition of this compound into polyethylene has little effect on thermal properties except for little improvement of its glass temperature, although it has reactive double bond in its molecular. Moreover, it is observed that it can enhance mechanical properties of this polymer and its addition has little change in colors of bulk materials. Therefore, it is believed that these excellent properties help to drive this antibacterial compound in applications.


2010 ◽  
Vol 150-151 ◽  
pp. 1417-1420 ◽  
Author(s):  
Lei Chen ◽  
Zhi Wei Xu ◽  
Jia Lu Li ◽  
Guang Wei Chen

Nanocomposites based on epoxy which were reinforced by different nanoparticles were fabricated. Five types of nanoparticles (corresponding to multi-walled carbon nanotubes (MWNTs), nano-Al2O3, nano-TiO2 and nano-SiO2) were chosen and the weight content of the nanoparticles was 2wt.%. Impact, flexural and thermal-mechanical properties of the nanocomposites were investigated. Compared with neat epoxy, impact strength of systems which were reinforced by MWNTs and nano-TiO2 was increased by 60%. Concerned with the flexural properties, there was also an increase of about 10%~50% with the addition of the some nanoparticles such as MWNTs, nano-TiO2 and nano-SiO2. The heat resistance of the EP was not decreased by adding nanoparticles and the thermal properties of the systems were even improved with the addition of MWNTs.


2007 ◽  
Vol 1006 ◽  
Author(s):  
Renato Amaral Minamisawa ◽  
Bopha Chhay ◽  
Daryush ILA

AbstractThe reported electromagnetic properties of carbon nanotubes (CNT) make them a promising material for nanoelectronic applications [1,2]. Addition of CNT has recently been shown to enhance mechanical properties of phenolic-resin polymers [3]. We are attempting to control the electrical transport behavior of phenolic-based polymers doped with CNT as a function of the different nanopowder concentration added to the polymer. In that regard, we developed a technique to obtain a material with homogenous dispersion of nanopowders, an important factor that influences the transport behavior. The chemical structure characterization was also evaluated using optical techniques.


2016 ◽  
Vol 138 (7) ◽  
Author(s):  
Abdullah Al-Sharafi ◽  
Ahmet Z. Sahin ◽  
Bekir S. Yilbas

The use of high conductive nanoparticles, such as carbon nanotubes (CNT), enhances the thermal and electrical conductivities of the carrier fluid. Depending upon the volumetric concentration of particles and their distribution in the carrier fluid, multifold enhancement of thermal and electrical properties is possible. Therefore, in the present study, thermal and electrical properties of CNT–water mixture are assessed at microscopic level. Special distribution of the CNT in water is obtained experimentally at microscale for different durations of the heating situation. Thermal and electrical properties are predicted numerically incorporating the particle distributions obtained from the experiment. The mass based analysis is also introduced to determine the thermal properties of the mixture. The findings are compared for those obtained from the simulations based on experimentally obtained micro-images. Algebraic equations are introduced to formulate the data obtained from the simulations for temperature dependent properties. It is demonstrated that the mass based estimation of thermal properties are significantly different than those obtained from the experimental based simulations because of the nonuniform particles distribution and their localized conductivity in the carrier fluid.


2022 ◽  
Vol 320 ◽  
pp. 126212
Author(s):  
Supakporn Aodkeng ◽  
Sakprayut Sinthupinyo ◽  
Busaya Chamnankid ◽  
Wilasinee Hanpongpun ◽  
Arnon Chaipanich

Sign in / Sign up

Export Citation Format

Share Document