Study of Structural, Optical, Dielectric and Magnetic Properties of Zinc Ferrite Synthesized by Co-Precipitation

2017 ◽  
Vol 17 ◽  
pp. 1-9
Author(s):  
P. Annie Vinosha ◽  
L. Ansel Mely ◽  
J. Emima Jeronsia ◽  
F. Heartlin Monica ◽  
K. Raja ◽  
...  

Spinel zinc ferrite (ZnFe2O4) nanoparticles have engrossed immense attention due to its unusual amalgamation of its properties especially the magnetic properties and these properties are catered as fitting candidates in the field of electronics. Nanostructured spinel zinc ferrite particles were synthesized using scalable co-precipitation technique. The morphology, particle size and reaction pace of the nanoparticles (NPs) were fine tuned by eco-friendly technique. These NPs were characterized by UV-Visible spectroscopy (UV-Vis), photoluminescence (PL), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and Transmission electron microscopy (TEM), vibrating sample magnetometer ((VSM) and Dielectric studies. The required profiles were confirmed by XRD and FTIR spectra, UV-Vis, PL spectral studies. Further these measurements divulge the significance of optical properties and the spectral parameters are used to appraise the optical constants required for fabrication. Transmission electron microscopy eventually discloses the morphological analysis of the synthesized ZnFe2O4 nanoparticle as 15 nm within the scaling limitations. Using, VSM, the magnetic behaviour of the material have been determined as a function of magnetic field at ambient temperature; the magnetic measurements well-establishes the magnetic property and disclosed to have weak ferromagnetic behaviour as the crystallite size decreases. The A.C. conductivity measurements and dielectric studies were done as a functional dependence of frequency and temperature on synthesized nanoparticles.

2015 ◽  
Vol 233-234 ◽  
pp. 623-628 ◽  
Author(s):  
Vladimir P. Menushenkov ◽  
Vladimir S. Shubakov

The microstructure and magnetic properties of Fe-Co-Cr alloys with 15 wt % Co were investigated using transmission electron microscopy and magnetic measurements. The secondary decomposition within both the α2-phase matrix and the α1-phase particles was observed for magnets subjected thermo-magnetic treatment and subsequent stepped aging or continuous-cooling treatments. During high-temperature treatments (630-600оC), when the α2phase is dominant (the volume fraction is more than 50%), the secondary decomposition of this phase takes place (α2→ α1'+ α2'). The deterioration of magnetic insulation of α1-phase particles results in the decrease in the coercive force of alloys. Below 600оC, when the α1phase is dominant (the volume fraction is more than 50%), the splitting of elongated α1-phase particles occurs. When the temperature of stepped-aging decreases in high steps, the secondary decomposition (α1→ α1'+ α2') leads to the splitting of initial α1-phase particles into fine slightly elongated particles and the decrease in the coercive force.


2010 ◽  
Vol 89-91 ◽  
pp. 757-762 ◽  
Author(s):  
Sung Kang ◽  
Teppei Muramatsu ◽  
Mahoto Takeda

The precipitation behavior of nano–scale particles formed in Cu–base alloys was studied by means of transmission electron microscopy (TEM) and SQUID measurements. Linear arrangements of two or more nano–scale particles cubic in shape were observed in the <100> orientations of matrices in a Cu–Co alloy. Although the trend was less explicit in a Cu–Fe alloy, Fe precipitates accompanying twin–like lattice modulations were found in the decomposition, when no deformation was applied. The present SQUID measurements revealed several significant influences to magnetic properties were induced during the precipitation in Cu–base alloys. Lorentz electron microscopy confirmed that phase transformation from γ → α occurred at the stage that the Fe particles reach to 40~60nm in size.


2019 ◽  
Vol 7 (5) ◽  
pp. 1280-1291 ◽  
Author(s):  
Alaka Panda ◽  
R. Govindaraj ◽  
R. Mythili ◽  
G. Amarendra

Bismuth and iron oxides subjected to ball milling followed by controlled annealing treatments showed the formation of core–shell nanostructures with Bi2Fe4O9 as the core and a shell of BiFeO3 and Bi25FeO40 phases as deduced based on the analysis of transmission electron microscopy results.


2013 ◽  
Vol 275-277 ◽  
pp. 1952-1955
Author(s):  
Ling Fang Jin ◽  
Xing Zhong Li

New functional nanocomposite FePt:C thin films with FePt underlayers were synthesized by noneptaxial growth. The effect of the FePt layer on the ordering, orientation and magnetic properties of the composite layer has been investigated by adjusting FePt underlayer thickness from 2 nm to 14 nm. Transmission electron microscopy (TEM), together with x-ray diffraction (XRD), has been used to check the growth of the double-layered films and to study the microstructure, including the grain size, shape, orientation and distribution. XRD scans reveal that the orientation of the films was dependent on FePt underlayer thickness. In this paper, the TEM studies of both single-layered nonepitaxially grown FePt and FePt:C composite L10 phase and double-layered deposition FePt:C/FePt are presented.


2006 ◽  
Vol 20 (10) ◽  
pp. 549-555 ◽  
Author(s):  
JUN WANG ◽  
YUEJIN ZHU ◽  
YEJUN WU ◽  
CHANGJUN WU ◽  
DONGFENG XU ◽  
...  

Nanoshells composed of close-packed nickel nanoparticles have been fabricated on sillca spheres via strong interaction between the metallic cations and ions of the support. The nickel hollow nanoballs can be self-assembled via magnetic field-assisted route, which is confirmed by the transmission electron microscopy. The magnetic properties of Ni nanoshells are discussed. It is expected that the prepared method can be extended to the synthesis of other hollow metal spheres.


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