The Magnetocaloric Effect in Ni-Mn-X (X=Ga, in) Heusler Alloys and Manganites with Magnetic Transition close to Room Temperature

2010 ◽  
Vol 168-169 ◽  
pp. 165-168
Author(s):  
Vasiliy D. Buchelnikov ◽  
Mikhail Drobosyuk ◽  
E.A. Smyshlyaev ◽  
O.O. Pavlukhina ◽  
A.V. Andreevskikh ◽  
...  

The magnetocaloric effect (MCE) in theNi2+xMn1-xGa (x = 0.33, 0.36, 0.39), Ni50Mn25In25, Ni54Mn21Ga18In7, Ni53.5Mn21.5Ga16In9, Ni45Co5Mn36.5In13.5 Heusler alloys and in the La0.7BayCa0.3-yMnO3 (y = 0.12, 0.24, 0.3) manganites at the Curie points have been measured by the direct method. For the magnetic field change H = 2 T, the maximal adiabatic temperature change Tad in the Ni2+xMn1-xGa alloys is larger than 0.6 K. For the Ni50Mn25In25 alloy the maximal value of Tad = 1.51 K (for the same magnetic field change H = 2 T) is observed at the magnetic phase transition temperature.

2009 ◽  
Vol 1200 ◽  
Author(s):  
Vasiliy Buchelnikov ◽  
Sergey Taskaev ◽  
Mikhail Drobosyuk ◽  
Vladimir Sokolovskiy ◽  
Viktor Koledov ◽  
...  

AbstractThe positive magnetocaloric effect (MCE) in the vicinity of the Curie point in Ni2+xMn1-xGa (x=0.33, 0.36, 0.39) Heusler alloys and the negative and positive MCE near the metamagnetostructural (MMS) transition and the Curie point, respectively, in Ni45Co5Mn36.5In13.5 Heusler alloy has been measured by a direct method. For the magnetic field change ΔH = 2 T, the maximal adiabatic temperature change ΔTad at the Curie point in Ni2+xMn1-xGa alloys is larger than 0.6 K. For Ni45Co5Mn36.5In13.5 alloy, the maximal value of ΔTad = 1.68 K (for the same magnetic field change, ΔH = 2 T) is observed at the MMS phase transition temperature.


2015 ◽  
Vol 233-234 ◽  
pp. 183-186 ◽  
Author(s):  
Rafael Fayzullin ◽  
Vasiliy D. Buchelnikov ◽  
Mikhail Drobosyuk ◽  
Alexey Mashirov ◽  
Alexander Kamantsev ◽  
...  

The magnetocaloric effect (MCE) in Ni1.81Mn1.64In0.55 Heusler alloy has been measured by the direct method. The field dependences of the magnetization were obtained. The phase transition temperatures were determined. The maximal adiabatic temperature change ΔTad near the Curie temperature is 1.8 K under the magnetic field change ∆H = 18 kOe. The inverse MCE (∆Tad = -3.72 K) in the same field change takes place near the temperature of martensitic transformation.


2011 ◽  
Vol 84-85 ◽  
pp. 667-670
Author(s):  
Guo Qiu Xie

In this paper, we report on the structure, magnetic properties and magnetocaloric effect in NaZn13-type LaFe11.1Co0.8Si1.1Bxalloys close to room temperature. The stable NaZn13cubic structure phase (space group isFm-3c) can easily obtained by annealing at 1080 °C for 225 hours. The maximal values of magnetic entropy change for LaFe11.1Co0.8Si1.1Bx(x=0.2, 0.25) were found to be 5.3 and 5.9 J/kg K at Curie temperature for a magnetic field change in 0-1.5 T, respectively. The calculated refrigerant capacity for a field change in 0–1.5 T is about 147 and 107 J/kg K, for LaFe11.1Co0.8Si1.1B0.2and LaFe11.1Co0.8Si1.1B0.25respectively, which is as larger as those of Gd(99.3%) alloy


2013 ◽  
Vol 738-739 ◽  
pp. 456-460 ◽  
Author(s):  
Rafael Fayzullin ◽  
Vasiliy D. Buchelnikov ◽  
Sergey Taskaev ◽  
Mikhail Drobosyuk ◽  
Vladimir V. Khovaylo

In this work we experimentally studied the MCE in the Heusler alloys Ni2.19-xFexMn0.81Ga (x = 0.01, 0.02, 0.03, 0.04) and Ni2.16-xCoxMn0.84Ga (x = 0.03, 0.06, 0.09). Magnetocaloric effect was measured by the direct method using the installation from the company AMT&C. The temperature dependencies of ∆Tad for the magnetic field change ∆H = 2 T were measured. The phase transition temperatures were determined from temperature dependencies of low field magnetization measured by original setup using Hall effect. Studies have shown that replacement of the Ni atoms with the iron atoms slightly reduces the temperature magnetostructural transition for x = 0.01,0.02, and starting with x = 0.03, magnetic and structural transitions occur separately and a further increase in iron concentration leads to the Curie temperature increase, while the temperature martensitic transformation decreases. When replacing the Ni atoms with the Co atoms of the martensitic transformation temperature and Curie temperature increase.


2012 ◽  
Vol 190 ◽  
pp. 355-358 ◽  
Author(s):  
D.A. Shishkin ◽  
N.V. Baranov ◽  
A.V. Proshkin ◽  
S.V. Andreev ◽  
A.S. Volegov

The liquid quenched Gd3Ni alloy is observed to exhibit a ferromagnetic behavior below TC = 117 K unlike crystalline compound having an antiferromagnetic order at T < TN = 99 K. Rapid quenching from the melt results in a considerable enhancement of the magnetocaloric effect in Gd3Ni at low magnetic fields. The maximal value of the isothermal magnetic entropy change at a magnetic field change of 20 kOe for the amorphous Gd3Ni surpasses by more than 8 times the SM value for the polycrystalline counterpart. The relative cooling power for the amorphous Gd3Ni alloy is estimated as 265 J kg-1 and 676 J kg-1 at a magnetic field change of 20 kOe and 50 kOe, respectively.


2012 ◽  
Vol 246-247 ◽  
pp. 1096-1101
Author(s):  
Song Wang ◽  
Guo Tian He ◽  
Li Song ◽  
Ze Yu Xu ◽  
Ying Chun Ran

With the development of theory that research on Magneto-Rheological Fluids (MRF), the MRF have been used in many fields in our life. The electrical characteristics of MRF can be widely used in automatic control, medical, automotive, aircraft manufacturing and many other areas .Firstly, this article have derived the formula of MRF between capacitance and Dielectric constant, made the Capacitors which can load the MRF. And then we measure the change of capacitance which is filled with the MRF when the time of magnetic field change, And we also measure the sensitivity of the dielectric constant of different concentrations of MRF as the magnetic field changes. And at last, we have made the curve of the capacitance - magnetic induction intensity the experimental results have been analyzed. We have the conclusion that when the magnetic field increases, the dielectric constant is also increases, resulting in increased capacitance of the conclusions of MRF. Introduction


1993 ◽  
Vol 13 (2) ◽  
pp. 145-150
Author(s):  
Nobuyuki Takagi ◽  
Tomoyasu Sugiura ◽  
Teiji Watanabe ◽  
Izumi Arima ◽  
Tosio Takeuti ◽  
...  

2004 ◽  
Vol 13 (4) ◽  
pp. 654-661 ◽  
Author(s):  
Johan Bohlmark ◽  
Ulf Helmersson ◽  
Michael VanZeeland ◽  
I Axnäs ◽  
Jones Alami ◽  
...  

2016 ◽  
Vol 872 ◽  
pp. 38-42
Author(s):  
Vladimir Khovaylo ◽  
Konstantin Skokov ◽  
Sergey Taskaev ◽  
Alexey Karpenkov ◽  
Dmitriy Karpenkov ◽  
...  

Magnetocaloric effect (MCE) in the vicinity of first order martensitic transformation and second order magnetic transition in a single crystalline Ni2.13Mn0.81Ga1.06 Heusler compound was studied by a direct method. The obtained results revealed that, for the applied magnetic field strength μ0H = 1.9 T, MCE is irreversible in the vicinity of the first order martensitic transformation only when the MCE measurements are performed under cooling protocol. Plot of the experimentally measured adiabatic temperature change ΔTad as a function of temperature T indicated that ΔTad has a negligible benefit from the magnetic field-induced conversion of the high-temperature austenitic phase into the low-temperature martensitic phase and is mainly determined by the paraprocess of the austenitic phase around both direct and reverse martensitic transformations.


2011 ◽  
Vol 685 ◽  
pp. 311-315
Author(s):  
Zhi Zeng ◽  
Xue Zhen Wang ◽  
Jian Huang ◽  
Jie Xiang ◽  
Xue Ling Hou

Gd5Si2Ge2-based alloys can exhibit a giant magnetocaloric effect (GMCE) which gives them the potential use in the cooling technologies[1].Through this studies, it can be found that the purity of Gd had a great impact on the magnetocaloric effect in Gd5Si2-xGe2-xZn2x alloys. When 3N Gd used and 2x=0.01, Gd5Si2-xGe2-xZn2x around the curie point of 280k get the maximum magnetic entropy change of 14.0 J/(Kg.K) under the external magnetic field change from 0 to 1T, but when 2N Gd used and 2x=0.05, Gd5Si2-xGe2-xZn2x around the curie point of 284.2k under the external magnetic field change 1T get the maximum magnetic entropy change 6.65 J/(Kg.K).


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