Using pH-dependent CEC to determine lime requirement

2006 ◽  
Vol 86 (1) ◽  
pp. 133-139 ◽  
Author(s):  
Edouard Lemire ◽  
Kate M Taillon ◽  
William H. Hendershot
Keyword(s):  
Organic Matter ◽  
Soil Properties ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Soil Analysis ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Ph Dependent ◽  
Ph Curve

Controlling soil pH is important to ensure good crop yield. This study was conducted to determine whether the accuracy of the existing Shoemaker-McLean-Pratt (SMP) pH-buffer method could be improved by using the pH-dependent cation exchange capacity curve (CECpd). Soil pH, SMP and CECpd measurements were performed on 18 acid surface horizon soil samples, with textures from sandy loam to clay loam. These soils were incubated with three levels of calcium carbonate for 12 wk, after which the soil pH and the effective cation exchange capacity (CECe) were measured. The correlation coefficient (R2) for the CECpd and CECe curves was 0.96. The main factor affecting the slope of the curves is the soil organic matter content. The increase of CECe in the soil was also found to be directly proportional to the amount of lime applied, regardless of the type of soil. By using the slope of the Qv versus pH curve for each soil and the relationship between CECe and lime application, we were able to determine the lime required to raise the soil pH in water to 6.5. As an alternative to the current practice of using the SMP buffer, we propose that it should be possible to estimate the pH-dependent CEC curve from measurable soil properties (e.g., organic matter) and to estimate the lime requirement as the difference in CECpd between the existing and desired pH values. Once the slope of the Qv/pH relationship has been determined or estimated for a soil, the only measurement necessary for calculating lime requirement in subsequent years would be the soil pH. The proposed method would provide lime requirement estimates while decreasing the annual cost of soil analysis. Key words: Lime requirement, cation exchange capacity, Non-Ideal Competitive Adsorption, soil properties, organic matter, Fe oxides

Spatial variability of uncultivated soils in derived savanna

2013 ◽  
Vol 27 (1) ◽  
pp. 57-67 ◽  
Author(s):  
S.E. Obalum ◽  
J. Oppong ◽  
C.A. Igwe ◽  
Y. Watanabe ◽  
M.E. Obi
Keyword(s):  
Organic Matter ◽  
Spatial Variability ◽  
Soil Properties ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Organic Matter Concentration ◽  
Derived Savanna ◽  
Matter Concentration

Abstract The spatial variability of some physicochemical properties of topsoils/subsoils under secondary forest, grassland fallow, and bare-soil fallow of three locations was evaluated. The data were analyzed and described using classical statistical parameters. Based on the coefficient of variation, bulk density, total porosity, 60-cm-tension moisture content, and soil pH were of low variability. Coarse and fine sand were of moderate variability. Highly variable soil properties included silt, clay, macroporosity, saturated hydraulic conductivity, organic matter concentration, and cation exchange capacity. Overall, soil pH and silt varied the least and the most, respectively. Relative weighting showed that location dominantly influenced the soil variability, except for soil porosity and organic matter concentration influenced mostly by land use. Most of the soil data were normally distributed; others were positively skewed and/or kurtotic. The minimum number of samples (at 25 samples ha-1) required to estimate mean values of soil properties was highly soil property-specific, ranging from 1 (topsoil pH-H2O) to 246 (topsoil silt). Cation exchange capacity of subsoils related fairly strongly with cation exchange capacity of topsoils (R2 = 0.63). Spatial variability data can be used to extrapolate dynamic soil properties across a derived-savanna landscape.

EVALUATING RELATIONSHIPS AMONG SOIL PROPERTIES BY COMPUTER ANALYSIS

1971 ◽  
Vol 51 (1) ◽  
pp. 105-111 ◽  
Author(s):  
J. A. McKEAGUE ◽  
J. H. DAY ◽  
J. A. SHIELDS
Keyword(s):  
Organic Matter ◽  
Linear Regression ◽  
Correlation Analysis ◽  
Soil Properties ◽  
Cation Exchange ◽  
Computer Analysis ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Regression Equations ◽  
Ph Dependent

Data for 16 measured and seven calculated properties of 461 samples from 115 soils occurring in various parts of Canada were coded, and a correlation analysis was run on the data for various groups of samples. In general, correlations of color value and organic matter were moderately high (|r| > 0.5) and significant, but for 21 Podzol Ae horizons the correlation was very low (r = −0.13) and not significant. Chroma and dithionite Fe were significantly correlated for several groups of samples but not for Podzolic B (spodic) horizons or Bm horizons. Linear regression equations expressing cation exchange capacity and pH-dependent charge as functions of organic matter and other variables fitted the data reasonably well. The danger of generalizing from presumed relationships among soil properties was indicated but, for some groups of samples, useful relationships existed between visible soil properties and properties measured in the laboratory.

ETUDE SUR LA VALEUR DES CRITERES CHIMIQUES PROPOSES PAR LA COMMISSION PEDOLOGIQUE DU CANADA POUR LA CLASSIFICATION TAXONOMIQUE DES SOLS DU QUEBEC

1977 ◽  
Vol 57 (3) ◽  
pp. 233-247 ◽  
Author(s):  
ROGER W. BARIL ◽  
THI SEN TRAN
Keyword(s):  
Cation Exchange ◽  
Soil Ph ◽  
Classification System ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Taxonomic Classification ◽  
Single Test ◽  
Ph Dependent ◽  
Extractable Al

Correlations were made among chemical criteria used for taxonomic soil classificaton. The compared tests were: oxalate Δ (Fe + Al), pyrophosphate-extractable (Fe + Al), oxalate-extractable Al, pH-dependent cation exchange capacity (ΔCEC), ratios of pyrophosphate-extractable (Fe + Al) over clay or over dithionite-extractable (Fe + Al), and finally soil pH measured in 1 M NaF. Significant correlations were found among various measured parameters. However, no single test was found to be reliable as a single criterion when applied to the taxonomic classification of Quebec soils. The two chemical tests, pyrophosphate-extractable (Fe + Al) and its ratio over clay, combined with morphologic criteria appeared useful for classifying Quebec Podzols. A few soils, which presented discrepancies from chemical criteria were found difficult to classify, thus suggesting the possibility of establishing new sub-groups in the Canadain soil taxonomic classification system.

scholarly journals Influence of brick manufacturing on phosphorus and sulfur in different agro-ecological soils of Bangladesh

2017 ◽  
Vol 29 (2) ◽  
pp. 123-131
Author(s):  
Reshma Akter ◽  
Md Jamal Uddin ◽  
Md Faruque Hossain ◽  
Zakia Parveen
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Clay Content ◽  
Exchange Capacity ◽  
Soil Samples ◽  
Maximum Accumulation ◽  
Brick Kilns ◽  
Total P

A study was carried out to evaluate the effects of brick manufacturing on phosphorus (P) and sulfur (S) concentrations in soil and plant collected from different distances of brick kilns in four AEZs of Bangladesh. Forty eight composite soil samples (0 - 15 cm depth) were collected from 48 points in 12 different sites at 0 m, 300 m, 800 m and 1500 m from brick kilns, where most (site 2, site 3, site 5, site 6, site 7, site 9 and site 10) of the brick kilns used coal for brick burning purposes. Plant samples (rice straw and different vegetables) were also collected from the respective fields except 0 m distances. Significantly (p ? 0.05) lower organic matter, cation exchange capacity, clay content and soil pH were found at 0 m distances compared to other distances. Highest concentration of total P in soil were recorded at 0 m distances and these concentrations decreased with increasing distances from the brick kilns in most of the sites; whereas available P is significantly lower at 0 m distances than that of other distances. Total and available concentration of S in soil followed the trend 0 m>300 m>800 m>1500 m. Maximum accumulation of P (69.15 mg kg-1) and S (0.14%) in plant was found at 800 m away from the brick kiln.Bangladesh J. Sci. Res. 29(2): 123-131, December-2016

ESTIMATION OF THE INORGANIC AND ORGANIC pH-DEPENDENT CATION EXCHANGE CAPACITY OF THE B HORIZONS OF PODZOLIC AND BRUNISOLIC SOILS

1968 ◽  
Vol 48 (1) ◽  
pp. 53-63 ◽  
Author(s):  
J. S. Clark ◽  
W. E. Nichol
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Acid Soils ◽  
Exchange Capacity ◽  
Hydrous Oxides ◽  
Before And After ◽  
Ph Dependent ◽  
The Difference ◽  
Wyoming Bentonite

Heating in hydrogen peroxide, dilute oxalic acid, and dilute aluminum oxalate did not change the effective cation exchange capacity (CEC) or the pH-7 CEC of Wyoming bentonite and Alberni clay soil containing excess Al(OH)x. This indicated that treatment of soils with H2O2 to oxidize organic matter and the possible production of oxalates during oxidation did not change the CEC values of the inorganic fraction of soils even if some clay exchange sites were blocked by hydrous oxides of Al.With soils of pH less than approximately 5.4, oxidation of organic matter did not change the effective CECs although the pH-7 CEC values were decreased. Thus, organic matter in acid soils appeared to have little or no effective CEC. Because of this and the negligible effect of H2O2 oxidation on the CEC values of clays, the difference of the pH-7 CEC of soils before and after H2O2 oxidation provided a simple means of estimating the amount of organic pH-dependent CEC in acid soils.The amount of organically derived pH-dependent CEC was determined in a number of soils by means of peroxide oxidation. The technique provided a useful indication of the quantities of sesquioxide–organic matter complexes accumulated in medium- and fine-textured soils.

FACTEURS QUI INFLUENCENT LA TENEUR DE LA MATIERE ORGANIQUE ET LES PROPRIETES D'ECHANGE CATIONIQUE DES HORIZONS Ap DES SOLS DE GRANDE CULTURE DU QUEBEC

1976 ◽  
Vol 56 (3) ◽  
pp. 213-221 ◽  
Author(s):  
Y. A. MARTEL ◽  
M. R. LAVERDIERE
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Western Canada ◽  
Regression Equations ◽  
Eastern Canada ◽  
Forage Crops ◽  
Exchangeable Bases

The objectives of this work were (1) to determine the relation existing between the organic matter contents of Ap horizons and their respective soil Orders, (Gleysolic and Podzolic), texture, pH and geographic locations in the different thermal regions of Quebec and (2) to determine the role of organic matter and soil texture on the cation exchange properties of the same Ap horizons coming from soils used for forage crops in Quebec. The cation-exchange capacity (CEC), the exchangeable bases and acidity were determined by using 1 N NH4OAC – pH 7. The results showed a variation in the carbon content ranging from 1.4 to 6.9%. The heat units accumulated in each region and the clay contents were correlated with the percentage of carbon and nitrogen. Soil pH and soil Orders (Gleysolic vs. Podzolic) did not seem to affect the organic matter content. The cation-exchange capacity (CEC) ranged from 10.6 to 42.6 meq/100 g soil; 40% of this was attributable to carbon and 32% to clay contents. Simple and multiple regression equations showed that carbon was correlated with the exchangeable acidity, while clay was related to the exchangeable bases. The CEC of organic matter and clay were respectively 161 ± 45 meq/100 g organic matter and 29 ± 6 meq/100 g clay. These values, lower than for Western Canada, reflected the nature of the organic matter that is less developed in Eastern Canada than in the Chernozemic soils; they also showed the effect of the predominant illite mineral found in the clay fractions compared to montmorillonite in Western Canada.

scholarly journals SOIL PROPERTIES AND NUTRIENT ELEMENT STATUS OF COCONUT LEAVES UNDER DEFFERENT CROPPING PATTERNS

CORD ◽  
1988 ◽  
Vol 4 (01) ◽  
pp. 34
Author(s):  
Doah Dekok Tarigans
Keyword(s):  
Organic Matter ◽  
Soil Properties ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Block Design ◽  
Exchange Capacity ◽  
Cropping Pattern ◽  
Nutrient Element ◽  
Cropping Patterns ◽  
Significant Difference

This study was conducted to investigate the effects of six co­conut cropping patterns on the soil properties and nutrient element status of coconut leaves. The experiments were carried out from August 1984 to May 1985 in Silang, Cavite, Philippines. Data on‑soil properties and nutrient element starus of coconut leaves were statistically analyzed in Randomized Block Design with three replications. Six cropping patterns in coconut with four species of perennial crops as intercrops, namely: banana, papaya, coffee and pineapple were used in this study. The organic matter, pH and cation exchange capacity of the soils did not differ significantly with cropping pattern although intensively cropped farms tended to have higher organic matter' and cation exchange capacity values. Nitrogen, phosphorus and potassium in the top soil were significantly higher in most intensive intercropped farms, but calcium and magnesium did not vary significantly. Moisture content, waterholding capacity, bulk density and particle density of the soil did not show significant difference with cropping patterns. Likewise, the number of bacteria, fungi and actinomycetes in the soil remained statistically the same. Leaf nitrogen and calcium, in­creased while potassium decreased with intensity of cropping. Phosphorus and magnesium showed no definite trend.

scholarly journals Effect of microalgae application on soil algal species diversity, cation exchange capacity and organic matter after herbicide treatments

F1000Research ◽  
2014 ◽  
Vol 3 ◽  
pp. 281 ◽  
Author(s):  
Karin L. Hastings ◽  
Lauren E. Smith ◽  
Michael L Lindsey ◽  
Luke C. Blotsky ◽  
Gloria R. Downing ◽  
...  
Keyword(s):  
Organic Matter ◽  
Species Diversity ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Soil Analysis ◽  
Soil Microbial Communities ◽  
Exchange Capacity ◽  
Positive Effects ◽  
Morphological Criteria ◽  
Herbicide Treatments

Soil microalgae live on small communities that change structure depending on many factors. Some of these factors include soil pH, agricultural practices as well as pesticide and herbicide treatments.  The size and activity of these soil microbial communities is an indicator of health, quality and fertility necessary for sustainable agriculture.  Methods:A commercial proprietary suspension of microalgae GOgreen®was applied at different concentrations through a center pivot irrigation system to a crop of cultivated corn (Zea mays) during six months.  Experimental plots of 0.5 acres each were planted in four rows. Corn (34,000 plants/acre) was planted in May and harvested in November allowing each plot to be studied for 6 months. In addition, one plot was planted for a second year to study the effects of consecutive planting and harvesting on algae populations in the soil. Soil samples were collected at a depth of 6 inches. Microalgae species identification was based on morphological criteria. Soil analysis included organic matter content (OM), pH and cation exchange capacity (CEC).Results:Treatment with GOgreen®has significant and measurable positive effects on soil OM content, CEC, pH and microalgae species diversity.Conclusions:  It was demonstrated through this study that GOgreen®increased diatom numbers and microalgae species diversity showing a restorative effect on soil quality after herbicide treatment in heavily farmed soil. Additionally, GOgreen®lowers the pH in soils with a pH higher than 7.0 emerging as an economical alternative that is safe for humans and the environment.

Soil fertility changes in the long-term experimental plots at Kybybolite, South Australia. III. Changes in cation exchange capacity and exchangeable cations

1961 ◽  
Vol 12 (2) ◽  
pp. 273 ◽  
Author(s):  
JS Russell
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Upward Movement ◽  
Exchangeable Calcium ◽  
Exchange Complex

Changes in the cation exchange complex are one of the secondary effects arising out of the increasing organic matter content of soils, due to the influence of phosphorus fertilizers on leguminous pastures. Analysis of solonetzic soils from the long-term Kybybolite P plots indicates that there is a close relation between organic matter increase and increases in cation exchange capacity. For each increase of 0.1 % soil nitrogen, there has been a corresponding increase of 3.48 m-equiv.jl00 g in cation exchange capacity. Associated with these changes there have been increases in the level of exchangeable calcium and exchangeable hydrogen. Changes in exchangeable calcium appear related to the amount and form of fertilizer or amendment applied. Where little calcium has been added, the increase in cation exchange capacity has been satisfied almost entirely by hydrogen, and base saturation has decreased. There appears to have been little upward movement of metal cations from the lower horizons to the surface by plants, possibly owing to the species involved, or to the intractable nature of the B horizon. The possible effects of changes in the cation exchange complex on plant growth are discussed. Also, the possibility of maintaining base saturation on infertile soils where cation exchange capacity is being increased, is examined.

Sustainable use of wetland soils in the eastern region of Uganda around Lake Victoria Basin

2011 ◽  
Vol 6 (3) ◽  
Author(s):  
J. Zake ◽  
J. Y. Z. Kitungulu ◽  
H. Busurwa ◽  
F. Kyewaze
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Lake Victoria ◽  
Exchange Capacity ◽  
Buffering Capacity ◽  
Wetland Soils ◽  
Lake Victoria Basin ◽  
Eastern Uganda

Wetlands are not wastelands but wealth lands, which are widely distributed throughout Uganda currently covering 11% of the total land area. They are accessible to a large proportion of the population. As the country's population grows, people increasingly convert wetlands for other land uses such as farming, settlement among others thus making it difficult to enforce legislation for their protection, sustainable management and utilization. Their profound importance to both humans and wildlife calls for a concerted effort to ensure their sustainable utilization and attempts should be made to promote sustainable development of such wetlands with adequate considerations being given to human and environmental requirements. This study was therefore carried out to determine the effect of drainage on organic matter levels and on soil chemical changes in wetland soils in eastern Uganda around the Lake Victoria basin. Secondly, to assess potential lime requirements for drained wetland soils in eastern Uganda around the Lake Victoria basin, this would reflect on wetland soil buffering capacity. In green house studies it was found that drainage of wetland soils led to a reduction of organic matter relative to soil structure and where sulfur and iron were present in large amounts, drainage caused decrease in soil pH to moderately acidic levels; but in cases where exchangeable bases were present in large amounts there was an increase in soil pH. Lime requirements were greater where the amount of clay, organic matter and cation exchange capacity were high. Consequently, such wetland soils had a high buffering capacity. It was concluded that wetland soils should be characterized in terms of potential of acidification, level of organic matter, nutrient content, cation exchange capacity, soil texture and levels of trace elements. Decisions to drain or not to drain should depend on these parameters and other socio-economic considerations for the area.

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