scholarly journals Synergistic Antibacterial Performance of a Cu/WO<sub>3</sub>-Added PTFE Particulate Superhydrophobic Composite under Visible-Light Exposure

2012 ◽  
Vol 03 (04) ◽  
pp. 421-430 ◽  
Author(s):  
Yanyan Yao ◽  
Kentaro Yamauchi ◽  
Goro Yamauchi ◽  
Tsuyoshi Ochiai ◽  
Taketoshi Murakami ◽  
...  
2020 ◽  
Vol 10 (2) ◽  
Author(s):  
Ameer Baig Ali Baig ◽  
Vadamalar Rathinam ◽  
Jayanthi Palaninathan

AbstractZr-doped SnO2 (Zr:SnO2) nanostructures (NSs) were produced by simplistic and low-cost co-precipitation route. The FTIR spectra of bands on 523 and 583 cm−1 were witnessed though indorsed as the features of (Sn–OH) term which approves the incident of Sn–O in the synthesized samples. The Zr:SnO2 NSs were spherical-like and composed of numerous agglomerated particles. The decreased crystallite sizes of the pristine and Zr-doped SnO2 NPs were 41.9, 38.9 and 35.8 nm individually. Moreover, the achievable growth manner of acquired samples was deliberated through the source of the customs of nucleation and crystal growth. The photocatalytic performances of 4% of Zr-doped SnO2 nanoparticles (NPs) were thoroughly explored in the photodegradation of methyl orange (MO) dye, thus revealing higher photocatalytic activity in the degradation of MO than pristine and 2% of Zr-doped SnO2 under via visible-light exposure. Related to pristine SnO2, the 4% Zr-doped SnO2 NPs are accessible to greater photocatalytic capability, which could be essentially accredited to existing in the nominal defects of oxygen vacancies by the produced NPs. Eventually, founded on the self-assembly progression the possible development of photocatalytic mechanism was projected by means of reactive species in trapping tests as well. Also, the antibacterial action was attained against E. coli and S. aureus bacteria through agar well diffusion system.


2019 ◽  
Vol 948 ◽  
pp. 33-42 ◽  
Author(s):  
Endang Tri Wahyuni ◽  
Roto Roto ◽  
Mirma Prameswari

A visible active antibacterial agent, namely TiO2-Ag-Nanoparticle has been prepared, characterized, and examined to combat E.coli bacteria in the present of the visible light. The preparation was carried out by reduction of AgNO3solution over TiO2photocatalyst under UV light exposure. TiO2-Ag nanoparticle was characterized using XRD, SEM and DRS instruments. The activity as an antibacterial agent has been tested for disinfection of E. coli bacteria in the contaminated well water. The antibacterial assay was carried out by visible light irradiation of the contaminated well water in the present of TiO2-Ag, as well as TiO2for comparison, for the various period. The antibacterial performance was represented as the number of the bacteria determined by colony counting method. Their XRD patterns probe that the Ag doping leads to the crystalline of TiO2partially destroyed and the average particle size of TiO2in TiO2-Ag is larger thanTiO2bare, and no peaks of Ag metal appeared, implying that the Ag silver is very small(nanoparticle) that may be inserted into the TiO2crystal lattice. Based on the DRS spectra it is observed that TiO2-Ag has visible light absorption meanwhile TiO2only can absorb the UV light. The antibacterial assessment demonstrates that the TiO2-Ag has high performance in the bacterial inactivation under visible light. Meanwhile, very low activity is shown by TiO2. Moreover, the increase of Ag loaded gives rise in the bacterial inactivation, but further increase leads to the inactivation slightly reduced. The extension time of the visible light exposure is found to promote more effective antibacterial process up to maximum level, and no effect was observed with the much longer time. It is also confirmed that a small amount of Ag is dissolved from TiO2-Ag NP during the antibacterial testing.


2019 ◽  
Vol 8 (1) ◽  
pp. 56-61
Author(s):  
Aneeya K. Samantara ◽  
Debasrita Dash ◽  
Dipti L. Bhuyan ◽  
Namita Dalai ◽  
Bijayalaxmi Jena

: In this article, we explored the possibility of controlling the reactivity of ZnO nanostructures by modifying its surface with gold nanoparticles (Au NPs). By varying the concentration of Au with different wt% (x = 0.01, 0.05, 0.08, 1 and 2), we have synthesized a series of (ZnO/Aux) nanocomposites (NCs). A thorough investigation of the photocatalytic performance of different wt% of Au NPs on ZnO nanosurface has been carried out. It was observed that ZnO/Au0.08 nanocomposite showed the highest photocatalytic activity among all concentrations of Au on the ZnO surface, which degrades the dye concentration within 2 minutes of visible light exposure. It was further revealed that with an increase in the size of plasmonic nanoparticles beyond 0.08%, the accessible surface area of the Au nanoparticle decreases. The photon absorption capacity of Au nanoparticle decreases beyond 0.08% resulting in a decrease in electron transfer rate from Au to ZnO and a decrease of photocatalytic activity. Background: Due to the industrialization process, most of the toxic materials go into the water bodies, affecting the water and our ecological system. The conventional techniques to remove dyes are expensive and inefficient. Recently, heterogeneous semiconductor materials like TiO2 and ZnO have been regarded as potential candidates for the removal of dye from the water system. Objective: To investigate the photocatalytic performance of different wt% of Au NPs on ZnO nanosurface and the effect of the size of Au NPs for photocatalytic performance in the degradation process. Methods: A facile microwave method has been adopted for the synthesis of ZnO nanostructure followed by a reduction of gold salt in the presence of ZnO nanostructure to form the composite. Results: ZnO/Au0.08 nanocomposite showed the highest photocatalytic activity which degrades the dye concentration within 2 minutes of visible light exposure. The schematic mechanism of electron transfer rate was discussed. Conclusion: Raspberry shaped ZnO nanoparticles modified with different percentages of Au NPs showed good photocatalytic behavior in the degradation of dye molecules. The synergetic effect of unique morphology of ZnO and well anchored Au nanostructures plays a crucial role.


ChemCatChem ◽  
2019 ◽  
Vol 11 (14) ◽  
pp. 3307-3317
Author(s):  
Andreea L. Chibac ◽  
Violeta Melinte ◽  
Vlasta Brezová ◽  
Estelle Renard ◽  
Arnaud Brosseau ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xiaoyu Zhao ◽  
Ye Zhao ◽  
Ming-De Li ◽  
Zhong’an Li ◽  
Haiyan Peng ◽  
...  

AbstractPhotopolymerization-based three-dimensional (3D) printing can enable customized manufacturing that is difficult to achieve through other traditional means. Nevertheless, it remains challenging to achieve efficient 3D printing due to the compromise between print speed and resolution. Herein, we report an efficient 3D printing approach based on the photooxidation of ketocoumarin that functions as the photosensitizer during photopolymerization, which can simultaneously deliver high print speed (5.1 cm h−1) and high print resolution (23 μm) on a common 3D printer. Mechanistically, the initiating radical and deethylated ketocoumarin are both generated upon visible light exposure, with the former giving rise to rapid photopolymerization and high print speed while the latter ensuring high print resolution by confining the light penetration. By comparison, the printed feature is hard to identify when the ketocoumarin encounters photoreduction due to the increased lateral photopolymerization. The proposed approach here provides a viable solution towards efficient additive manufacturing by controlling the photoreaction of photosensitizers during photopolymerization.


2018 ◽  
Vol 42 (17) ◽  
pp. 14229-14238 ◽  
Author(s):  
Joyee Mitra ◽  
Manav Saxena ◽  
Navendu Paul ◽  
Ekata Saha ◽  
Rudra Sarkar ◽  
...  

An easily separable graphene oxide–molybdenum oxo-bis(dithiolene) ([Ph4P]2[MoO(S2C2(CN)2)2]) composite degraded Rhodamine B and Rose Bengal dye upon visible light exposure.


2019 ◽  
Vol 30 (16) ◽  
pp. 15299-15312 ◽  
Author(s):  
Shahid Ali Khan ◽  
Tofail Arshad ◽  
Md. Faisal ◽  
Zarbad Shah ◽  
Kausar Shaheen ◽  
...  

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