Plastics with embedded particles decompose in days instead of years

2021 ◽  
pp. 4-4
Author(s):  
Leigh Krietsch Boerner
Keyword(s):  
1995 ◽  
Vol 60 (11) ◽  
pp. 1875-1887 ◽  
Author(s):  
Jaroslav Holoubek ◽  
Miroslav Raab

Theoretical background for an optical method is presented which makes it possible to distinguish unambiguously between voids and particles as light scattering sites in polymeric materials. Typical dependences of turbidity as a function of diameter of scattering elements, their volume fractions and also turbidity curves as a function of the wavelength of the incident light were calculated, based both on the Lorenz-Mie theory and the fluctuation theory. Such dependences calculated for polypropylene-containing voids on the one hand and particles, differing only slightly from the surrounding matrix in their refractive index, on the other hand, are markedly different. The most significant results are: (i) Turbidity is at least by two orders of magnitude larger for voids in comparison to embedded particles of ethylene-propylene (EPDM) rubber of the same size, concentration and at the same wavelength. (ii) The wavelength dependence of turbidity for EPDM particles and the inherent refractive index fluctuations in the polypropylene matrix is much steeper as compared to voids for all considered diameters (0.1-10 μm). Thus, the nature of stress whitening in complex polymeric materials can be determined from turbidity measurements.


Author(s):  
José De Jesús Pérez Bueno ◽  
Jorge Luis Soto Corral ◽  
José Luis Reyes Araiza ◽  
Maria Luisa Mendoza López ◽  
Alejandro Manzano Ramírez

2001 ◽  
Vol 703 ◽  
Author(s):  
K. Chattopadhyay ◽  
V. Bhattacharya ◽  
A. P. Tsai

ABSTRACTNanodispersed lead in metallic and amorphous matrices was synthesized by rapid solidification processing. The optimum microstructure was tailored to avoid percolation of the particles. With these embedded particles it is possible to study quantitatively the effect of size on the superconducting transition temperature by carrying out quantitative microstructural characterization and magnetic measurements. Our results suggest the role of the matrices in enhancement or depression of superconducting transition temperature of lead. The origin of this difference in behavior with respect to different matrices and sizes is discussed.


Author(s):  
Razvan-Dumitru Ceuca

We consider a Landau-de Gennes model for a connected cubic lattice scaffold in a nematic host, in a dilute regime. We analyse the homogenised limit for both cases in which the lattice of embedded particles presents or not cubic symmetry and then we compute the free effective energy of the composite material. In the cubic symmetry case, we impose different types of surface anchoring energy densities, such as quartic, Rapini-Papoular or more general versions, and, in this case, we show that we can tune any coefficient from the corresponding bulk potential, especially the phase transition temperature. In the case with loss of cubic symmetry, we prove similar results in which the effective free energy functional has now an additional term, which describes a change in the preferred alignment of the liquid crystal particles inside the domain. Moreover, we compute the rate of convergence for how fast the surface energies converge to the homogenised one and also for how fast the minimisers of the free energies tend to the minimiser of the homogenised free energy.


1977 ◽  
Vol 21 ◽  
pp. 305-307 ◽  
Author(s):  
C. S. Barrett ◽  
P. K. Predecki

The method presented In 1976 for measuring stresses in polymeric materials including fiber-reinforced composites (1,2) yielded directly only one or two of the principal stresses and (elastic) strains in the embedded crystalline particles. The method is now extended so as to yield determinations of all three principal stresses σ1, σ2, σ3 and strains, ε1, ε2, ε3, The method applies to both residual and applied stresses and strains.High angle diffractometry such as is used in ordinary X-ray stress determinations in metal objects is used, with suitable particles being embedded in a homogeneous plastic or reinforced composite before curing.


Scilight ◽  
2019 ◽  
Vol 2019 (46) ◽  
pp. 461105
Author(s):  
Anashe Bandari
Keyword(s):  

1993 ◽  
Vol 39 (132) ◽  
pp. 303-315 ◽  
Author(s):  
J. -L Tison ◽  
J. -R. Petit ◽  
J. -M. Barnola ◽  
W. C. Mahaney

AbstractThe debris-rich ice from the bottom 6 m of the 82 m deep CAROLINE (Coastal Antarctic Record of Last Interglacial Natural Environment) ice core reaching bedrock, and from five 2 m long surface cores at Moraine Prudhomme in Terre Adélie (Antarctica) is described and compared to debris-laden ice from the core-drilling site DIO. Isotopic, total-gas content, CO2concentration and SEM investigations of embedded particles, together with ice textures and fabrics, rule out “pressure-melting” regelation around bed obstacles or “freezing-on” as possible mechanisms for the debris entrainment at the ice-bedrock interface. It is suggested that the debris entrapment by purely mechanical means (e.g. shearing) is an efficient process in forming basal ice layers (BIL) at sub-freezing temperatures. This process might be dominant at the margin of the Antarctic ice sheet where no ice shelf exists and where a ramp terminus or a buttressing coastal relief induces compressive flow.


2018 ◽  
Vol 14 (S345) ◽  
pp. 237-238
Author(s):  
Wilhelm Kley ◽  
Giovanni Picogna ◽  
Moritz H. R. Stoll

AbstractPlanets form in protoplanetary accretion discs around young protostars. These discs are driven by internal turbulence and the gas flow is not laminar but has stochastic components. For weakly ionised discs the turbulence can be generated purely hydrodynamically through the vertical shear instability (VSI). Embedded particles (dust/pebbles) experience a hydrodynamic drag and drift inward radially and are stirred up vertically by the turbulent motion of the disc. We study the accretion of particles onto a forming planet embedded in a VSI turbulent protoplanetary disc through a series of 3D hydrodynamical simulations for locally isothermal discs with embedded planets in the mass range from 5 to 100 Earth masses (M2295).


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