Influence of Squeezing Rate on Yield Stress and Viscosity of Fresh Mortar

In the present work, squeeze flow techniques were used to investigate the influence of squeezing rates on the yield stress of mortars in fresh state. The tested samples were prepared under similar conditions of room temperature and atmospheric pressure. The fresh mortars were tested at three squeezing rates (20 and 200mm/s) 15 minutes after mixing. The results show that the material’s yield stress increases with the increasing of the squeeze velocity. This increase is evident at low tensile speeds and is not obvious at high tack velocity. Elongational viscosity values increased as a result of the gap reduction for all the tested samples. However, when the squeeze speed was high, the strain rate increased because of the high displacement rates, a significant reduction in the mortar’s elongational viscosity was observed compared with those obtained when the squeeze speed was low. Despite that this behavior is associated with fluid-solid phase separation, which occurs for low displacement rates, these viscosity values actually represent the behavior of the material in practical situations when submitted to different velocities. The increase in the displacement rate of one order of magnitude caused a reduction in the viscosity of one order of magnitude.

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Influence of Tack Speed on The Rheological Properties of Mortar in Fresh State

Engineering, Technology & Applied Science Research ◽

10.48084/etasr.3756 ◽

2020 ◽

Vol 10 (5) ◽

pp. 6249-6252

Author(s):

V. T. Phan

Keyword(s):

Rheological Properties ◽

Yield Stress ◽

Atmospheric Pressure ◽

High Speed ◽

Room Temperature ◽

Elongational Viscosity ◽

Extensional Viscosity ◽

Squeeze Flow ◽

Fresh State ◽

Flow Techniques

In the present work, the squeeze flow techniques were used to investigate the influence of tack speed to the rheological properties of mortar in fresh sate, including yield stress and extensional viscosity.Tested samples were prepared under similar conditions of room temperature and atmospheric pressure. Compositions of mortars were tested at two different squeezing rates (20 and 200 mm/s) 15 min after mixing. Results indicate that mortar’s yield stress increases with the increasing of the pulling speed. This increase is evident at low tensile speeds. At high speed of tack, this increase is not obvious, especially in case of high squeeze speed of 200 mm/s. It can be concluded that the optima speed for removing the mortar and the upper surface is lower than 20 mm/s. The extensional viscosity of fresh mortars significantly decrease as the tack speed increases. Elongational viscosity values decreased as a result of gap increasing. The increase of the gap during tack experiment stimulates different units (grains getting far apart to each other) causing the observed decrease of the mortars' elongational viscosity

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In Situ Synthesis of Porous Carbons by Using Room-Temperature, Atmospheric-Pressure Dielectric Barrier Discharge Plasma as High-Performance Adsorbents for Solid-Phase Microextraction

Chemistry - A European Journal ◽

10.1002/chem.201500814 ◽

2015 ◽

Vol 21 (39) ◽

pp. 13618-13624 ◽

Cited By ~ 9

Author(s):

Yao Lin ◽

Li Wu ◽

Kailai Xu ◽

Yunfei Tian ◽

Xiandeng Hou ◽

...

Keyword(s):

Atmospheric Pressure ◽

Solid Phase Microextraction ◽

High Performance ◽

Room Temperature ◽

Discharge Plasma ◽

Barrier Discharge ◽

Solid Phase ◽

Dielectric Barrier Discharge Plasma ◽

Barrier Discharge Plasma

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Retraction: Feasibility Study of PM Elimination by Silent Discharge Type of DPF under Room Temperature and Atmospheric Pressure Condition

IEEJ Transactions on Fundamentals and Materials ◽

10.1541/ieejfms.131.151 ◽

2011 ◽

Vol 131 (2) ◽

pp. 151-152

Author(s):

Minoru Chuubachi ◽

Takeshi Nagasawa

Keyword(s):

Feasibility Study ◽

Atmospheric Pressure ◽

Room Temperature ◽

Pressure Condition ◽

Silent Discharge

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Luminescence Properties of Europium-Doped Yttrium Oxides Derived from Their Dodecylsulfate-Templated Mesostructure and Nanotube Forms

MRS Proceedings ◽

10.1557/proc-775-p3.2 ◽

2003 ◽

Vol 775 ◽

Cited By ~ 2

Author(s):

Tsuyoshi Kijima ◽

Kenichi Iwanaga ◽

Tomomi Hamasuna ◽

Shinji Mohri ◽

Mitsunori Yada ◽

...

Keyword(s):

Room Temperature ◽

Broad Band ◽

Concentration Quenching ◽

Precipitation Method ◽

Homogeneous Precipitation ◽

Bulk Materials ◽

Main Band ◽

Homogeneous Precipitation Method ◽

Order Of Magnitude ◽

Weak Luminescence

AbstractEuropium-doped hexagonal-mesostructured and nanotubular yttrium oxides templated by dodecylsulfate species as well as surfactant free bulk oxides were synthesized by the homogeneous precipitation method. All the as grown nanostructured or bulk materials with amorphous or poorly crystalline frameworks showed weak luminescence bands at room temperature. On calcination at 1000°C these materials were converted into highly crystalline yttrium oxides, resulting in a total increase in intensity of all the bands by one order of magnitude. In the hexagonal-mesostructured system, the main band due to the 5D0-7F2 transition for the calcined phases showed a sharp but asymmetrical multiplet splitting indicating multiple Eu sites. Concentration quenching was found at a Eu content of 3 mol% or above for these phases. In contrast, the main emission for the calcined solids in the nanotubular system occurred as poorly resolved broad band and the intensity of the main band at higher Eu content was significantly enhanced compared with those for the other two systems.

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Temperature Dependence of the Self-Assembled Styrene Based Random Ionomers in Aqueous Solution

MRS Proceedings ◽

10.1557/proc-775-p6.27 ◽

2003 ◽

Vol 775 ◽

Author(s):

Sung-Hwa Oh ◽

Ju-Myung Song ◽

Joon-Seop Kim ◽

Hyang-Rim Oh ◽

Jeong-A Yu

Keyword(s):

Partition Coefficients ◽

Room Temperature ◽

Aqueous Media ◽

The Self ◽

Spectroscopic Methods ◽

Ion Content ◽

Repeat Units ◽

Notable Effect ◽

Order Of Magnitude ◽

Experimental Errors

AbstractSolution behaviors of poly(styrene-co-sodium methacrylate) were studied by fluorescence spectroscopic methods using pyrene as a probe. The mol% of methacrylate was in the range 3.6–9.4. Water and N,N-dimethylforamide(DMF) mixture was used as a solvent (DMF/water = 0.2 mol %). The critical micelle (or aggregation) concentrations of ionomers and the partition coefficients of pyrene were obtained the temperature range 10–80°C. At room temperature, the values of CMCs (or CACs) were in the range 4.7 ×10-6 5.3 ×10-6 g/mL and we could not find any notable effect of the content of ionic repeat units within the experimental errors. Unlike CMCs, as the ion content increased, partitioning of pyrene between the hydrophobic aggregates and an aqueous media decreased from 1.5 ×105 to 9.4 ×104. As the temperature increased from 10 to 80 °C, the values of CMCs increased less than one order of magnitude. While, the partition coefficients of pyrene decreased one order of magnitude and the effect of the ion content became negligible.

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A Nylon Filter A-ELISA for Detecting Viruses in Water

Water Science & Technology ◽

10.2166/wst.1993.0544 ◽

1993 ◽

Vol 27 (7-8) ◽

pp. 135-141 ◽

Cited By ~ 3

Author(s):

Abidelfatah M. Nasser ◽

Yehudit Elkana ◽

Leon Goldstein

Keyword(s):

Positive Result ◽

Solid Phase ◽

Enteric Viruses ◽

High Specificity ◽

Negative Results ◽

Order Of Magnitude ◽

Lower Background

This study was designed to develop a modification of A-ELISA performed in microtitre plates. Nylon filters have been utilized successfully as a solid phase for the performance of A-ELISA. The use of nylon filters resulted in lower background than nitro-cellulose and paper filters, indicating their suitability as a solid phase for developing A-ELISA. With enteric viruses, human rotaviruses and MS-2 coliphage, negative results were obtained, suggesting high specificity of the developed technique for poliovirus 1. The sensitivity of the developed A-ELISA has been shown to be at least one order of magnitude greater than ordinary ELISA. A positive result with the nylon A-ELISA can be obtained with samples containing 100-1000 pfu/ml of poliovirus. Up to date methods used for detecting viruses in water are elaborate, time consuming and costly. Applying the nylon A-ELISA may overcome some of these disadvantages.

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Comparison of the Potency of 8-L-Arginine, 8-D-Arginine and 8-D-Homoarginine Vasopressin Analogs with Substituted Phenylalanine in Position 2

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19941439 ◽

1994 ◽

Vol 59 (6) ◽

pp. 1439-1450 ◽

Cited By ~ 2

Author(s):

Miroslava Žertová ◽

Jiřina Slaninová ◽

Zdenko Procházka

Keyword(s):

Amino Acid ◽

Solid Phase Synthesis ◽

Solid Phase ◽

Basic Amino Acid ◽

The Other ◽

Side Chain ◽

Inhibitory Potency ◽

Phase Synthesis ◽

Other Hand ◽

Order Of Magnitude

An analysis of the uterotonic potencies of all analogs having substituted L- or D-tyrosine or -phenylalanine in position 2 and L-arginine, D-arginine or D-homoarginine in position 8 was made. The series of analogs already published was completed by the solid phase synthesis of ten new analogs having L- or D-Phe, L- or D-Phe(2-Et), L- or D-Phe(2,4,6-triMe) or D-Tyr(Me) in position 2 and either L- or D-arginine in position 8. All newly synthesized analogs were found to be uterotonic inhibitors. Deamination increases both the agonistic and antagonistic potency. In the case of phenylalanine analogs the change of configuration from L to D in position 2 enhances the uterotonic inhibition for more than 1 order of magnitude. The L to D change in position 8 enhances the inhibitory potency negligibly. Prolongation of the side chain of the D-basic amino acid in position 8 seems to decrease slightly the inhibitory potency if there is L-substituted amino acid in position 2. On the other hand there is a tendency to the increase of the inhibitory potency if there is D-substituted amino acid in position 2.

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68Ga, 44Sc and 177Lu-labeled AAZTA5-PSMA-617: synthesis, radiolabeling, stability and cell binding compared to DOTA-PSMA-617 analogues

EJNMMI Radiopharmacy and Chemistry ◽

10.1186/s41181-020-00107-8 ◽

2020 ◽

Vol 5 (1) ◽

Author(s):

Jean-Philippe Sinnes ◽

Ulrike Bauder-Wüst ◽

Martin Schäfer ◽

Euy Sung Moon ◽

Klaus Kopka ◽

...

Keyword(s):

Human Serum ◽

Room Temperature ◽

Solid Phase ◽

Negative Influence ◽

Binding Motif ◽

Lncap Cells ◽

Cell Binding ◽

Binding Characteristics

Abstract Background The AAZTA chelator and in particular its bifunctional derivative AAZTA5 was recently investigated to demonstrate unique capabilities to complex diagnostic and therapeutic trivalent radiometals under mild conditions. This study presents a comparison of 68Ga, 44Sc and 177Lu-labeled AAZTA5-PSMA-617 with DOTA-PSMA-617 analogues. We evaluated the radiolabeling characteristics, in vitro stability of the radiolabeled compounds and evaluated their binding affinity and internalization behavior on LNCaP tumor cells in direct comparison to the radiolabeled DOTA-conjugated PSMA-617 analogs. Results AAZTA5 was synthesized in a five-step synthesis and coupled to the PSMA-617 backbone on solid phase. Radiochemical evaluation of AAZTA5-PSMA-617 with 68Ga, 44Sc and 177Lu achieved quantitative radiolabeling of > 99% after less than 5 min at room temperature. Stabilities against human serum, PBS buffer and EDTA and DTPA solutions were analyzed. While there was a small degradation of the 68Ga complex over 2 h in human serum, PBS and EDTA/DTPA, the 44Sc and 177Lu complexes were stable at 2 h and remained stable over 8 h and 1 day. For all three compounds, i.e. [natGa]Ga-AAZTA5-PSMA-617, [natSc]Sc-AAZTA5-PSMA-617 and [natLu]Lu-AAZTA5-PSMA-617, in vitro studies on PSMA-positive LNCaP cells were performed in direct comparison to radiolabeled DOTA-PSMA-617 yielding the corresponding inhibition constants (Ki). Ki values were in the range of 8–31 nM values which correspond with those of [natGa]Ga-DOTA-PSMA-617, [natSc]Sc-DOTA-PSMA-617 and [natLu]Lu-DOTA-PSMA-617, i.e. 5–7 nM, respectively. Internalization studies demonstrated cellular membrane to internalization ratios for the radiolabeled 68Ga, 44Sc and 177Lu-AAZTA5-PSMA-617 tracers (13–20%IA/106 cells) in the same range as the ones of the three radiolabeled DOTA-PSMA-617 tracers (17–20%IA/106 cells) in the same assay. Conclusions The AAZTA5-PSMA-617 structure proved fast and quantitative radiolabeling with all three radiometal complexes at room temperature, excellent stability with 44Sc, very high stability with 177Lu and medium stability with 68Ga in human serum, PBS and EDTA/DTPA solutions. All three AAZTA5-PSMA-617 tracers showed binding affinities and internalization ratios in LNCaP cells comparable with that of radiolabeled DOTA-PSMA-617 analogues. Therefore, the exchange of the chelator DOTA with AAZTA5 within the PSMA-617 binding motif has no negative influence on in vitro LNCaP cell binding characteristics. In combination with the faster and milder radiolabeling features, AAZTA5-PSMA-617 thus demonstrates promising potential for in vivo application for theranostics of prostate cancer.

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Non-Destructive Detection of Pentachlorophenol Residues in Historical Wooden Objects

Polymers ◽

10.3390/polym13071052 ◽

2021 ◽

Vol 13 (7) ◽

pp. 1052

Author(s):

Ida Kraševec ◽

Nataša Nemeček ◽

Maja Lozar Štamcar ◽

Irena Kralj Cigić ◽

Helena Prosen

Keyword(s):

Indoor Air ◽

Room Temperature ◽

Quantitative Methods ◽

Solid Phase ◽

Contact Mode ◽

Solvent Extraction Method ◽

Museum Objects ◽

Wooden Furniture ◽

Non Destructive ◽

Heritage Collections

Wood is a natural polymeric material that is an important constituent of many heritage collections. Because of its susceptibility to biodegradation, it is often chemically treated with substances that can be harmful to human health. One of the most widely used wood preservatives was pentachlorophenol (PCP), which is still present in museum objects today, although its use has been restricted for about forty years. The development of non-destructive methods for its determination, suitable for the analysis of valuable objects, is therefore of great importance. In this work, two non-destructive solid-phase microextraction (SPME) methods were developed and optimized, using either headspace or contact mode. They were compared with a destructive solvent extraction method and found to be suitable for quantification in the range of 7.5 to 75 mg PCP/kg wood at room temperature. The developed semi-quantitative methods were applied in the wooden furniture depot of National Museum of Slovenia. PCP was detected inside two furniture objects using headspace mode. The pesticide lindane was also detected in one object. The indoor air of the depot with furniture was also sampled with HS SPME, and traces of PCP were found. According to the results, SPME methods are suitable for the detection of PCP residues in museum objects and in the environment.

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