scholarly journals Extremely High-Rate, Uniform Dissolution of Alloy 22 in Anhydrous Organic Solutions at Room Temperature

CORROSION ◽  
10.5006/2081 ◽  
2016 ◽  
Vol 72 (10) ◽  
pp. 1292-1299 ◽  
Author(s):  
E.J. Schindelholz ◽  
M.A. Christie ◽  
S.P. Allwein ◽  
R.G. Kelly

2019 ◽  
Author(s):  
Meifeng Wang ◽  
Liyin Zhang ◽  
Yiqun Li ◽  
Liuqun Gu

<p></p>Anomerization of glycosides were rarely performed under basic condition due to lack of efficiency. Here an imidazole promoted anomerization of β-D-glucose pentaacetate was developed; and reaction could proceed in both organic solvents and solid state at room temperature. Although mechanism is not yet clear, this unprecedent mild anomerization in solid state may open a new promising way for stereoseletive anomerization of broad glucosides and materials design in the future..



2020 ◽  
Vol 41 (Supplement_1) ◽  
pp. S169-S170
Author(s):  
Angela R Jockheck-Clark ◽  
Cortes Williams ◽  
Christine Kowalczewski ◽  
Jahnabi Roy ◽  
Marc A Thompson ◽  
...  

Abstract Introduction During periods of delayed burn treatment, cells within the eschar leach toxic and immunomodulatory metabolites that can profoundly impact neighboring tissue. Therefore, to reduce the burn-related morbidities and mortalities that are the result of delayed surgical interventions, electrospinning was utilized to generate a novel cerium (III) nitrate (Ce(III)N) dressing. Previously published work has demonstrated that topical Ce(III)N application changes the eschar morphology, and that tissue beneath the treated eschar was generally healthy and had a high rate of graft acceptance. Methods Ce(III)N was dissolved with polyethylene oxide and spun onto a grounded rotating mandrel. The uni-axially spun mesh was compared to a co-axially electrospun dressing that contained a Ce(III)N core. Dressings were evaluated for topography/morphology, porosity and oxygen permeation using scanning electron microscopy, helium pycnometry, and a gas exchange chamber, respectively. Ce(III)N release rates were evaluated, as well as 60-day storage stability. Results All electrospun dressings contained functional Ce(III)N, with the co-axially spun dressing containing three times the amount of Ce(III)N as the traditionally spun dressing. Uni-axially and co-axially spun nanofibers had diameters of 1487±560 nm and 1071±147 nm, and porosities of 83.9% and 74.1%, respectively. Scaffolds released the majority of Ce(III)N within the first hour of wetting. Conclusions All dressings were capable of a burst of Ce(III)N release and maintained stability when stored at room temperature for 60 days. Applicability of Research to Practice Despite advancement in protective equipment worn by military personnel, the incidence of thermal injury is expected to rise in future conflicts. There are no burn wound dressings that can mitigate the pathophysiological processes associated with delayed burn wound treatment.





2020 ◽  
Vol 27 (2) ◽  
pp. 319-328 ◽  
Author(s):  
Leonardo Abbene ◽  
Fabio Principato ◽  
Gaetano Gerardi ◽  
Antonino Buttacavoli ◽  
Donato Cascio ◽  
...  

In this work, the spectroscopic performances of new cadmium–zinc–telluride (CZT) pixel detectors recently developed at IMEM-CNR of Parma (Italy) are presented. Sub-millimetre arrays with pixel pitch less than 500 µm, based on boron oxide encapsulated vertical Bridgman grown CZT crystals, were fabricated. Excellent room-temperature performance characterizes the detectors even at high-bias-voltage operation (9000 V cm−1), with energy resolutions (FWHM) of 4% (0.9 keV), 1.7% (1 keV) and 1.3% (1.6 keV) at 22.1, 59.5 and 122.1 keV, respectively. Charge-sharing investigations were performed with both uncollimated and collimated synchrotron X-ray beams with particular attention to the mitigation of the charge losses at the inter-pixel gap region. High-rate measurements demonstrated the absence of high-flux radiation-induced polarization phenomena up to 2 × 106 photons mm−2 s−1. These activities are in the framework of an international collaboration on the development of energy-resolved photon-counting systems for high-flux energy-resolved X-ray imaging.



2015 ◽  
Vol 27 (8) ◽  
pp. 3143-3149 ◽  
Author(s):  
Yuan-Li Ding ◽  
Yuren Wen ◽  
Peter A. van Aken ◽  
Joachim Maier ◽  
Yan Yu


2017 ◽  
Vol 748 ◽  
pp. 127-131 ◽  
Author(s):  
Wu Lin Li ◽  
Wen Jing Yang ◽  
Mei Long ◽  
Gen Rong Li ◽  
Yan Ma ◽  
...  

The quasi-regular arrangements porous silicon was fabricated by by electrochemical process using organic solutions with front-side illumination, and SEM showed that the morphology of porous silicon was dependent sensitively on the current density, organic electrolytes and their concentration. The results indicate that N-dimethylformamide (DMF) is the best organic solution and quasi-regular arranged pores can be well organized in 20%HF/DMF solution. The luminescence shows fresh porous silicon can emit the red luminescence at room temperature and quench after nanoporous layer destroyed.



2019 ◽  
Vol 9 (29) ◽  
pp. 1970113
Author(s):  
Jihui Lang ◽  
Chunlei Jiang ◽  
Yue Fang ◽  
Lei Shi ◽  
Shijie Miao ◽  
...  


2019 ◽  
Author(s):  
Meifeng Wang ◽  
Liyin Zhang ◽  
Yiqun Li ◽  
Liuqun Gu

<p></p>Anomerization of glycosides were rarely performed under basic condition due to lack of efficiency. Here an imidazole promoted anomerization of β-D-glucose pentaacetate was developed; and reaction could proceed in both organic solvents and solid state at room temperature. Although mechanism is not yet clear, this unprecedent mild anomerization in solid state may open a new promising way for stereoseletive anomerization of broad glucosides and materials design in the future..



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