The Corrosion of Cast Duplex Stainless Steels in Seawater and Sour Brines

CORROSION ◽  
10.5006/3284 ◽  
2019 ◽  
Vol 75 (11) ◽  
pp. 1383-1390 ◽  
Author(s):  
Roger Francis ◽  
Stan Hebdon

Modern duplex stainless steels have been in use since the early 1970s and cast versions of the wrought alloys were soon in demand for pumps and valves. Since that time a range of cast duplex stainless steels have been developed with a wide range of compositions, but all with approximately 50/50 austenite/ferrite phase balance and deliberate additions of nitrogen. This paper presents some comparative corrosion data on a range of cast duplex stainless steels, mainly in seawater. The differences in performance related to composition and microstructure are discussed. Corrosion data in lower chloride brines are also presented to show the limits of use of some lower alloyed duplex materials. In addition to oxidizing chloride solutions, some data are presented on cast duplex stainless steels in reducing brines containing H2S, where the main corrosion problem is sulfide stress corrosion cracking. Finally, the importance of using a suitable technical specification, over and above ASTM, combined with selecting a suitably skilled foundry in order to obtain satisfactory castings is discussed.


1974 ◽  
Vol 17 (3) ◽  
pp. 234-239
Author(s):  
Daizo Yamasaki ◽  
Toshikazu Shinkawa ◽  
Sadato Shigemura


Author(s):  
Hiroyuki Iwamoto ◽  
Fumiyoshi Minami

Abstract A Japanese welding guideline for duplex stainless steels (DSSs)1) has been developed in a Sub-Committee of Chemical Plant Welding Research Committee in the Japan Welding Engineering Society. The guideline recommends 13 key points as a basis to prevent the unforeseen corrosion of weldments, which are based on practical experience in Japanese Oil & Gas and Chemical industries and similar published guidelines. The principal concept is how to obtain an acceptable ratio of ferrite/austenite phase balance along with no detrimental intermetallic compounds in the weld metal and heat affected zone. For the weld metal, consumable selection, the shielding and purging gas composition and weld heat input control are most critical. For HAZ, the nitrogen content of the base metal is most critical. This guideline is developed for DSS welders and welding engineers so as to understand the difference of DSS from standard austenitic stainless steel. This guideline is composed of three parts, the first is 13 basic recommendations, the second is to explain some technical aspects for these 13 key points and the third contains comprehensive data relating DSS base metal and weld metal including some important key points for each step of fabrication to understand the welding characteristics of DSS clearly. This paper introduces the basic 13 recommendations for guidance purpose in addition to the mandatory requirements of the construction code in Japan.









Author(s):  
Robert N Gunn




Alloy Digest ◽  
2012 ◽  
Vol 61 (4) ◽  

Abstract Stoody AP stainless steel wires are all-position wires. The nickel in this product will achieve a good balance of austenite and ferrite in lean duplex stainless steels. This datasheet provides information on composition and tensile properties as well as fracture toughness. It also includes information on forming and joining. Filing Code: SS-1118. Producer or source: Stoody Company.





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