scholarly journals Catalytic Process in Producing Green Aromatics through Fast Pyrolysis of Wood of Five Tropical Fast Growing Trees Species

2021 ◽  
Vol 12 (1) ◽  
pp. 18-27
Author(s):  
Joko Sulistyo ◽  
Toshimitsu Hata ◽  
Ganis Lukmandaru ◽  
Yunida Syafriani ◽  
Sensho Honma

The generation of liquid fuels and chemicals is potential through a catalytic fast pyrolysis (CFP) which is a rapid, inexpensive, and promising method utilizing tropical wood biomass as starting material. There is a little known in the potential of wood biomass from tropical fast-growing trees as starting materials for the production of liquid fuel and chemicals. In this study the formation of aromatics by pyrolytic-gas chromatography/mass spectroscopy (Py-GC/MS) is evaluated on the effect of wood species with different characteristics and its cellulose component to the formation of aromatics. Fast pyrolysis of eucalyptus wood characterized with low content of ash and high percentages of hollocellulose and α-cellulose produced much high relative peaks of levoglucosan and small relative peaks of lignin derived products. Meanwhile high content of vollatile matter and high crystallinity of cellulose attributed balsa and jabon woods as feedstock for fast pyrolysis. The catalytic process in fast pyrolysis of eucalyptus decomposed the most of oxygenated compound such as levoglucosan and furfural into aromatics in the presence of ZSM-5. Coke formation on the surface catalyst might lead partly of decomposition of levoglucosan and furfural to form aromatics in the catalytic fast pyrolysis of balsa wood. Cellulose component determined on the formation of benzene, toluene, styrene, p-xylene, indane, indene, and naphthalene in catalytic fast pyrolysis of wood.

RSC Advances ◽  
2015 ◽  
Vol 5 (69) ◽  
pp. 56286-56292 ◽  
Author(s):  
Bo Zhang ◽  
Zhaoping Zhong ◽  
Qinglong Xie ◽  
Paul Chen ◽  
Roger Ruan

External surface modification of HZSM-5 can promote the formation of aromatics and olefins and reduce coke yield.


Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 685
Author(s):  
Zeyu Xue ◽  
Zhaoping Zhong ◽  
Bo Zhang

To delve into the law of hydrocarbon production in microwave-assisted catalytic fast pyrolysis (MACFP) of corn straw, physical mixed Mesoporous Crystalline Material-41 (MCM-41) and Zeolite Socony Mobile-5 (ZSM-5) catalyst prototypes were exploited in this study. Besides, the effects exerted by temperature of reaction and MCM-41/ZSM-5 mass ratio were explored. As revealed from the results, carbon outputs of hydrocarbons rose initially as the temperature of MACFP rose and reached the maximal data at 550 °C; subsequently, it declined as reaction temperature rose. Moreover, the MCM-41/ZSM-5 mass ratio of 1:2 was second-to-none for hydrocarbon formation in the course of biomass MACFP. It was reported that adding MCM-41 can hinder coke formation on ZSM-5. Furthermore, MCM-41/ZSM-5 mixture exhibited more significant catalytic activity than ZSM-5/MCM-41 composite, demonstrating that hydrocarbon producing process can be stimulated by a simple physical MCM-41 and ZSM-5 catalysts mixture instead of synthesizing complex hierarchically-structured ZSM-5/MCM-41 composite.


2019 ◽  
Vol 143 ◽  
pp. 104669 ◽  
Author(s):  
Qiang Lu ◽  
Zhen-xi Zhang ◽  
Xiao-ning Ye ◽  
Kai Li ◽  
Min-shu Cui ◽  
...  

2021 ◽  
Vol 9 (3) ◽  
pp. 1235-1245
Author(s):  
Richard J. French ◽  
Kristiina Iisa ◽  
Kellene A. Orton ◽  
Michael B. Griffin ◽  
Earl Christensen ◽  
...  

2021 ◽  
Vol 127 ◽  
pp. 141-146
Author(s):  
Jun Zhang ◽  
Jing Gu ◽  
Haoran Yuan ◽  
Yong Chen

2013 ◽  
Vol 455 ◽  
pp. 114-121 ◽  
Author(s):  
Xiangyu Li ◽  
Haifeng Zhang ◽  
Jian Li ◽  
Lu Su ◽  
Jiane Zuo ◽  
...  

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