scholarly journals Ozone trends derived from the total column and vertical profiles at a northern mid-latitude station

2013 ◽  
Vol 13 (20) ◽  
pp. 10373-10384 ◽  
Author(s):  
P. J. Nair ◽  
S. Godin-Beekmann ◽  
J. Kuttippurath ◽  
G. Ancellet ◽  
F. Goutail ◽  
...  
Keyword(s):  
Heat Flux ◽  
Stratospheric Ozone ◽  
Solar Flux ◽  
Quasi Biennial Oscillation ◽  
Data Set ◽  
Total Column Ozone ◽  
Latitude Station ◽  
Ozone Trends ◽  
Column Ozone ◽  
Total Column

Abstract. The trends and variability of ozone are assessed over a northern mid-latitude station, Haute-Provence Observatory (OHP: 43.93° N, 5.71° E), using total column ozone observations from the Dobson and Système d'Analyse par Observation Zénithale spectrometers, and stratospheric ozone profile measurements from light detection and ranging (lidar), ozonesondes, Stratospheric Aerosol and Gas Experiment (SAGE) II, Halogen Occultation Experiment (HALOE) and Aura Microwave Limb Sounder (MLS). A multivariate regression model with quasi-biennial oscillation (QBO), solar flux, aerosol optical thickness, heat flux, North Atlantic Oscillation (NAO) and a piecewise linear trend (PWLT) or equivalent effective stratospheric chlorine (EESC) functions is applied to the ozone anomalies. The maximum variability of ozone in winter/spring is explained by QBO and heat flux in the ranges 15–45 km and 15–24 km, respectively. The NAO shows maximum influence in the lower stratosphere during winter, while the solar flux influence is largest in the lower and middle stratosphere in summer. The total column ozone trends estimated from the PWLT and EESC functions are of −1.47 ± 0.27 and −1.40 ± 0.25 DU yr−1, respectively, over the period 1984–1996 and about 0.55 ± 0.30 and 0.42 ± 0.08 DU yr−1, respectively, over the period 1997–2010. The ozone profiles yield similar and significant EESC-based and PWLT trends for 1984–1996, and are about −0.5 and −0.8% yr−1 in the lower and upper stratosphere, respectively. For 1997–2010, the EESC-based and PWLT estimates are of the order of 0.3 and 0.1% yr−1, respectively, in the 18–28 km range, and at 40–45 km, EESC provides significant ozone trends larger than the insignificant PWLT results. Furthermore, very similar vertical trends for the respective time periods are also deduced from another long-term satellite-based data set (GOZCARDS–Global OZone Chemistry And Related trace gas Data records for the Stratosphere) sampled at northern mid-latitudes. Therefore, this analysis unveils ozone recovery signals from total column ozone and profile measurements at OHP, and hence in the northern mid-latitudes.

scholarly journals Ozone trends derived from the total column and vertical profiles at a northern mid-latitude station

2013 ◽  
Vol 13 (3) ◽  
pp. 7081-7112 ◽  
Author(s):  
P. J. Nair ◽  
S. Godin-Beekmann ◽  
J. Kuttippurath ◽  
G. Ancellet ◽  
F. Goutail ◽  
...  
Keyword(s):  
Heat Flux ◽  
Linear Trend ◽  
Stratospheric Ozone ◽  
Solar Flux ◽  
Quasi Biennial Oscillation ◽  
Total Column Ozone ◽  
Latitude Station ◽  
Ozone Trends ◽  
Column Ozone ◽  
Total Column

Abstract. The trends and variability of ozone are assessed over a northern mid-latitude station, Haute-Provence Observatory (OHP – 43.93° N, 5.71° E), using total column ozone observations from the Dobson and Système d'Analyse par Observation Zénithale spectrometers, and stratospheric ozone profile measurements from Light detection and ranging, ozonesondes, Stratospheric Aerosol and Gas Experiment II, Halogen Occultation Experiment and Aura Microwave Limb Sounder. A multi-variate regression model with quasi biennial oscillation (QBO), solar flux, aerosol optical thickness, heat flux, North Atlantic oscillation (NAO) and piecewise linear trend (PWLT) or Equivalent Effective Stratospheric Chlorine (EESC) functions is applied to the ozone anomalies. The maximum variability of ozone in winter/spring is explained by QBO and heat flux in 15–45 km and in 15–24 km, respectively. The NAO shows maximum influence in the lower stratosphere during winter while the solar flux influence is largest in the lower and middle stratosphere in summer. The total column ozone trends estimated from the PWLT and EESC functions are of −1.39±0.26 and −1.40±0.25 DU yr−1, respectively over 1984–1996 and about 0.65±0.32 and 0.42±0.08 DU yr−1, respectively over 1997–2010. The ozone profiles yield similar and significant EESC-based and PWLT trends in 1984–1996 and are about −0.5 and −0.8 % yr−1 in the lower and upper stratosphere, respectively. In 1997–2010, the EESC-based and PWLT trends are significant and of order 0.3 and 0.1 % yr−1, respectively in the 18–28 km range, and at 40–45 km, EESC provides significant ozone trends larger than the insignificant PWLT results. Therefore, this analysis unveils ozone recovery signals from total column ozone and profile measurements at OHP, and hence in the mid-latitudes.

scholarly journals Statistical diagnostic and correction of a chemistry-transport model for the prediction of total column ozone

2006 ◽  
Vol 6 (2) ◽  
pp. 525-537 ◽  
Author(s):  
S. Guillas ◽  
G. C. Tiao ◽  
D. J. Wuebbles ◽  
A. Zubrow
Keyword(s):  
Transport Model ◽  
Chemical Transport ◽  
Satellite System ◽  
Chemical Transport Model ◽  
Quasi Biennial Oscillation ◽  
Data Set ◽  
Total Column Ozone ◽  
Noise Component ◽  
Column Ozone ◽  
Total Column

Abstract. In this paper, we introduce a statistical method for examining and adjusting chemical-transport models. We illustrate the findings with total column ozone predictions, based on the University of Illinois at Urbana-Champaign 2-D (UIUC 2-D) chemical-transport model of the global atmosphere. We propose a general diagnostic procedure for the model outputs in total ozone over the latitudes ranging from 60° South to 60° North to see if the model captures some typical patterns in the data. The method proceeds in two steps to avoid possible collinearity issues. First, we regress the measurements given by a cohesive data set from the SBUV(/2) satellite system on the model outputs with an autoregressive noise component. Second, we regress the residuals of this first regression on the solar flux, the annual cycle, the Antarctic or Arctic Oscillation, and the Quasi Biennial Oscillation. If the coefficients from this second regression are statistically significant, then they mean that the model did not simulate properly the pattern associated with these factors. Systematic anomalies of the model are identified using data from 1979 to 1995, and statistically corrected afterwards. The 1996–2003 validation sample confirms that the combined approach yields better predictions than the direct UIUC 2-D outputs.

scholarly journals A global historical ozone data set and prominent features of stratospheric variability prior to 1979

2013 ◽  
Vol 13 (18) ◽  
pp. 9623-9639 ◽  
Author(s):  
S. Brönnimann ◽  
J. Bhend ◽  
J. Franke ◽  
S. Flückiger ◽  
A. M. Fischer ◽  
...  
Keyword(s):  
Solar Cycle ◽  
Greenhouse Gases ◽  
Southern Oscillation ◽  
Observation Error ◽  
Quasi Biennial Oscillation ◽  
Data Set ◽  
Total Column Ozone ◽  
Ozone Data ◽  
Column Ozone ◽  
Total Column

Abstract. We present a vertically resolved zonal mean monthly mean global ozone data set spanning the period 1901 to 2007, called HISTOZ.1.0. It is based on a new approach that combines information from an ensemble of chemistry climate model (CCM) simulations with historical total column ozone information. The CCM simulations incorporate important external drivers of stratospheric chemistry and dynamics (in particular solar and volcanic effects, greenhouse gases and ozone depleting substances, sea surface temperatures, and the quasi-biennial oscillation). The historical total column ozone observations include ground-based measurements from the 1920s onward and satellite observations from 1970 to 1976. An off-line data assimilation approach is used to combine model simulations, observations, and information on the observation error. The period starting in 1979 was used for validation with existing ozone data sets and therefore only ground-based measurements were assimilated. Results demonstrate considerable skill from the CCM simulations alone. Assimilating observations provides additional skill for total column ozone. With respect to the vertical ozone distribution, assimilating observations increases on average the correlation with a reference data set, but does not decrease the mean squared error. Analyses of HISTOZ.1.0 with respect to the effects of El Niño–Southern Oscillation (ENSO) and of the 11 yr solar cycle on stratospheric ozone from 1934 to 1979 qualitatively confirm previous studies that focussed on the post-1979 period. The ENSO signature exhibits a much clearer imprint of a change in strength of the Brewer–Dobson circulation compared to the post-1979 period. The imprint of the 11 yr solar cycle is slightly weaker in the earlier period. Furthermore, the total column ozone increase from the 1950s to around 1970 at northern mid-latitudes is briefly discussed. Indications for contributions of a tropospheric ozone increase, greenhouse gases, and changes in atmospheric circulation are found. Finally, the paper points at several possible future improvements of HISTOZ.1.0.

scholarly journals Evaluation of tropospheric and stratospheric ozone trends over Western Europe from ground-based FTIR network observations

2008 ◽  
Vol 8 (23) ◽  
pp. 6865-6886 ◽  
Author(s):  
C. Vigouroux ◽  
M. De Mazière ◽  
P. Demoulin ◽  
C. Servais ◽  
F. Hase ◽  
...  
Keyword(s):  
Time Series ◽  
Western Europe ◽  
Stratospheric Ozone ◽  
Estimation Method ◽  
Optimal Estimation ◽  
Atmospheric Composition ◽  
Total Column Ozone ◽  
Ozone Trends ◽  
Column Ozone ◽  
Total Column

Abstract. Within the European project UFTIR (Time series of Upper Free Troposphere observations from an European ground-based FTIR network), six ground-based stations in Western Europe, from 79° N to 28° N, all equipped with Fourier Transform infrared (FTIR) instruments and part of the Network for the Detection of Atmospheric Composition Change (NDACC), have joined their efforts to evaluate the trends of several direct and indirect greenhouse gases over the period 1995–2004. The retrievals of CO, CH4, C2H6, N2O, CHClF2, and O3 have been optimized. Using the optimal estimation method, some vertical information can be obtained in addition to total column amounts. A bootstrap resampling method has been implemented to determine annual partial and total column trends for the target gases. The present work focuses on the ozone results. The retrieved time series of partial and total ozone columns are validated with ground-based correlative data (Brewer, Dobson, UV-Vis, ozonesondes, and Lidar). The observed total column ozone trends are in agreement with previous studies: 1) no total column ozone trend is seen at the lowest latitude station Izaña (28° N); 2) slightly positive total column trends are seen at the two mid-latitude stations Zugspitze and Jungfraujoch (47° N), only one of them being significant; 3) the highest latitude stations Harestua (60° N), Kiruna (68° N) and Ny-Ålesund (79° N) show significant positive total column trends. Following the vertical information contained in the ozone FTIR retrievals, we provide partial columns trends for the layers: ground-10 km, 10–18 km, 18–27 km, and 27–42 km, which helps to distinguish the contributions from dynamical and chemical changes on the total column ozone trends. We obtain no statistically significant trends in the ground-10 km layer for five out of the six ground-based stations. We find significant positive trends for the lowermost stratosphere at the two mid-latitude stations, and at Ny-Ålesund. We find smaller, but significant trends for the 18–27 km layer at Kiruna, Harestua, Jungfraujoch, and Izaña. The results for the upper layer are quite contrasted: we find significant positive trends at Kiruna, Harestua, and Jungfraujoch, and significant negative trends at Zugspitze and Izaña. These ozone partial columns trends are discussed and compared with previous studies.

scholarly journals Evaluation of tropospheric and stratospheric ozone trends over Western Europe from ground-based FTIR network observations

2008 ◽  
Vol 8 (2) ◽  
pp. 5007-5060 ◽  
Author(s):  
C. Vigouroux ◽  
M. De Mazière ◽  
P. Demoulin ◽  
C. Servais ◽  
F. Hase ◽  
...  
Keyword(s):  
Time Series ◽  
Western Europe ◽  
Stratospheric Ozone ◽  
Estimation Method ◽  
Optimal Estimation ◽  
Atmospheric Composition ◽  
Total Column Ozone ◽  
Ozone Trends ◽  
Column Ozone ◽  
Total Column

Abstract. Within the European project UFTIR (Time series of Upper Free Troposphere observations from an European ground-based FTIR network), six ground-based stations in Western Europe, from 79° N to 28° N, all equipped with Fourier Transform infrared (FTIR) instruments and part of the Network for the Detection of Atmospheric Composition Change (NDACC), have joined their efforts to evaluate the trend of several direct and indirect greenhouse gases over the period 1995–2004. The retrievals of CO, CH4, C2H6, N2O, CHClF2, and O3 have been optimized. Using the optimal estimation method, some vertical information can be obtained in addition to total column amounts. A bootstrap resampling method has been implemented to determine annual partial and total column trends for the target gases. The present work focuses on the ozone results. The retrieved time series of partial and total ozone columns are validated with ground-based correlative data (Brewer, Dobson, UV-Vis, ozonesondes, and Lidar). The observed total column ozone trends are in agreement with previous studies: 1) no total column ozone trend is seen at the lowest latitude station Izaña (28° N); 2) slightly positive total column trends are seen at the two mid-latitude stations Zugspitze and Jungfraujoch (47° N), only one of them being significant; 3) the highest latitude stations Harestua (60° N), Kiruna (68° N) and Ny-Ålesund (79° N) show significant positive total column trends. Following the vertical information contained in the ozone FTIR retrievals, we provide partial columns trends for the layers: ground-10 km, 10–18 km, 18–27 km, and 27–42 km, which helps to distinguish the contributions from dynamical and chemical changes on the total column ozone trends. We obtain no statistically significant trends in the ground–10 km layer for five out of the six ground-based stations. We find significant positive trends for the lowermost stratosphere at the two mid-latitude stations, and at Ny-Ålesund. We find smaller, but significant trends for the 18–27 km layer at Kiruna, Harestua, Jungfraujoch, and Izaña. The results for the upper layer are quite contrasted: we find significant positive trends at Kiruna, Harestua, and Jungfraujoch, and significant negative trends at Zugspitze and Izaña. These ozone partial columns trends are discussed and confronted to previous studies.

scholarly journals Statistical diagnostic and correction of a chemistry-transport model for the prediction of total column ozone

2005 ◽  
Vol 5 (5) ◽  
pp. 10421-10453 ◽  
Author(s):  
S. Guillas ◽  
G. C. Tiao ◽  
D. J. Wuebbles ◽  
A. Zubrow
Keyword(s):  
Transport Model ◽  
Chemical Transport ◽  
Satellite System ◽  
Chemical Transport Model ◽  
Quasi Biennial Oscillation ◽  
Data Set ◽  
Total Column Ozone ◽  
Noise Component ◽  
Column Ozone ◽  
Total Column

Abstract. In this paper, we introduce a statistical method for examining and adjusting chemical-transport models. We illustrate the findings with total column ozone predictions, based on the University of Illinois at Urbana-Champaign 2-D (UIUC 2-D) chemical-transport model of the global atmosphere. We propose a general diagnostic procedure for the model outputs in total ozone over the latitudes ranging from 60° South to 60° North to see if the model captures some typical patterns in the data. The method proceeds in two steps to avoid possible collinearity issues. First, we regress the measurements given by a cohesive data set from the SBUV(/2) satellite system on the model outputs with an autoregressive noise component. Second, we regress the residuals of this first regression on the solar flux, the annual cycle, the Antarctic or Arctic Oscillation, and the Quasi Biennial Oscillation. If the coefficients from this second regression are statistically significant, then they mean that the model did not simulate properly the pattern associated with these factors. Systematic anomalies of the model are identified using data from 1979 to 1995, and statistically corrected afterwards. The 1996–2003 validation sample confirms that the combined approach yields better predictions than the direct UIUC 2-D outputs.

scholarly journals Trend Quality Ozone from NPP OMPS: the Version 2 Processing

2018 ◽  
Author(s):  
Richard McPeters ◽  
Stacey Frith ◽  
Natalya Kramarova ◽  
Jerry Ziemke ◽  
Gordon Labow
Keyword(s):  
Trend Analysis ◽  
Tropospheric Ozone ◽  
Scattered Light ◽  
Stratospheric Ozone ◽  
Total Column Ozone ◽  
Average Bias ◽  
Latitude Zone ◽  
Zonal Average ◽  
Column Ozone ◽  
Total Column

Abstract. A version 2 processing of data from two ozone monitoring instruments on Suomi NPP, the OMPS nadir ozone mapper and the OMPS nadir ozone profiler, has now been completed. The previously released data were useful for many purposes but were not suitable for use in ozone trend analysis. In this processing, instrument artifacts have been identified and corrected, an improved scattered light correction and wavelength registration have been applied, and soft calibration techniques were implemented to produce a calibration consistent with data from the series of SBUV/2 instruments. The result is a high quality ozone time series suitable for trend analysis. Total column ozone data from the OMPS nadir mapper now agree with data from the SBUV/2 instrument on NOAA 19 with a zonal average bias of −0.2 % over the 60° S to 60° N latitude zone. Differences are somewhat larger between OMPS nadir profiler and N19 total column ozone, with an average difference of −1.1  % over the 60° S to 60° N latitude zone and a residual seasonal variation of about 2 % at latitudes higher than about 50 degrees. For the profile retrieval, zonal average ozone in the upper stratosphere (between 2.5 and 4 hPa) agrees with that from NOAA 19 within ±3 % and an average bias of −1.1 %. In the lower stratosphere (between 25 and 40 hPa) agreement is within ±3 % with an average bias of +1.1 %. Tropospheric ozone produced by subtracting stratospheric ozone measured by the OMPS limb profiler from total column ozone measured by the nadir mapper is consistent with tropospheric ozone produced by subtracting stratospheric ozone from MLS from total ozone from the OMI instrument on Aura. The agreement of tropospheric ozone is within 10 % in most locations.

scholarly journals Indicators of Antarctic ozone depletion

2005 ◽  
Vol 5 (3) ◽  
pp. 3811-3845 ◽  
Author(s):  
G. E. Bodeker ◽  
H. Shiona ◽  
H. Eskes
Keyword(s):  
Data Base ◽  
Ozone Hole ◽  
Data Set ◽  
Total Column Ozone ◽  
Spatial Coverage ◽  
Antarctic Ozone ◽  
Column Ozone ◽  
The Antarctic ◽  
Total Column ◽  
Antarctic Ozone Hole

Abstract. An assimilated data base of total column ozone measurements from satellites has been used to generate a set of indicators describing attributes of the Antarctic ozone hole for the period 1979 to 2003, including (i) daily measures of the area over Antarctica where ozone levels are below 150DU, below 220DU, more than 30% below 1979 to 1981 norms, and more than 50% below 1979 to 1981 norms, (ii) the date of disappearance of 150DU ozone values, 220DU ozone values, values 30% below 1979 to 1981 norms, and values 50% below 1979 to 1981 norms, for each year, (iii) daily minimum total column ozone values over Antarctica, and (iv) daily values of the ozone mass deficit based on a O3<220DU threshold. The assimilated data base combines satellite-based ozone measurements from 4 Total Ozone Mapping Spectrometer (TOMS) instruments, 3 different retrievals from the Global Ozone Monitoring Experiment (GOME), and data from 4 Solar Backscatter Ultra-Violet (SBUV) instruments. Comparisons with the global ground-based Dobson spectrophotometer network are used to remove offsets and drifts between the different data sets to produce a global homogeneous data set that combines the advantages of good spatial coverage of satellite data with good long-term stability of ground-based measurements. One potential use of the derived indices is detection of the expected recovery of the Antarctic ozone hole. The suitability of the derived indicators to this task is discussed in the context of their variability and their susceptibility to saturation effects which makes them less responsive to decreasing stratospheric halogen loading. It is also shown that if the corrections required to match recent Earth Probe TOMS measurements to Dobson measurements are not applied, some of the indictors are affected so as to obscure detection of the recovery of the Antarctic ozone hole.

scholarly journals OMI total column ozone: extending the long-term data record

2015 ◽  
Vol 8 (11) ◽  
pp. 4845-4850 ◽  
Author(s):  
R. D. McPeters ◽  
S. Frith ◽  
G. J. Labow
Keyword(s):  
Cross Sections ◽  
Total Ozone ◽  
Retrieval Algorithm ◽  
Data Set ◽  
Total Column Ozone ◽  
Ozone Data ◽  
Combining Data ◽  
Data Record ◽  
Column Ozone ◽  
Total Column

Abstract. The ozone data record from the Ozone Monitoring Instrument (OMI) onboard the NASA Earth Observing System (EOS) Aura satellite has proven to be very stable over the 10-plus years of operation. The OMI total column ozone processed through the Total Ozone Mapping Spectrometer (TOMS) ozone retrieval algorithm (version 8.5) has been compared with ground-based measurements and with ozone from a series of SBUV/2 (Solar Backscatter Ultraviolet) instruments. Comparison with an ensemble of Brewer–Dobson sites shows an absolute offset of about 1.5 % and almost no relative trend. Comparison with a merged ozone data set (MOD) created by combining data from a series of SBUV/2 instruments again shows an offset, of about 1 %, and a relative trend of less than 0.5 % over 10 years. The offset is mostly due to the use of the old Bass–Paur ozone cross sections in the OMI retrievals rather than the Brion–Daumont–Malicet cross sections that are now recommended. The bias in the Southern Hemisphere is smaller than that in the Northern Hemisphere, 0.9 % vs. 1.5 %, for reasons that are not completely understood. When OMI was compared with the European realization of a multi-instrument ozone time series, the GTO (GOME type Total Ozone) data set, there was a small trend of about −0.85 % decade−1. Since all the comparisons of OMI relative to other ozone measuring systems show relative trends that are less than 1 % decade−1, we conclude that the OMI total column ozone data are sufficiently stable that they can be used in studies of ozone trends.

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