scholarly journals Evidence for a larger contribution of smoldering combustion to boreal forest fire emissions from tower observations in Alaska

2020 ◽  
Author(s):  
Elizabeth B. Wiggins ◽  
Arlyn Andrews ◽  
Colm Sweeney ◽  
John B. Miller ◽  
Charles E. Miller ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Co2 Emission ◽  
Emission Factor ◽  
Emission Factors ◽  
Trace Gas ◽  
Ch4 Emission ◽  
Fire Emissions ◽  
Emission Ratio ◽  
Dry Biomass ◽  
Co Emission

Abstract. With recent increases in burned area within boreal forests that have been linked to climate warming, there is a need to better understand the composition of emissions and their impact on atmospheric composition. Most previous studies have estimated boreal fire emission factors from daytime samples collected via aircraft near fire plumes or at the surface near actively burning fires. Here we quantified emission factors for CO and CH4 from a massive regional fire complex in interior Alaska during the summer of 2015 using continuous high-resolution trace gas observations from the CRV tower (Fox, AK). Averaged over the 2015 fire season, the CO/CO2 emission ratio was 0.138±0.048 and the CO emission factor was 145±50 g CO per kg of dry biomass consumed. The CO/CO2 emission ratio was about 35 % higher and more variable than most previous aircraft-based estimates for fresh wildfire emissions. The mean CH4/CO2 emission ratio was 0.010±0.003 and the CH4 emission factor was 6.05±2.09 g CH4 per kg of dry biomass consumed, with means similar to previous reports. CO and CH4 emission factors varied in synchrony, with higher CH4 emission factors observed during periods with lower modified combustion efficiency (MCE). By coupling a fire emissions inventory with an atmospheric model, we identified that at least 35 individual fires contributed to trace gas variations measured at the CRV tower, representing a significant increase in sampling compared to the number of boreal fires measured in all previous boreal forest fire work. The model also indicated that typical mean transit times between trace gas emission and tower measurement were 1–3 days, indicating that the time series sampled combustion across day and night burning phases. The high and variable CO emission factor estimates reported here provide evidence for a more prominent role of smoldering combustion, highlighting the importance of continuously sampling of fires across time-varying environmental conditions that are representative of typical burning conditions.

scholarly journals Boreal forest fire CO and CH<sub>4</sub> emission factors derived from tower observations in Alaska during the extreme fire season of 2015

2021 ◽  
Vol 21 (11) ◽  
pp. 8557-8574
Author(s):  
Elizabeth B. Wiggins ◽  
Arlyn Andrews ◽  
Colm Sweeney ◽  
John B. Miller ◽  
Charles E. Miller ◽  
...  
Keyword(s):  
Co2 Emission ◽  
Emission Factor ◽  
Emission Factors ◽  
Trace Gas ◽  
Fire Season ◽  
Ch4 Emission ◽  
Emission Ratio ◽  
Dry Biomass ◽  
The Mean ◽  
Co Emission

Abstract. Recent increases in boreal forest burned area, which have been linked with climate warming, highlight the need to better understand the composition of wildfire emissions and their atmospheric impacts. Here we quantified emission factors for CO and CH4 from a massive regional fire complex in interior Alaska during the summer of 2015 using continuous high-resolution trace gas observations from the Carbon in Arctic Reservoirs Vulnerability Experiment (CRV) tower in Fox, Alaska. Averaged over the 2015 fire season, the mean CO / CO2 emission ratio was 0.142 ± 0.051, and the mean CO emission factor was 127 ± 40 g kg−1 dry biomass burned. The CO / CO2 emission ratio was about 39 % higher than the mean of previous estimates derived from aircraft sampling of wildfires from boreal North America. The mean CH4 / CO2 emission ratio was 0.010 ± 0.004, and the CH4 emission factor was 5.3 ± 1.8 g kg−1 dry biomass burned, which are consistent with the mean of previous reports. CO and CH4 emission ratios varied in synchrony, with higher CH4 emission factors observed during periods with lower modified combustion efficiency (MCE). By coupling a fire emissions inventory with an atmospheric model, we identified at least 34 individual fires that contributed to trace gas variations measured at the CRV tower, representing a sample size that is nearly the same as the total number of boreal fires measured in all previous field campaigns. The model also indicated that typical mean transit times between trace gas emission within a fire perimeter and tower measurement were 1–3 d, indicating that the time series sampled combustion across day and night burning phases. The high CO emission ratio estimates reported here provide evidence for a prominent role of smoldering combustion and illustrate the importance of continuously sampling fires across time-varying environmental conditions that are representative of a fire season.

scholarly journals Global fire emissions estimates during 1997–2015

2017 ◽  
Author(s):  
Guido R. van der Werf ◽  
James T. Randerson ◽  
Louis Giglio ◽  
Thijs T. van Leeuwen ◽  
Yang Chen ◽  
...  
Keyword(s):  
North America ◽  
Fuel Consumption ◽  
Fire Severity ◽  
Emission Factors ◽  
Trace Gas ◽  
Burned Area ◽  
Biogeochemical Model ◽  
Fire Dynamics ◽  
Fire Emissions ◽  
Aerosol Emissions

Abstract. Climate, land use, and other anthropogenic and natural drivers have the potential to influence fire dynamics in many regions. To develop a mechanistic understanding of the changing role of these drivers and their impact on atmospheric composition, long term fire records are needed that fuse information from different satellite and in-situ data streams. Here we describe the fourth version of the Global Fire Emissions Database (GFED) and quantify global fire emissions patterns during 1997–2015. The modeling system, based on the Carnegie-Ames-Stanford-Approach (CASA) biogeochemical model, has several modifications from the previous version and uses higher quality input datasets. Significant upgrades include: 1) new burned area estimates with contributions from small fires, 2) a revised fuel consumption parameterization optimized using field observations, 3) modifications that improve the representation of fuel consumption in frequently burning landscapes, and 4) fire severity estimates that better represent continental differences in burning processes across boreal regions of North America and Eurasia. The new version has a higher spatial resolution (0.25°) and uses a different set of emission factors that separately resolves trace gas and aerosol emissions from temperate and boreal forest ecosystems. Global mean carbon emissions using the burned area dataset with small fires (GFED4s) were 2.2 x 1015 grams carbon per year (Pg C yr-1) during 1997–2015, with a maximum in 1997 (3.0 Pg C yr-1) and minimum in 2013 (1.8 Pg C yr-1). These estimates were 11 % higher than our previous estimates (GFED3) during 1997–2011, when the two datasets overlapped. This increase was the result of a substantial increase in burned area (37 %), mostly due to the inclusion of small fires, and a modest decrease in mean fuel consumption (–19 %) to better match estimates from field studies, primarily in savannas and grasslands. For trace gas and aerosol emissions, differences between GFED4s and GFED3 were often larger due to the use of revised emission factors. If small fire burned area was excluded (GFED4 without the "s" for small fires), average emissions were 1.5 Pg C yr-1. The addition of small fires had the largest impact on emissions in temperate North America, Central America, Europe, and temperate Asia. Our improved dataset provides an internally consistent set of burned area and emissions that may contribute to a better understanding of multi-decadal changes in fire dynamics and their impact on the Earth System. GFED data is available from http://www.globalfiredata.org.

scholarly journals Global fire emissions estimates during 1997–2016

2017 ◽  
Vol 9 (2) ◽  
pp. 697-720 ◽  
Author(s):  
Guido R. van der Werf ◽  
James T. Randerson ◽  
Louis Giglio ◽  
Thijs T. van Leeuwen ◽  
Yang Chen ◽  
...  
Keyword(s):  
North America ◽  
Fuel Consumption ◽  
Fire Severity ◽  
Emission Factors ◽  
Trace Gas ◽  
Burned Area ◽  
Biogeochemical Model ◽  
Fire Dynamics ◽  
Fire Emissions ◽  
Aerosol Emissions

Abstract. Climate, land use, and other anthropogenic and natural drivers have the potential to influence fire dynamics in many regions. To develop a mechanistic understanding of the changing role of these drivers and their impact on atmospheric composition, long-term fire records are needed that fuse information from different satellite and in situ data streams. Here we describe the fourth version of the Global Fire Emissions Database (GFED) and quantify global fire emissions patterns during 1997–2016. The modeling system, based on the Carnegie–Ames–Stanford Approach (CASA) biogeochemical model, has several modifications from the previous version and uses higher quality input datasets. Significant upgrades include (1) new burned area estimates with contributions from small fires, (2) a revised fuel consumption parameterization optimized using field observations, (3) modifications that improve the representation of fuel consumption in frequently burning landscapes, and (4) fire severity estimates that better represent continental differences in burning processes across boreal regions of North America and Eurasia. The new version has a higher spatial resolution (0.25°) and uses a different set of emission factors that separately resolves trace gas and aerosol emissions from temperate and boreal forest ecosystems. Global mean carbon emissions using the burned area dataset with small fires (GFED4s) were 2.2  ×  1015 grams of carbon per year (Pg C yr−1) during 1997–2016, with a maximum in 1997 (3.0 Pg C yr−1) and minimum in 2013 (1.8 Pg C yr−1). These estimates were 11 % higher than our previous estimates (GFED3) during 1997–2011, when the two datasets overlapped. This net increase was the result of a substantial increase in burned area (37 %), mostly due to the inclusion of small fires, and a modest decrease in mean fuel consumption (−19 %) to better match estimates from field studies, primarily in savannas and grasslands. For trace gas and aerosol emissions, differences between GFED4s and GFED3 were often larger due to the use of revised emission factors. If small fire burned area was excluded (GFED4 without the s for small fires), average emissions were 1.5 Pg C yr−1. The addition of small fires had the largest impact on emissions in temperate North America, Central America, Europe, and temperate Asia. This small fire layer carries substantial uncertainties; improving these estimates will require use of new burned area products derived from high-resolution satellite imagery. Our revised dataset provides an internally consistent set of burned area and emissions that may contribute to a better understanding of multi-decadal changes in fire dynamics and their impact on the Earth system. GFED data are available from http://www.globalfiredata.org.

scholarly journals Analysis of Main Factors for CH4 Emission Factor Development in Manufacturing Industries and Construction Sector

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1220
Author(s):  
Seongmin Kang ◽  
Seonghum Cho ◽  
Joonyoung Roh ◽  
Eui-chan Jeon
Keyword(s):  
Emission Factor ◽  
Emission Factors ◽  
Ch4 Emission ◽  
Test Results ◽  
Intergovernmental Panel ◽  
Average Value ◽  
South Korean ◽  
National Characteristics ◽  
Lng Fuel ◽  
Model Year

This study has statistically analyzed the effect of boiler type and model year on CH4 emission factors, focusing on liquefied natural gas (LNG)—the most commonly used fuel in South Korean manufacturing combustion facilities. Samples were collected from the boilers of 39 manufacturing combustion facilities that use LNG fuel. The CH4 emission factors were developed based on 4 overhead fire-tube boilers, 14 once-through boilers, 14 vertical boilers with vertical water tubes, and 7 other boilers. This resulted in an average value of 0.11 CH4 kg/TJ, which is considerably lower than the Intergovernmental Panel on Climate Change (IPCC) 1996 guidelines(G/L) emission factor of 5 CH4 kg/TJ currently used in South Korea. In the Kruskal–Wallis test results, the significance probability was greater than 0.05 for the boiler types and ages, and there was no major difference in the average distributions, according to the boiler type or age. Therefore, according to the results of this study, the differences in the CH4 emission factors according to the boiler types and ages are not statistically large, and it was determined that there is no major difference even when the emission factors are applied to different fuel types. However, there was a major difference when the developed factors were compared to the CH4 emission factor proposed by the IPCC. Thus, there is a need to develop manufacturing combustion CH4 emission factors that reflect national characteristics.

scholarly journals Measurements of reactive trace gases and variable O<sub>3</sub> formation rates in some South Carolina biomass burning plumes

2013 ◽  
Vol 13 (3) ◽  
pp. 1141-1165 ◽  
Author(s):  
S. K. Akagi ◽  
R. J. Yokelson ◽  
I. R. Burling ◽  
S. Meinardi ◽  
I. Simpson ◽  
...  
Keyword(s):  
South Carolina ◽  
Biomass Burning ◽  
Stand Structure ◽  
Trace Gases ◽  
Field Studies ◽  
Emission Factors ◽  
Trace Gas ◽  
Methanol Production ◽  
Fire Emissions ◽  
Reactive Trace Gases

Abstract. In October–November 2011 we measured trace gas emission factors from seven prescribed fires in South Carolina (SC), US, using two Fourier transform infrared spectrometer (FTIR) systems and whole air sampling (WAS) into canisters followed by gas-chromatographic analysis. A total of 97 trace gas species were quantified from both airborne and ground-based sampling platforms, making this one of the most detailed field studies of fire emissions to date. The measurements include the first emission factors for a suite of monoterpenes produced by heating vegetative fuels during field fires. The first quantitative FTIR observations of limonene in smoke are reported along with an expanded suite of monoterpenes measured by WAS including α-pinene, β-pinene, limonene, camphene, 4-carene, and myrcene. The known chemistry of the monoterpenes and their measured abundance of 0.4–27.9% of non-methane organic compounds (NMOCs) and ~ 21% of organic aerosol (mass basis) suggests that they impacted secondary formation of ozone (O3), aerosols, and small organic trace gases such as methanol and formaldehyde in the sampled plumes in the first few hours after emission. The variability in the initial terpene emissions in the SC fire plumes was high and, in general, the speciation of the initially emitted gas-phase NMOCs was 13–195% different from that observed in a similar study in nominally similar pine forests in North Carolina ~ 20 months earlier. It is likely that differences in stand structure and environmental conditions contributed to the high variability observed within and between these studies. Similar factors may explain much of the variability in initial emissions in the literature. The ΔHCN/ΔCO emission ratio, however, was found to be fairly consistent with previous airborne fire measurements in other coniferous-dominated ecosystems, with the mean for these studies being 0.90 ± 0.06%, further confirming the value of HCN as a biomass burning tracer. The SC results also support an earlier finding that C3-C4 alkynes may be of use as biomass burning indicators on the time-scale of hours to a day. It was possible to measure the downwind chemical evolution of the plume on four of the fires and significant O3 formation (ΔO3/ΔCO from 10–90%) occurred in all of these plumes within two hours. The slowest O3 production was observed on a cloudy day with low co-emission of NOx. The fastest O3 production was observed on a sunny day when the downwind plume almost certainly incorporated significant additional NOx by passing over the Columbia, SC metropolitan area. Due to rapid plume dilution, it was only possible to acquire high-quality downwind data for two other trace gas species (formaldehyde and methanol) during two of the fires. In all four of these cases, significant increases in formaldehyde and methanol were observed in <2 h. This is likely the first direct observation of post-emission methanol production in biomass burning plumes. Post-emission production of methanol does not always happen in young biomass burning plumes, and its occurrence in this study could have involved terpene precursors to a significant extent.

scholarly journals Measurements of reactive trace gases and variable O<sub>3</sub> formation rates in some South Carolina biomass burning plumes

2012 ◽  
Vol 12 (9) ◽  
pp. 25255-25328 ◽  
Author(s):  
S. K. Akagi ◽  
R. J. Yokelson ◽  
I. R. Burling ◽  
S. Meinardi ◽  
I. Simpson ◽  
...  
Keyword(s):  
South Carolina ◽  
Biomass Burning ◽  
Stand Structure ◽  
Trace Gases ◽  
Field Studies ◽  
Emission Factors ◽  
Trace Gas ◽  
Methanol Production ◽  
Fire Emissions ◽  
Reactive Trace Gases

Abstract. In October–November 2011 we measured trace gas emission factors from seven prescribed fires in South Carolina (SC), US, using two Fourier transform infrared spectrometer (FTIR) systems and whole air sampling (WAS) into canisters followed by gas-chromatographic analysis. A total of 97 trace gas species were quantified from both airborne and ground-based sampling platforms, making this one of the most detailed field studies of fire emissions to date. The measurements include the first emission factors for a suite of monoterpenes produced by heating vegetative fuels during field fires. The first quantitative FTIR observations of limonene in smoke are reported along with an expanded suite of monoterpenes measured by WAS including α-pinene, β-pinene, limonene, camphene, 4-carene, and myrcene. The known chemistry of the monoterpenes and their measured abundance of 0.4–27.9% of non-methane organic compounds (NMOCs) and ~21% of organic aerosol (mass basis) suggests that they impacted secondary formation of ozone (O3), aerosols, and small organic trace gases such as methanol and formaldehyde in the sampled plumes in first few hours after emission. The variability in the initial terpene emissions in the SC fire plumes was high and, in general, the speciation of the initially emitted gas-phase NMOCs was 13–195% different from that observed in a similar study in nominally similar pine forests in North Carolina ~20 months earlier. It is likely that differences in stand structure and environmental conditions contributed to the high variability observed within and between these studies. Similar factors may explain much of the variability in initial emissions in the literature. The ΔHCN/ΔCO emission ratio, however, was found to be fairly consistent with previous airborne fire measurements in other coniferous-dominated ecosystems, with the mean for these studies being 0.90 ± 0.06%, further confirming the value of HCN as a biomass burning tracer. The SC results also support an earlier finding that C3-C4 alkynes may be of use as biomass burning indicators on the time-scale of hours to a day. It was possible to measure the downwind chemical evolution of the plume on four of the fires and significant O3 formation (ΔO3/ΔCO from 10–90%) occurred in all of these plumes within two hours. The slowest O3 production was observed on a cloudy day with low co-emission of NOx. The fastest O3 production was observed on a sunny day when the downwind plume almost certainly incorporated significant additional NOx by passing over the Columbia, SC metropolitan area. Due to rapid plume dilution, it was only possible to acquire high-quality downwind data for two other trace gas species (formaldehyde and methanol) during two of the fires. In all four of these cases, significant increases in formaldehyde and methanol were observed in <2 h. This is likely the first direct observation of post-emission methanol production in biomass burning plumes. Post-emission production of methanol does not always happen in young biomass burning plumes, and its occurrence in this study could have involved terpene precursors to a significant extent.

scholarly journals Satellite observations indicate substantial spatiotemporal variability in biomass burning NO<sub>x</sub> emission factors for South America

2013 ◽  
Vol 13 (8) ◽  
pp. 22757-22793 ◽  
Author(s):  
P. Castellanos ◽  
K. F. Boersma ◽  
G. R. van der Werf
Keyword(s):  
South America ◽  
Biomass Burning ◽  
Temporal Variability ◽  
Emission Factor ◽  
Combustion Efficiency ◽  
Emission Factors ◽  
Dry Season ◽  
Nox Emission ◽  
Bottom Up ◽  
Fire Emissions

Abstract. Biomass burning is an important contributor to global total emissions of NOx (NO + NO2). Generally bottom-up fire emissions models calculate NOx emissions by multiplying fuel consumption estimates with static biome specific emission factors, defined in units of grams of NO per kilogram of dry matter consumed. Emission factors are a significant source of uncertainty in bottom-up fire emissions modeling because relatively few observations are available to characterize the large spatial and temporal variability of burning conditions. In this paper we use NO2 tropospheric column observations from the Ozone Monitoring Instrument (OMI) from the year 2005 over South America to calculate monthly NOx emission factors for four fire types: deforestation, savanna/grassland, woodland, and agricultural waste burning. In general, the spatial trends in NOx emission factors calculated in this work are consistent with emission factors derived from in situ measurements from the region, but are more variable than published biome specific global average emission factors widely used in bottom up fire emissions inventories such as the Global Fire Emissions Database (GFED) v3. Satellite based NOx emission factors also indicate substantial temporal variability in burning conditions. Overall, we found that deforestation fires have the lowest NOx emission factors, on average 30 % lower than the emission factors used in GFED v3. Agricultural fire NOx emission factors were the highest, on average a factor of 2 higher than GFED v3 values. For savanna, woodland, and deforestation fires early dry season NOx emission factors were a factor of ~1.5–2.0 higher than late dry season emission factors. A minimum in the NOx emission factor seasonal cycle for deforestation fires occurred in August, the time period of severe drought in South America in 2005. Our results support the hypothesis that prolonged dry spells may lead to an increase in the contribution of smoldering combustion from large diameter fuels to total fire emissions, which would lower the overall modified combustion efficiency (MCE) and NOx emission factor, and offset the higher combustion efficiency of dryer fine fuels. We evaluated the OMI derived NOx emission factors with SCIAMACHY NO2 tropospheric column observations and found improved model performance in regions dominated by fire emissions.

scholarly journals Boreal forest fire emissions in fresh Canadian smoke plumes: C<sub>1</sub>-C<sub>10</sub> volatile organic compounds (VOCs), CO<sub>2</sub>, CO, NO<sub>2</sub>, NO, HCN and CH<sub>3</sub>CN

2011 ◽  
Vol 11 (13) ◽  
pp. 6445-6463 ◽  
Author(s):  
I. J. Simpson ◽  
S. K. Akagi ◽  
B. Barletta ◽  
N. J. Blake ◽  
Y. Choi ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Organic Compounds ◽  
Biomass Burning ◽  
Forest Fires ◽  
Trace Gas ◽  
Air Samples ◽  
Fire Emissions ◽  
Trace Gas Emissions ◽  
Smoke Plumes ◽  
Volatile Organic

Abstract. Boreal regions comprise about 17 % of the global land area, and they both affect and are influenced by climate change. To better understand boreal forest fire emissions and plume evolution, 947 whole air samples were collected aboard the NASA DC-8 research aircraft in summer 2008 as part of the ARCTAS-B field mission, and analyzed for 79 non-methane volatile organic compounds (NMVOCs) using gas chromatography. Together with simultaneous measurements of CO2, CO, CH4, CH2O, NO2, NO, HCN and CH3CN, these measurements represent the most comprehensive assessment of trace gas emissions from boreal forest fires to date. Based on 105 air samples collected in fresh Canadian smoke plumes, 57 of the 80 measured NMVOCs (including CH2O) were emitted from the fires, including 45 species that were quantified from boreal forest fires for the first time. After CO2, CO and CH4, the largest emission factors (EFs) for individual species were formaldehyde (2.1 ± 0.2 g kg−1), followed by methanol, NO2, HCN, ethene, α-pinene, β-pinene, ethane, benzene, propene, acetone and CH3CN. Globally, we estimate that boreal forest fires release 2.4 ± 0.6 Tg C yr−1 in the form of NMVOCs, with approximately 41 % of the carbon released as C1-C2 NMVOCs and 21 % as pinenes. These are the first reported field measurements of monoterpene emissions from boreal forest fires, and we speculate that the pinenes, which are relatively heavy molecules, were detected in the fire plumes as the result of distillation of stored terpenes as the vegetation is heated. Their inclusion in smoke chemistry models is expected to improve model predictions of secondary organic aerosol (SOA) formation. The fire-averaged EF of dichloromethane or CH2Cl2, (6.9 ± 8.6) × 10−4 g kg−1, was not significantly different from zero and supports recent findings that its global biomass burning source appears to have been overestimated. Similarly, we found no evidence for emissions of chloroform (CHCl3) or methyl chloroform (CH3CCl3) from boreal forest fires. The speciated hydrocarbon measurements presented here show the importance of carbon released by short-chain NMVOCs, the strong contribution of pinene emissions from boreal forest fires, and the wide range of compound classes in the most abundantly emitted NMVOCs, all of which can be used to improve biomass burning inventories in local/global models and reduce uncertainties in model estimates of trace gas emissions and their impact on the atmosphere.

scholarly journals Uncertainty Analysis for the CH4 Emission Factor of Thermal Power Plant by Monte Carlo Simulation

2018 ◽  
Vol 10 (10) ◽  
pp. 3448 ◽  
Author(s):  
Changsang Cho ◽  
Seongmin Kang ◽  
Minwook Kim ◽  
Yoonjung Hong ◽  
Eui-chan Jeon
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Emission Factor ◽  
Power Plants ◽  
Thermal Power ◽  
Emission Factors ◽  
Operating Conditions ◽  
Thermal Power Plants ◽  
Ch4 Emission ◽  
Uncertainty Range

Thermal power plants are a large source of greenhouse gas emissions among energy industry facilities. Emission factors for methane and nitrous oxide depend on combustion technologies and operating conditions and vary significantly with individual thermal power plants. Due to this variability, use of average emission factors for these gases will introduce relatively large uncertainties. This study determined the CH4 emission factors of thermal power plants currently in operation in Korea by conducting field investigations according to fuel type and type of combustion technique. Through use of the Monte Carlo simulation, the uncertainty range for the CH4 emission factor was determined. The estimation showed, at the 95% confidence level, that the uncertainty range for CH4 emission factor from a tangential firing boiler using bituminous coal was −46.6% to +145.2%. The range for the opposed wall-firing boiler was −25.3% to +70.9%. The range for the tangential firing boiler using fuel oil was −39.0% to 93.5%, that from the opposed wall-firing boiler was −47.7% to +201.1%, and that from the internal combustion engine boiler was −38.7% to +106.1%. Finally, the uncertainty range for the CH4 emission factor from the combined cycle boiler using LNG was −90% to +326%.

scholarly journals Boreal forest fire emissions in fresh Canadian smoke plumes: C<sub>1</sub>–C<sub>10</sub> volatile organic compounds (VOCs), CO<sub>2</sub>, CO, NO<sub>2</sub>, NO, HCN and CH<sub>3</sub>CN

2011 ◽  
Vol 11 (3) ◽  
pp. 9515-9566 ◽  
Author(s):  
I. J. Simpson ◽  
S. K. Akagi ◽  
B. Barletta ◽  
N. J. Blake ◽  
Y. Choi ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Organic Compounds ◽  
Biomass Burning ◽  
Forest Fires ◽  
Trace Gas ◽  
Air Samples ◽  
Fire Emissions ◽  
Trace Gas Emissions ◽  
Smoke Plumes ◽  
Volatile Organic

Abstract. Boreal regions comprise about 17% of the global land area, and they both affect and are influenced by climate change. To better understand boreal forest fire emissions and plume evolution, 947 whole air samples were collected aboard the NASA DC-8 research aircraft in summer 2008 as part of the ARCTAS-B field mission, and analyzed for 79 non-methane volatile organic compounds (NMVOCs) using gas chromatography. Together with simultaneous measurements of CO2, CO, CH4, CH2O, NO2, NO, HCN and CH3CN, these measurements represent the most comprehensive assessment of trace gas emissions from boreal forest fires to date. Based on 105 air samples collected in fresh Canadian smoke plumes, 57 of the 80 measured NMVOCs (including CH2O) were emitted from the fires, including 45 species that were quantified from boreal forest fires for the first time. After CO2, CO and CH4, the largest emission factors (EFs) for individual species were formaldehyde (2.1 ± 0.2 g kg−1), followed by methanol, NO2, HCN, ethene, α-pinene, β-pinene, ethane, benzene, propene, acetone and CH3CN. Globally, we estimate that boreal forest fires release 2.4 ± 0.6 Tg C yr−1 in the form of NMVOCs, with approximately 41% of the carbon released as C1–C2 NMVOCs and 21% as pinenes. These are the first reported field measurements of monoterpene emissions from boreal forest fires, and we speculate that the pinenes, which are relatively heavy molecules, were detected in the fire plumes as the result of distillation of stored terpenes as the vegetation is heated. Their inclusion in smoke chemistry models is expected to improve model predictions of secondary organic aerosol (SOA) formation. The fire-averaged EF of dichloromethane or CH2Cl2, (6.9 ± 8.6) ×10−4 g kg−1, was not significantly different from zero and supports recent findings that its global biomass burning source appears to have been overestimated. Similarly, we found no evidence for emissions of chloroform (CHCl3) or methyl chloroform (CH3CCl3) from boreal forest fires. The speciated hydrocarbon measurements presented here show the importance of carbon released by short-chain NMVOCs, the strong contribution of pinene emissions from boreal forest fires, and the wide range of compound classes in the most abundantly emitted NMVOCs, all of which can be used to improve biomass burning inventories in local/global models and reduce uncertainties in model estimates of trace gas emissions and their impact on the atmosphere.

Sign in / Sign up

Export Citation Format

Share Document