Comparison of 3R4F cigarette smoke and IQOS heated tobacco product aerosol emissions

In this study, the smoke from a 3R4F research cigarette and the aerosol generated by the Heated Tobacco Product IQOS, also referred to as the Tobacco Heating System (THS) 2.2 in the literature, were compared. The objective was to characterize the gas and suspended particulate matter compositions in the mainstream smoke from a combusted 3R4F cigarette and in the aerosol generated by IQOS during use. The results indicated that the determined aerosol emissions from IQOS were notably lower than in the cigarette smoke under a Health Canada Intense puffing regimen. As an interesting detail in this study, the maximum nicotine concentrations within a puff were practically the same in both the 3R4F smoke and the IQOS aerosol, but the average concentration was lower for the IQOS aerosol. For both products, water constituted a significant proportion of the particulate matter, although it was substantially higher in the IQOS aerosol. Furthermore, combustion-related solid particles observed in the 3R4F smoke contained elements such as carbon, oxygen, potassium, calcium, and silicon. In contrast, IQOS aerosol particulate matter was composed of semi-volatile organic constituents with some minor traces of oxygen and silicon. The particulate matter found in the IQOS aerosol was volatile, which was especially noticeable when exposed to the electron beam of the scanning electron microscope (SEM) and Transmission Electron Microscope (TEM).

Human-caused long-term changes in global aridity

Widespread aridification of the land surface causes substantial environmental challenges and is generally well documented. However, the mechanisms underlying increased aridity remain relatively underexplored. Here, we investigated the anthropogenic and natural factors affecting long-term global aridity changes using multisource observation-based aridity index, factorial simulations from the Coupled Model Intercomparison Project phase 6 (CMIP6), and rigorous detection and attribution (D&A) methods. Our study found that anthropogenic forcings, mainly rising greenhouse gas emissions (GHGE) and aerosols, caused the increased aridification of the globe and each hemisphere with high statistical confidence for 1965–2014; the GHGE contributed to drying trends, whereas the aerosol emissions led to wetting tendencies; moreover, the bias-corrected CMIP6 future aridity index based on the scaling factors from optimal D&A demonstrated greater aridification than the original simulations. These findings highlight the dominant role of human effects on increasing aridification at broad spatial scales, implying future reductions in aridity will rely primarily on the GHGE mitigation.

Improving the Representation of Whitecap Fraction and Sea Salt Aerosol Emissions in the ECMWF IFS-AER

The European Centre for Medium-Range Weather Forecasts (ECMWF) operates the Integrated Forecasting System aerosol module (IFS-AER) to provide daily global analysis and forecast of aerosols for the Copernicus Atmosphere Monitoring Service (CAMS). New estimates of sea salt aerosol emissions have been implemented in the IFS-AER using a new parameterization of whitecap fraction as a function of wind speed and sea surface temperature. The effect of whitecap fraction simulated by old and new parameterizations has been evaluated by comparing the IFS-AER new sea salt aerosol characteristics to those of aerosol retrievals. The new parameterization brought a significant improvement as compared to the two parameterizations of sea salt aerosol emissions previously implemented in the IFS-AER. Likewise, the simulated sea salt aerosol optical depth and surface concentration are significantly improved, as compared against ground and remote sensing products.

The impact of molecular self-organisation on the atmospheric fate of a cooking aerosol proxy

Atmospheric aerosols influence the climate via cloud droplet nucleation and can facilitate the long-range transport of harmful pollutants. The lifetime of such aerosols can therefore determine their environmental impact. Fatty acids are found in organic aerosol emissions with oleic acid, an unsaturated fatty acid, being a large contributor to cooking emissions. As a surfactant, oleic acid can self-organise into nanostructured lamellar bilayers with its sodium salt, and this self-organisation can influence reaction kinetics. We developed a kinetic multi-layer model-based description of decay data we obtained from laboratory experiments of the ozonolysis of coated films of this self-organised system, demonstrating a decreased diffusivity for both oleic acid and ozone due to lamellar bilayer formation. Diffusivity was further inhibited by a viscous oligomer product forming in the surface layers of the film. Our results indicate that nanostructure formation can increase the reactive half-life of oleic acid by an order of days at typical indoor and outdoor atmospheric ozone concentrations. We are now able to place nanostructure formation in an atmospherically meaningful and quantifiable context. These results have implications for the transport of harmful pollutants and the climate.

Nonlinear response of Asian summer monsoon precipitation to emission reductions in South and East Asia

Anthropogenic aerosols over South and East Asia currently have a stronger impact on the Asian Summer Monsoon (ASM) than greenhouse gas emissions, yet projected aerosol emission changes in these regions are subject to considerable uncertainties such as timescale, location, emission type, and even the sign of the change. We use a circulation/climate model with idealised aerosol distributions to demonstrate that the sum of ASM responses to aerosol emission reductions in each region is very different to the response to simultaneous reductions in both regions, implying the ASM response to aerosol emissions reductions is highly nonlinear. The phenomenon is independent of whether aerosols are scattering or absorbing, and results from interaction of induced atmospheric circulation changes. The nonlinearity from interactions between aerosol forcing from different regions represents a new source of uncertainty in projections of ASM changes over the next 30-40 years, and may limit the utility of country-dependent aerosol trajectories when considering their Asia-wide effects, though we recommend further work to establish whether the nonlinearity is buffered by other drivers. To understand likely changes in the ASM due to aerosol reductions, countries will need to accurately take account of emissions reductions from across the wider region, rather than approximating them using simple scenarios and emulators. The nonlinearity in the response to forcing therefore presents a regional public goods issue for countries affected by the ASM, as the costs and benefits of aerosol emissions reductions are not internalised; in fact, forcings from different countries such as India and China work jointly to determine outcomes across the region.

Conceptual issues of professional education of specialists in the "Environmental Protection Technologies"

Composing the programs for the education of specialists in the field of environmental protection requires clear ideas about the concepts, place of basic disciplines and the main issues of the future specialty. Peculiarities of methodological aspects of description of levels and assessment of quality of education in terminology of competences and learning outcomes are considered. They consist in the predominance of competencies, that have a physical meaning and ensure the filling of the "core" of the educational program with physical principles, methods and models. The study of polluting processes in natural objects requires knowledge of the physics of aerodisperse systems in connection with the solution of aerosol emissions into the atmosphere, knowledge of the physics of the dispersible silt-covered upcasts into the aquatic environment, knowledge and understanding of physical phenomena of heat and mass transfer processes in soil, as in the granular system, knowledge of the physics of external radiation, including sound, heat, electromagnetic, in particular, ionizing radiation, and their impact on the environment. Peculiarities of the educational system of training specialists in the field of environmental protection take into account the tasks of systemic radioecology, among which the tasks of radiation monitoring are especially important. The conceptual approach to the study of radioecology is proposed not as a whole, mixing the laws of physics, chemistry and, for example, biology, but by individual branches, and systematically.