scholarly journals Measurement report: Long-term variations in carbon monoxide at a background station in China's Yangtze River Delta region

2020 ◽  
Author(s):  
Yijing Chen ◽  
Qianli Ma ◽  
Weili Lin ◽  
Xiaobin Xu ◽  
Jie Yao ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Yangtze River ◽  
Yangtze River Delta ◽  
River Delta ◽  
Control Measures ◽  
Mixing Ratios ◽  
Significant Downward Trend ◽  
The Yrd ◽  
Long Term Variations

Abstract. This study analyzed the long-term variations in carbon monoxide (CO) mixing ratios from January 2006 to December 2017 at the Lin'an regional atmospheric background station (LAN; 30.3° N, 119.73° E, 138 m a.s.l.) in China's Yangtze River Delta (YRD) region. The CO mixing ratios were at their highest (0.69 ± 0.08 ppm) and lowest (0.54 ± 0.06 ppm) in winter and summer, respectively. The average daily variation of CO exhibited a double-peaked pattern, with peaks in the morning and evening and a valley in the afternoon. A significant downward trend of −11.3 ppb/yr of CO was observed from 2006 to 2017 at the LAN station, which was in accordance with the negative trend of the average CO mixing ratios and total column retrieved from the satellite data (the Measurements Of Pollution In The Troposphere, MOPITT) over the YRD region during the same period. The average annual CO mixing ratio at the LAN station in 2017 was 0.51 ± 0.04 ppm, which was significantly lower than that (0.71 ± 0.12 ppm) in 2006. The decrease in CO levels was largest in autumn (−15.7 ppb/yr), followed by summer (−11.1 ppb/yr), spring (−10.8 ppb/yr), and winter (−9.7 ppb/yr). Moreover, the CO levels under relatively polluted conditions (the annually 95th percentiles) declined even more rapidly (−22.4 ppb/yr, α = 0.05, r = −0.68) from 2006 (0.91 ppm) to 2017 (0.58 ppm) and the CO levels under clean conditions (the annually 5th percentiles) were relatively stable throughout the years. The long-term decline and short-term variations in the CO mixing ratios at the LAN station were mainly attributed to the implementation of the anthropogenic pollution control measures in the YRD region and to the events like Shanghai Expo in 2020 and Hangzhou G20 in 2016. The decreased CO level may influence atmospheric chemistry over the region. The average OH reactivity of CO at the LAN station is estimated to significantly drop from 4.1 ± 0.7 s-1 in 2006 to 3.0 ± 0.3 s-1 in 2017.

scholarly journals Measurement report: Long-term variations in carbon monoxide at a background station in China's Yangtze River Delta region

2020 ◽  
Vol 20 (24) ◽  
pp. 15969-15982
Author(s):  
Yijing Chen ◽  
Qianli Ma ◽  
Weili Lin ◽  
Xiaobin Xu ◽  
Jie Yao ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Yangtze River ◽  
Yangtze River Delta ◽  
River Delta ◽  
Control Measures ◽  
Mixing Ratios ◽  
Significant Downward Trend ◽  
The Yrd ◽  
Long Term Variations

Abstract. This study analyzed the long-term variations in carbon monoxide (CO) mixing ratios from January 2006 to December 2017 at the Lin'an regional atmospheric background station (LAN; 30.3∘ N, 119.73∘ E, 138 m a.s.l.) in China's Yangtze River Delta (YRD) region. The CO mixing ratios were at their highest (0.69 ± 0.08 ppm) and lowest (0.54 ± 0.06 ppm) in winter and summer, respectively. The average daily variation in CO exhibited a double-peaked pattern, with peaks in the morning and evening and a valley in the afternoon. A significant downward trend of −11.3 ppb yr−1 of CO was observed from 2006 to 2017 at the LAN station, which was in accordance with the negative trends of the average CO mixing ratios and total column retrieved from the satellite data (Measurements of Pollution in the Troposphere, MOPITT) over the YRD region during the same period. The average annual CO mixing ratio at the LAN station in 2017 was 0.51 ± 0.04 ppm, which was significantly lower than that (0.71 ± 0.12 ppm) in 2006. The decrease in CO levels was largest in autumn (−15.7 ppb yr−1), followed by summer (−11.1 ppb yr−1), spring (−10.8 ppb yr−1), and winter (−9.7 ppb yr−1). Moreover, the CO levels under relatively polluted conditions (the annual 95th percentiles) declined even more rapidly (−22.4 ppb yr−1, r=-0.68, p<0.05) from 2006 (0.91 ppm) to 2017 (0.58 ppm), and the CO levels under clean conditions (the annual 5th percentiles) showed decreasing evidence but not statistically significant (r=-0.41, p=0.19) throughout the years. The long-term decline and short-term variations in the CO mixing ratios at the LAN station were mainly attributed to the implementation of the anthropogenic pollution control measures in the YRD region and to events like the Shanghai Expo in 2010 and Hangzhou G20 in 2016. The decreased CO level may influence atmospheric chemistry over the region. The average OH reactivity of CO at the LAN station is estimated to significantly drop from 4.1 ± 0.7 s−1 in 2006 to 3.0 ± 0.3 s−1 in 2017.

scholarly journals Measurement report: Long-term variations in surface NO<sub>x</sub> and SO<sub>2</sub> from 2006 to 2016 at a background site in the Yangtze River Delta region, China

2021 ◽  
Author(s):  
Qingqing Yin ◽  
Qianli Ma ◽  
Weili Lin ◽  
Xiaobin Xu ◽  
Jie Yao
Keyword(s):  
Yangtze River ◽  
Yangtze River Delta ◽  
Mixing Ratio ◽  
So2 Emissions ◽  
Annual Average ◽  
Mixing Ratios ◽  
The Yrd ◽  
The Yangtze River Delta ◽  
Long Term Variations

Abstract. China has been experiencing rapid changes in emissions of air pollutants in recent decades. Increased emissions of primary particulates and reactive gases caused severe haze in several polluted regions including the Yangtze River Delta (YRD). Measures implemented in recent years for improving air quality have reduced the emissions of NOX, SO2, etc. The emission changes of these gases are reflected by tropospheric columns from satellite observations and surface measurements of surface concentrations from urban sites. However, little is known about the long-term variations in regional background NOX and SO2. In this study, we present NOX and SO2 measurements from the Lin'an station (LAN, 119°44' E,30°18' N,138.6 m a.s.l.), one of the Global Atmosphere Watch (GAW) stations in China. We characterize the seasonal and diurnal variations and study the long-term trends of NOX and SO2 mixing ratios observed at LAN from 2006 to 2016. We also interpret the observed variations and trends in term of changes in meteorological conditions as well as emission of these gases. The overall average mixing ratios of NOX and SO2 during 2006–2016 were 13.6 ± 1.2 ppb and 7.0 ± 4.2 ppb, respectively. The averaged seasonal variations showed maximum values of NOx and SO2 in December (23.5 ± 4.4 ppb) and January (11.9 ± 6.2 ppb), respectively, and minimum values of 7.1 ± 0.8 ppb and 2.8 ± 2.3 ppb (both in July), respectively. The average diurnal variation characteristics of NOX and SO2 differed considerably from each other though the daily average mixing ratios of both gases were significantly correlated (R2 = 0.29, P < 0.001). The annual average mixing ratio of NOX increased during 2006–2011 and then decreased significantly at 0.78 ppb/yr (−5.16 %/yr, P < 0.01). The annual 95 % and 5 % percentiles of hourly NOX mixing ratios showed upward trends until 2012 and 2014, respectively, before a clear decline. The annual average mixing ratio of SO2 decreased significantly at 0.99 ppb/yr (−8.27 %/yr, P < 0.01) from 2006–2016. The annual 95 % and 5 % percentiles of hourly SO2 mixing ratios all exhibited significant (P < 0.001) downward trends at 3.18 ppb/yr and 0.19 ppb/yr, respectively. Changes in the total NOX and SO2 emissions as well as the industrial emissions in the YRD region were significantly correlated with the changes in annual NOX and SO2 mixing ratios. The significant decreases in NOX from 2011 to 2016 and SO2 from 2006 to 2016 highlight the effectiveness of relevant control measures on the reduction in NOX and SO2 emissions in the YRD region. A decrease of annual S / N ratio was found, suggesting a better efficacy in the emission reduction of SO2 than NOX. We found gradual changes in average diurnal patterns of NOX and SO2, which could be attributed to increasing contributions of vehicle emissions to NOX and weakening impacts of large sources on the SO2 concentration. This study reaffirms China's success in controlling both NOX and SO2 in the YRD but indicate at the same time a necessity to strengthen the NOX emission control.

scholarly journals Ozone and fine particle in the western Yangtze River Delta: an overview of 1 yr data at the SORPES station

2013 ◽  
Vol 13 (11) ◽  
pp. 5813-5830 ◽  
Author(s):  
A. J. Ding ◽  
C. B. Fu ◽  
X. Q. Yang ◽  
J. N. Sun ◽  
L. F. Zheng ◽  
...  
Keyword(s):  
Air Pollution ◽  
Air Quality ◽  
Yangtze River ◽  
Eastern China ◽  
Ambient Air ◽  
Yangtze River Delta ◽  
River Delta ◽  
Control Measures ◽  
Transport Pathway ◽  
The Yrd

Abstract. This work presents an overview of 1 yr measurements of ozone (O3) and fine particular matter (PM2.5) and related trace gases at a recently developed regional background site, the Station for Observing Regional Processes of the Earth System (SORPES), in the western part of the Yangtze River Delta (YRD) in eastern China. Ozone and PM2.5 showed strong seasonal cycles but with contrast patterns: O3 reached a maximum in warm seasons but PM2.5 in cold seasons. Correlation analysis suggests a VOC-sensitive regime for O3 chemistry and a formation of secondary aerosols under conditions of high O3 in summer. Compared with the National Ambient Air Quality Standards in China, our measurements report 15 days of O3 exceedance and 148 days of PM2.5 exceedance during the 1 yr period, suggesting a severe air pollution situation in this region. Case studies for typical O3 and PM2.5 episodes demonstrated that these episodes were generally associated with an air mass transport pathway over the mid-YRD, i.e., along the Nanjing–Shanghai axis with its city clusters, and showed that synoptic weather played an important role in air pollution, especially for O3. Agricultural burning activities caused high PM2.5 and O3 pollution during harvest seasons, especially in June. A calculation of potential source contributions based on Lagrangian dispersion simulations suggests that emissions from the YRD contributed to over 70% of the O3 precursor CO, with a majority from the mid-YRD. North-YRD and the North China Plain are the main contributors to PM2.5 pollution in this region. This work shows an important environmental impact from industrialization and urbanization in the YRD region, and suggests an urgent need for improving air quality in these areas through collaborative control measures among different administrative regions.

scholarly journals Ozone and fine particle in the western Yangtze River Delta: an overview of 1-yr data at the SORPES station

2013 ◽  
Vol 13 (1) ◽  
pp. 2835-2876 ◽  
Author(s):  
A. J. Ding ◽  
C. B. Fu ◽  
X. Q. Yang ◽  
J. N. Sun ◽  
L. F. Zheng ◽  
...  
Keyword(s):  
Air Pollution ◽  
Air Quality ◽  
Yangtze River ◽  
Ambient Air ◽  
Yangtze River Delta ◽  
River Delta ◽  
Control Measures ◽  
Transport Pathway ◽  
The North ◽  
The Yrd

Abstract. This work presents an overview of 1-yr measurements of ozone (O3) and fine particular matter (PM2.5) and related trace gases at a recently developed regional background site, the Station for Observing Regional Processes of the Earth System (SORPES), in the western part of the Yangtze River Delta (YRD) in East China. O3 and PM2.5 showed distinguished seasonal cycles but with contrast patterns: O3 reached a maximum in warm seasons but PM2.5 in cold seasons. Correlation analysis suggests a VOC-sensitive regime for O3 chemistry and also indicates a substantial formation of secondary aerosols under conditions of high O3 in summer. Compared with the National Ambient Air Quality Standards in China, our measurements report 15 days of O3 exceedance and 148 days of PM2.5 exceedance during the 1-yr period, suggesting a severe air pollution situation in this region. Case studies for typical O3 and PM2.5 episodes demonstrated that these episodes were generally associated with an air mass transport pathway over the mid-YRD, i.e. along the Nanjing-Shanghai axis with its city clusters, and showed that synoptic weather played an important role in air pollution, especially for O3. Agricultural burning activities caused high PM2.5 and O3 pollution during harvest seasons, especially in June. A calculation of potential source contributions based on Lagrangian dispersion simulations suggests that emissions from the YRD contributed to over 70% of the O3 precursor CO, with a majority from the middle-YRD. North-YRD and the North China Plain are the main contributors to PM2.5 pollution in this region, especially for the burning episode days. This work shows an important environmental impact from industrialization and urbanization in the YRD region, and suggests an urgent need for improving air quality in these areas through collaborative control measures among different administrative regions.

scholarly journals Interpreting the <sup>13</sup>C  ∕ <sup>12</sup>C ratio of carbon dioxide in an urban airshed in the Yangtze River Delta, China

2017 ◽  
Vol 17 (5) ◽  
pp. 3385-3399 ◽  
Author(s):  
Jiaping Xu ◽  
Xuhui Lee ◽  
Wei Xiao ◽  
Chang Cao ◽  
Shoudong Liu ◽  
...  
Keyword(s):  
Mole Fraction ◽  
Yangtze River ◽  
Eastern China ◽  
Yangtze River Delta ◽  
River Delta ◽  
Atmospheric Co2 ◽  
The Tibetan Plateau ◽  
Natural Ecosystems ◽  
Carbon Cycles ◽  
The Yrd

Abstract. Observations of atmospheric CO2 mole fraction and the 13C ∕ 12C ratio (expressed as δ13C) in urban airsheds provide constraints on the roles of anthropogenic and natural sources and sinks in local and regional carbon cycles. In this study, we report observations of these quantities in Nanjing at hourly intervals from March 2013 to August 2015, using a laser-based optical instrument. Nanjing is the second largest city located in the highly industrialized Yangtze River Delta (YRD), eastern China. The mean CO2 mole fraction and δ13C were (439.7 ± 7.5) µmol mol−1 and (−8.48 ± 0.56) ‰ over this observational period. The peak monthly mean δ13C (−7.44 ‰, July 2013) was 0.74 ‰ higher than that observed at Mount Waliguan, a WMO (World Meteorological Organization) baseline site on the Tibetan Plateau and upwind of the YRD region. The highly 13C-enriched signal was partly attributed to the influence of cement production in the region. By applying the Miller–Tans method to nighttime and daytime observations to represent signals from the city of Nanjing and the YRD, respectively, we showed that the 13C ∕ 12C ratio of CO2 sources in the Nanjing municipality was (0.21 ± 0.53) ‰ lower than that in the YRD. Flux partitioning calculations revealed that natural ecosystems in the YRD were a negligibly small source of atmospheric CO2.

scholarly journals The influence of spatiality on shipping emissions, air quality and potential human exposure in Yangtze River Delta/Shanghai, China

2018 ◽  
Author(s):  
Junlan Feng ◽  
Yan Zhang ◽  
Shanshan Li ◽  
Jingbo Mao ◽  
Allison P. Patton ◽  
...  
Keyword(s):  
Air Quality ◽  
Yangtze River ◽  
Human Exposure ◽  
Regional Scale ◽  
Yangtze River Delta ◽  
River Delta ◽  
Population Exposure ◽  
Inland Water ◽  
The Yrd ◽  
The Impact

Abstract. The Yangtze River Delta (YRD) and the megacity of Shanghai are host to one of the busiest port clusters in the world, the region also suffers from high levels of air pollution. The goal of this study was to estimate the contributions of shipping to emissions, air quality, and population exposure and characterize their dependence on the geographic spatiality of ship lanes from the regional scale to city scale for 2015. The WRF-CMAQ model was used to simulate the influence of coastal and inland-water shipping, in port emissions, shipping-related cargo transport on air quality and, population-weighted concentrations, a measure of human exposure. Our results showed that the impact of shipping on air quality in the YRD was attributable primarily to shipping emissions within 12 NM of shore, but emissions coming from the coastal area of 24 to 96 NM still contributed substantially to ship-related PM2.5 concentrations in YRD. The overall contribution of ships to PM2.5 concentration in YRD could reach to 4.62 μg/m3 in summer when monsoon winds transport shipping emissions onshore. In Shanghai city, inland-water going ships were major contributors (40–80 %) to the shipping impact on urban air quality. Given the proximity of inland-water ships to urban populations of Shanghai, the emissions of inland-water ships contributed more to population-weighted concentrations. These research results provide scientific evidence to inform policies for controlling future shipping emissions; in particular, stricter standards could be considered for the ships on inland rivers and other waterways close to residential regions.

Long-term observations of tropospheric NO2, SO2 and HCHO by MAX-DOAS in Yangtze River Delta area, China

2018 ◽  
Vol 71 ◽  
pp. 207-221 ◽  
Author(s):  
Xin Tian ◽  
Pinhua Xie ◽  
Jin Xu ◽  
Ang Li ◽  
Yang Wang ◽  
...  
Keyword(s):  
Yangtze River ◽  
Yangtze River Delta ◽  
River Delta ◽  
Delta Area ◽  
Tropospheric No2

scholarly journals Integrating Sustainability Assessment into Decoupling Analysis: A Focus on the Yangtze River Delta Urban Agglomerations

2020 ◽  
Vol 12 (19) ◽  
pp. 7872
Author(s):  
Yijia Huang ◽  
Jiaqi Zhang ◽  
Jinqun Wu
Keyword(s):  
Environmental Sustainability ◽  
Yangtze River ◽  
Sustainability Assessment ◽  
Yangtze River Delta ◽  
River Delta ◽  
The Yangtze River ◽  
Urban Agglomerations ◽  
Decoupling Analysis ◽  
The Yrd ◽  
The Yangtze River Delta

Rapid urbanization has led to a growing number of environmental challenges in large parts of China, where the Yangtze River Delta (YRD) urban agglomerations serve as a typical example. To evaluate the relationship between environmental sustainability gaps and urbanization in 26 cities of the YRD, this study revisited the environmental sustainability assessment (ESA) by combining the metrics of environmental footprints and planetary boundaries at the city level, and then integrated the footprint-boundary ESA framework into decoupling analysis. The results demonstrated considerable spatiotemporal heterogeneity in the environmental sustainability of water use, land use, carbon emissions, nitrogen emissions, phosphorus emissions and PM2.5 emissions across the YRD cities during the study period 2007–2017. Decoupling analysis revealed a positive sign that more than half of the 26 cities had achieved the decoupling of each category of environmental sustainability gaps from urbanization since 2014, especially for nitrogen and phosphorus emissions. On the basis of ESA and decoupling analysis, all the cities were categorized into six patterns, for which the optimal pathways towards sustainable development were discussed in depth. Our study will assist policy makers in formulating more tangible and differentiated policies to achieve decoupling between environmental sustainability gaps and urbanization.

scholarly journals Integrating Ecosystem Services Supply–Demand and Spatial Relationships for Intercity Cooperation: A Case Study of the Yangtze River Delta

2020 ◽  
Vol 12 (10) ◽  
pp. 4131
Author(s):  
Wenbo Cai ◽  
Tong Wu ◽  
Wei Jiang ◽  
Wanting Peng ◽  
Yongli Cai
Keyword(s):  
Ecosystem Services ◽  
Yangtze River ◽  
Urban Expansion ◽  
Supply And Demand ◽  
Spatial Relations ◽  
Yangtze River Delta ◽  
River Delta ◽  
Spatial Relationships ◽  
Environmental Cooperation ◽  
The Yrd

Transboundary environmental problems caused by urban expansion and economic growth cannot be solved by individual cities. Successful intercity environmental cooperation relies on the clear identification and definition of the rights and obligations of each city. An Ecosystem services (ES) approach not only budgets the ES supply and demand of a city, but also defines the spatial relationships between Services Provisioning Areas (SPA) and Services Benefiting Areas (SBA). However, to date, quantitative studies integrating ES budgets and spatial relations have been scarce. This study integrates ecosystem services supply–demand budgeting with flow direction analysis to identify intercity environmental cooperation in the highly urbanized Yangtze River Delta (YRD) region of China for water-related ecosystem services (flood protection, erosion regulation and water purification). The results demonstrated that there were significant spatial mismatches in the supply and demand of three water-related ES among 16 core cities in the YRD region: five to six cities in the southern part of the region had significant service surpluses, while ten to 11 cities in the north–central part had significant service deficits. We then went on to offer definitions for Ecosystem Services Surplus City, Ecosystem Services Deficit City and Ecosystem Services Balance City, as well as Service Provisioning City, Service Benefiting City and Service Connecting City in which to categorize cities in the YRD Region. Furthermore, we identified two intercity cooperation types and two non-cooperation types. This framework can be used to promote ecological integration in highly urbanized regions to advance sustainable development.

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