scholarly journals Review of “Technical Note: Effect of varying the λ = 185 and 254 nm photon flux ratio on radical generation in oxidation flow reactors”

2020 ◽  
2020 ◽  
Vol 20 (21) ◽  
pp. 13417-13424
Author(s):  
Jake P. Rowe ◽  
Andrew T. Lambe ◽  
William H. Brune

Abstract. Oxidation flow reactors (OFRs) complement environmental smog chambers as a portable, low-cost technique for exposing atmospheric compounds to oxidants such as ozone (O3), nitrate (NO3) radicals, and hydroxyl (OH) radicals. OH is most commonly generated in OFRs via photolysis of externally added O3 at λ=254 nm (OFR254) or combined photolysis of O2 and H2O at λ=185 nm plus photolysis of O3 at λ=254 nm (OFR185) using low-pressure mercury (Hg) lamps. Whereas OFR254 radical generation is influenced by [O3], [H2O], and photon flux at λ=254 nm (I254), OFR185 radical generation is influenced by [O2], [H2O], I185, and I254. Because the ratio of photon fluxes, I185:I254, is OFR-specific, OFR185 performance varies between different systems even when constant [H2O] and I254 are maintained. Thus, calibrations and models developed for one OFR185 system may not be applicable to another. To investigate these issues, we conducted a series of experiments in which I185:I254 emitted by Hg lamps installed in an OFR was systematically varied by fusing multiple segments of lamp quartz together that either transmitted or blocked λ=185 nm radiation. Integrated OH exposure (OHexp) values achieved for each lamp type were obtained using the tracer decay method as a function of UV intensity, humidity, residence time, and external OH reactivity (OHRext). Following previous related studies, a photochemical box model was used to develop a generalized OHexp estimation equation as a function of [H2O], [O3], and OHRext that is applicable for I185:I254≈0.001 to 0.1.


2020 ◽  
Author(s):  
Jake P. Rowe ◽  
Andrew T. Lambe ◽  
William H. Brune

Abstract. Oxidation flow reactors (OFRs) complement environmental smog chambers as a portable, low-cost technique for exposing atmospheric compounds to oxidants such as ozone (O3) and hydroxyl (OH) radicals. OH is most commonly generated in OFRs via photolysis of externally added O3 at λ = 254  nm (OFR254), or combined photolysis of O2 and H2O at λ = 185 nm plus photolysis of O3 at λ = 254 nm (OFR185) using low-pressure mercury (Hg) lamps. Whereas OFR254 radical generation is influenced by [O3], [H2O], and photon flux at λ = 254 nm (I254), OFR185 radical generation is influenced by [O2], [H2O], I185, and I254. Because the ratio of photon fluxes, I185 : I254, is OFR-specific, OFR185 performance varies between different systems even when constant H2O and I254 are maintained. Thus, calibrations and models developed for one OFR185 system may not be applicable to another. To investigate these issues, we conducted a series of experiments in which I185 : I254 emitted by Hg lamps installed in an OFR was systematically varied by fusing multiple segments of lamp quartz together that either transmitted or blocked 185 nm radiation. Integrated OH exposure (OHexp) values achieved for each lamp type were obtained using the tracer decay method as a function of UV intensity, humidity, residence time, and external OH reactivity (OHRext). Following previous related studies, a photochemical box model was used to develop a generalized OHexp estimation equation as a function of [H2O], [O3] and OHRext that is applicable for I185 : I254 ≈ 0.001 to 0.1.


HortScience ◽  
2019 ◽  
Vol 54 (7) ◽  
pp. 1168-1174 ◽  
Author(s):  
Chase Jones-Baumgardt ◽  
David Llewellyn ◽  
Qinglu Ying ◽  
Youbin Zheng

Indoor farming is an increasingly popular approach for growing leafy vegetables, and under this production system, artificial light provides the sole source (SS) of radiation for photosynthesis and light signaling. With newer horticultural light-emitting diodes (LEDs), growers have the ability to manipulate the lighting environment to achieve specific production goals. However, there is limited research on LED lighting specific to microgreen production, and available research shows that there is variability in how microgreens respond to their lighting environment. The present study examined the effects of SS light intensity (LI) on growth, yield, and quality of kale (Brassica napus L. ‘Red Russian’), cabbage (Brassica oleracea L.), arugula (Eruca sativa L.), and mustard (Brassica juncea L. ‘Ruby Streaks’) microgreens grown in a walk-in growth chamber. SS LEDs were used to provide six target photosynthetic photon flux density density (PPFD) treatments: 100, 200, 300, 400, 500, and 600 μmol·m−2·s−1 with a photon flux ratio of 15 blue: 85 red and a 16-hour photoperiod. As LI increased from 100 to 600 μmol·m−2· s−1, fresh weight (FW) increased by 0.59 kg·m−2 (36%), 0.70 kg·m−2 (56%), 0.71 kg·m−2 (76%), and 0.67 kg·m−2 (82%) for kale, cabbage, arugula, and mustard, respectively. Similarly, dry weight (DW) increased by 47 g·m−2 (65%), 45 g·m−2 (69%), 64 g·m−2 (122%), and 65 g·m−2 (145%) for kale, cabbage, arugula, and mustard, respectively, as LI increased from 100 to 600 μmol·m−2· s−1. Increasing LI decreased hypocotyl length and hue angle linearly in all genotypes. Saturation of cabbage and mustard decreased linearly by 18% and 36%, respectively, as LI increased from 100 to 600 μmol·m−2·s−1. Growers can use the results of this study to optimize SS LI for their production systems, genotypes, and production goals.


2005 ◽  
Vol 22 (2) ◽  
pp. 102-110 ◽  
Author(s):  
Hailu Sharew ◽  
Anne Hairston-Strang

Abstract Survival, height, and diameter growth of seedlings were evaluated for three years after planting using five types of tree shelters and seven species: green ash (Fraxinus pennylvanica), northern red oak (Quercus rubra L.), pin oak (Q. palustris), American sycamore (Platanus occidentalis), black walnut (Juglans nigra L.), flowering dogwood (Cornus florida), and eastern white pine (Pinus strobus). Differences in shelter environments were measured, including: light transmission measured as percent photosynthetic photon flux, ratio of red:far red (r:f-r) light from the red and far-red wavelengths, and air temperature inside the tubes. The differences seen in seedling survival were not significant (p < 0.05) for the presence or type of tree tube, with an average survival of 96% for all but two species. For most species, seedlings grown in high light-transmitting tubes with proportional r:f-r ratio light showed superior height growth (e.g., Miracle Tube, Tree-Pro, and Protex). Diameter growth generally decreased in shelters. Sycamore showed no significant benefit from the use of tubes. The lowest diameter increments were seen using Tubex brown and Mesh Guard shelters, which had low light transmission with high r:f-r ratio and mechanical damage, respectively. Light transmission in translucent tree tubes was within the ranges found in open canopy forest, but the proportion of growth-promoting far-red wavelength was generally lower. In tubes with higher light transmission, r:f-r ratio is closer to natural ranges for that light level. For tubes with lower light transmissivity, this information suggests that seedling height growth might be improved if red wavelengths were blocked more strongly.North. J. appl. For. North. J. Appl. For. 22(2):102–110.


1999 ◽  
Vol 68 (1) ◽  
pp. 189-191 ◽  
Author(s):  
Takashi Ikeda ◽  
Kunihiko Okada ◽  
Hiroko Yamazaki ◽  
Ryu Oi ◽  
Shigeo Imada

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