scholarly journals The CO<sub>2</sub> tracer clock for the Tropical Tropopause Layer

2007 ◽  
Vol 7 (14) ◽  
pp. 3989-4000 ◽  
Author(s):  
S. Park ◽  
R. Jiménez ◽  
B. C. Daube ◽  
L. Pfister ◽  
T. J. Conway ◽  
...  
Keyword(s):  
Large Scale ◽  
Deep Convection ◽  
Potential Temperature ◽  
Co2 Concentration ◽  
Vertical Gradient ◽  
Warm Pool ◽  
Tropical Tropopause Layer ◽  
Ascent Rate ◽  
Tropical Tropopause ◽  
Validation Experiment

Abstract. Observations of CO2 were made in the upper troposphere and lower stratosphere in the deep tropics in order to determine the patterns of large-scale vertical transport and age of air in the Tropical Tropopause Layer (TTL). Flights aboard the NASA WB-57F aircraft over Central America and adjacent ocean areas took place in January and February, 2004 (Pre-AURA Validation Experiment, Pre-AVE) and 2006 (Costa Rice AVE, CR-AVE), and for the same flight dates of 2006, aboard the Proteus aircraft from the surface to 15 km over Darwin, Australia (Tropical Warm Pool International Cloud Experiment, TWP-ICE). The data demonstrate that the TTL is composed of two layers with distinctive features: (1) the lower TTL, 350–360 K (potential temperature(θ); approximately 12–14 km), is subject to inputs of convective outflows, as indicated by layers of variable CO2 concentrations, with air parcels of zero age distributed throughout the layer; (2) the upper TTL, from θ=~360 K to ~390 K (14–18 km), ascends slowly and ages uniformly, as shown by a linear decline in CO2 mixing ratio tightly correlated with altitude, associated with increasing age. This division is confirmed by ensemble trajectory analysis. The CO2 concentration at the level of 360 K was 380.0(±0.2) ppmv, indistinguishable from surface site values in the Intertropical Convergence Zone (ITCZ) for the flight dates. Values declined with altitude to 379.2(±0.2) ppmv at 390 K, implying that air in the upper TTL monotonically ages while ascending. In combination with the winter slope of the CO2 seasonal cycle (+10.8±0.4 ppmv/yr), the vertical gradient of –0.78 (±0.09) ppmv gives a mean age of 26(±3) days for the air at 390 K and a mean ascent rate of 1.5(±0.3) mm s−1. The TTL near 360 K in the Southern Hemisphere over Australia is very close in CO2 composition to the TTL in the Northern Hemisphere over Costa Rica, with strong contrasts emerging at lower altitudes (<360 K). Both Pre-AVE and CR-AVE CO2 observed unexpected input from deep convection over Amazônia deep into the TTL. The CO2 data confirm the operation of a highly accurate tracer clock in the TTL that provides a direct measure of the ascent rate of the TTL and of the age of air entering the stratosphere.

scholarly journals The CO<sub>2</sub> tracer clock for the Tropical Tropopause Layer

2007 ◽  
Vol 7 (3) ◽  
pp. 6655-6685 ◽  
Author(s):  
S. Park ◽  
R. Jiménez ◽  
B. C. Daube ◽  
L. Pfister ◽  
T. J. Conway ◽  
...  
Keyword(s):  
Large Scale ◽  
Deep Convection ◽  
Potential Temperature ◽  
Co2 Concentration ◽  
Vertical Gradient ◽  
Warm Pool ◽  
Tropical Tropopause Layer ◽  
Ascent Rate ◽  
Tropical Tropopause ◽  
Validation Experiment

Abstract. Observations of CO2 were made in the upper troposphere and lower stratosphere in the deep tropics in order to determine the patterns of large-scale vertical transport and age of air in the Tropical Tropopause Layer (TTL). Flights aboard the NASA WB-57F aircraft over Central America and adjacent ocean areas took place in January and February, 2004 (Pre-AURA Validation Experiment, Pre-AVE) and 2006 (Costa Rice AVE, CR-AVE), and for the same flight dates of 2006, aboard the Proteus aircraft from the surface to 15 km over Darwin, Australia (Tropical Warm Pool International Cloud Experiment , TWP-ICE). The data demonstrate that the TTL is composed of two layers with distinctive features: (1) the lower TTL, 350–360 K (potential temperature (θ); approximately 12–14 km), is subject to inputs of convective outflows, as indicated by layers of variable CO2 concentrations, with air parcels of zero age distributed throughout the layer; (2) the upper TTL, from θ= ~360 K to ~390 K (14–18 km), ascends slowly and ages uniformly, as shown by a linear decline in CO2 mixing ratio tightly correlated with altitude, associated with increasing age. This division is confirmed by ensemble trajectory analysis. The CO2 concentration at the level of 360 K was 380.0(±0.2) ppmv, indistinguishable from surface site values in the Intertropical Convergence Zone (ITCZ) for the flight dates. Values declined with altitude to 379.2(±0.2) ppmv at 390 K, implying that air in the upper TTL monotonically ages while ascending. In combination with the winter slope of the CO2 seasonal cycle (+10.8±0.4 ppmv/yr), the vertical gradient of 0.78 (±0.09) ppmv gives a mean age of 26(±3) days for the air at 390 K and a mean ascent rate of 1.5(±0.3) mm s−1. The TTL near 360 K in the Southern Hemisphere over Australia is very close in CO2 composition to the TTL in the Northern Hemisphere over Costa Rica, with strong contrasts emerging at lower altitudes (<360 K). Both Pre-AVE and CR-AVE CO2 observed unexpected input from deep convection over Amazônia deep into the TTL. The CO2 data confirm the operation of a highly accurate tracer clock in the TTL that provides a direct measure of the ascent rate of the TTL and of the age of air entering the stratosphere.

scholarly journals Ozonesonde profiles from the West Pacific Warm Pool

2015 ◽  
Vol 15 (12) ◽  
pp. 16655-16696 ◽  
Author(s):  
R. Newton ◽  
G. Vaughan ◽  
H. M. A. Ricketts ◽  
L. L. Pan ◽  
A. J. Weinheimer ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Ozone Concentration ◽  
Deep Convection ◽  
Warm Pool ◽  
Atmospheric Composition ◽  
Measured Signal ◽  
Background Current ◽  
West Pacific ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause

Abstract. We present a series of ozonesonde profiles measured from Manus Island, Papua New Guinea, during February 2014. The experiment formed a part of a wider airborne campaign involving three aircraft based in Guam, to characterise the atmospheric composition above the tropical West Pacific in unprecedented detail. Thirty-nine ozonesondes were launched between 2 and 25 February, of which 34 gave good ozone profiles. Particular attention was paid to measuring the background current of the ozonesonde before launch, as this can amount to half the measured signal in the tropical tropopause layer (TTL). An unexpected contamination event affected these measurements and required a departure from standard operating procedures for the ozonesondes. Comparison with aircraft measurements allows validation of the measured ozone profiles and confirms that for well-characterized sondes (background current <50 nA) a constant background current should be assumed throughout the profile, equal to the minimum value measured during preparation just before launch. From this set of 34 ozonesondes, the minimum reproducible ozone concentration measured in the TTL was 12–13 ppbv; no examples of near-zero ozone concentration as reported by other recent papers were measured. The lowest ozone concentrations coincided with outflow from extensive deep convection to the east of Manus, consistent with uplift of ozone-poor air from the boundary layer. However, these minima were lower than the ozone concentration measured through most of the boundary layer, and were matched only by measurements at the surface in Manus.

Moisture fluxes in the tropics dominated by deep convection up to near tropical tropopause levels

2021 ◽  
Author(s):  
Maximilien Bolot ◽  
Stephan Fueglistaler
Keyword(s):  
Large Scale ◽  
Deep Convection ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause ◽  
Convective Scale ◽  
Moisture Fluxes ◽  
Global Impacts ◽  
Observational Estimate ◽  
Cold Point ◽  
Open Question

&lt;p&gt;The role played by tropical storms in the tropical tropopause layer (TTL), the transitional layer regulating the flux into the stratosphere of trace gases affecting radiation and the ozone layer, has been a long-standing open question. Progress has been slow because of computational limitations and challenging conditions for measurements and most numerical studies have used simulations over limited domains whose results must be upscaled to the tropical surface to infer global impacts. We compute the first global observational estimate of the convective ice flux at near tropical tropopause levels by using spaceborne lidar measurements from CALIOP. The calculation uses a method to convert from lidar extinction to sedimenting ice flux and uses error propagation to provide margins of uncertainty. We show that, at any given level in the TTL, the sedimenting ice flux exceeds the inflow of vapor computed from ERA5 reanalysis, revealing additional ice transport and allowing to deduce the advective ice flux as a function of altitude. The contribution to this flux of large-scale motions (resolved by ERA5) is computed and the residual is hypothesized to represent the flux of ice on the convective scale. Results show without ambiguity that the upward ice flux in deep convection dominates moisture transport up to close to the level of the cold point tropopause.&lt;/p&gt;

scholarly journals Ozonesonde profiles from the West Pacific Warm Pool: measurements and validation

2016 ◽  
Vol 16 (2) ◽  
pp. 619-634 ◽  
Author(s):  
R. Newton ◽  
G. Vaughan ◽  
H. M. A. Ricketts ◽  
L. L. Pan ◽  
A. J. Weinheimer ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Ozone Concentration ◽  
Deep Convection ◽  
Warm Pool ◽  
Atmospheric Composition ◽  
Measured Signal ◽  
Background Current ◽  
West Pacific ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause

Abstract. We present a series of ozonesonde profiles measured from Manus Island, Papua New Guinea, during February 2014, with new insights on the calibration of ozonesondes for measurements in the tropical troposphere. The experiment formed a part of a wider airborne campaign involving three aircraft based in Guam, to characterise the atmospheric composition above the tropical West Pacific in unprecedented detail. Thirty-nine ozonesondes were launched between 2 and 25 February of which 34 gave good ozone profiles. Particular attention was paid to evaluating the background current of the ozonesondes, as this can amount to half the measured signal in the tropical tropopause layer (TTL). An unexpected contamination event affected the measurements and required a departure from standard operating procedures for the ozonesondes. The most significant departure was not exposing the sondes to ozone during preparation, which meant that the background current remained stable before launch. Comparison with aircraft measurements allows validation of the measured ozone profiles and confirms that for well-characterized sondes (background current ∼  50 nA) a constant background current could be assumed throughout the profile, equal to the minimum value measured during preparation just before launch. From this set of 34 ozonesondes, the minimum reproducible ozone concentration measured in the TTL was 12–13 ppbv; no examples of ozone concentrations  <  5 ppbv, as reported by other recent papers, were measured. The lowest ozone concentrations coincided with outflow from extensive deep convection to the east of Manus, consistent with uplift of ozone-poor air from the boundary layer. However, these minima were lower than the ozone concentration measured through most of the boundary layer, and were matched only by measurements at the surface in Manus.

scholarly journals Modelling deep convection and its impacts on the tropical tropopause layer

2010 ◽  
Vol 10 (8) ◽  
pp. 20267-20302 ◽  
Author(s):  
J. S. Hosking ◽  
M. R. Russo ◽  
P. Braesicke ◽  
J. A. Pyle
Keyword(s):  
Deep Convection ◽  
Warm Pool ◽  
Horizontal Structure ◽  
Tropical Regions ◽  
Tropical Tropopause Layer ◽  
Tropical Warm Pool ◽  
Tropical Tropopause ◽  
Rapid Transport ◽  
The Uk ◽  
The Impact

Abstract. The UK Met Office's Unified Model is used at a high global resolution (N216, ~0.83° × ~0.56°, ~60 km) to assess the impact of deep tropical convection on the structure of the tropical tropopause layer (TTL). We focus on the potential for rapid transport of short-lived ozone depleting species to the stratosphere by rapid convective uplift. The modelled horizontal structure of organised convection is shown to match closely with signatures found in the OLR satellite data. In the model, deep convective elevators rapidly lift air from 4–5 km up to 12–14 km. The influx of tropospheric air entering the TTL (11–12 km) is similar for all tropical regions with most convection stopping below ~14 km. The tropical tropopause is coldest and driest between November and February, coinciding with the greatest upwelling over the tropical warm pool. As this deep convection is co-located with bromine-rich biogenic coastal emissions, this period and location could potentially be the preferential gateway for stratospheric bromine.

scholarly journals Modelling deep convection and its impacts on the tropical tropopause layer

2010 ◽  
Vol 10 (22) ◽  
pp. 11175-11188 ◽  
Author(s):  
J. S. Hosking ◽  
M. R. Russo ◽  
P. Braesicke ◽  
J. A. Pyle
Keyword(s):  
Deep Convection ◽  
Warm Pool ◽  
Horizontal Structure ◽  
Tropical Regions ◽  
Tropical Tropopause Layer ◽  
Tropical Warm Pool ◽  
Tropical Tropopause ◽  
Rapid Transport ◽  
The Uk ◽  
The Impact

Abstract. The UK Met Office's Unified Model is used at a climate resolution (N216, ~0.83°×~0.56°, ~60 km) to assess the impact of deep tropical convection on the structure of the tropical tropopause layer (TTL). We focus on the potential for rapid transport of short-lived ozone depleting species to the stratosphere by rapid convective uplift. The modelled horizontal structure of organised convection is shown to match closely with signatures found in the OLR satellite data. In the model, deep convective elevators rapidly lift air from 4–5 km up to 12–14 km. The influx of tropospheric air entering the TTL (11–12 km) is similar for all tropical regions with most convection stopping below ~14 km. The tropical tropopause is coldest and driest between November and February, coinciding with the greatest upwelling over the tropical warm pool. As this deep convection is co-located with bromine-rich biogenic coastal emissions, this period and location could potentially be the preferential gateway for stratospheric bromine.

scholarly journals Vertical transport rates and concentrations of OH and Cl radicals in the Tropical Tropopause Layer from Observations of CO<sub>2</sub> and halocarbons: implications for distributions of long- and short-lived chemical species

2010 ◽  
Vol 10 (3) ◽  
pp. 6059-6095
Author(s):  
S. Park ◽  
E. L. Atlas ◽  
R. Jiménez ◽  
B. C. Daube ◽  
E. W. Gottlieb ◽  
...  
Keyword(s):  
Large Scale ◽  
Chemical Species ◽  
Vertical Transport ◽  
Upward Movement ◽  
Upper Troposphere ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause ◽  
Validation Experiment ◽  
In Situ Observations

Abstract. Rates for large-scale vertical transport of air in the Tropical Tropopause Layer (TTL) were determined using high-resolution, in situ observations of CO2 concentrations in the tropical upper troposphere and lower stratosphere during the NASA Tropical Composition, Cloud and Climate Coupling (TC4) campaign in August 2007. Upward movement of trace gases in the deep tropics was notably slower in TC4 than during the Costa Rica AURA Validation Experiment (CR-AVE), in January 2006. Transport rates in the TTL were combined with in situ measurements of chlorinated and brominated organic compounds from whole air samples to determine chemical loss rates for reactive chemical species, providing empirical vertical profiles for 24-h mean concentrations of hydroxyl radicals (OH) and chlorine atoms in the TTL. The analysis shows that important short-lived species such as CHCl3, CH2Cl2, and CH2Br2 have longer chemical lifetimes than the time for transit of the TTL, implying that these species, which are not included in most models, could readily reach the stratosphere and make significant contributions of chlorine and/or bromine to stratospheric loading.

scholarly journals Vertical transport rates and concentrations of OH and Cl radicals in the Tropical Tropopause Layer from observations of CO<sub>2</sub> and halocarbons: implications for distributions of long- and short-lived chemical species

2010 ◽  
Vol 10 (14) ◽  
pp. 6669-6684 ◽  
Author(s):  
S. Park ◽  
E. L. Atlas ◽  
R. Jiménez ◽  
B. C. Daube ◽  
E. W. Gottlieb ◽  
...  
Keyword(s):  
Large Scale ◽  
Chemical Species ◽  
Vertical Transport ◽  
Upward Movement ◽  
Upper Troposphere ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause ◽  
Validation Experiment ◽  
In Situ Observations

Abstract. Rates for large-scale vertical transport of air in the Tropical Tropopause Layer (TTL) were determined using high-resolution, in situ observations of CO2 concentrations in the tropical upper troposphere and lower stratosphere during the NASA Tropical Composition, Cloud and Climate Coupling (TC4) campaign in August 2007. Upward movement of trace gases in the deep tropics was notably slower in TC4 than during the Costa Rica AURA Validation Experiment (CR-AVE), in January 2006. Transport rates in the TTL were combined with in situ measurements of chlorinated and brominated organic compounds from whole air samples to determine chemical loss rates for reactive chemical species, providing empirical vertical profiles for 24-h mean concentrations of hydroxyl radicals (OH) and chlorine atoms in the TTL. The analysis shows that important short-lived species such as CHCl3, CH2Cl2, and CH2Br2 have longer chemical lifetimes than the time for transit of the TTL, implying that these species, which are not included in most models, could readily reach the stratosphere and make significant contributions of chlorine and/or bromine to stratospheric loading.

scholarly journals Model study of the cross-tropopause transport of biomass burning pollution

2007 ◽  
Vol 7 (14) ◽  
pp. 3713-3736 ◽  
Author(s):  
B. N. Duncan ◽  
S. E. Strahan ◽  
Y. Yoshida ◽  
S. D. Steenrod ◽  
N. Livesey
Keyword(s):  
Biomass Burning ◽  
El Niño ◽  
Fossil Fuels ◽  
Extreme Event ◽  
El Nino ◽  
Deep Convection ◽  
Tropical Tropopause Layer ◽  
Tropical Tropopause ◽  
El Niño Event ◽  
The Impact

Abstract. We present a modeling study of the troposphere-to-stratosphere transport (TST) of pollution from major biomass burning regions to the tropical upper troposphere and lower stratosphere (UT/LS). TST occurs predominately through 1) slow ascent in the tropical tropopause layer (TTL) to the LS and 2) quasi-horizontal exchange to the lowermost stratosphere (LMS). We show that biomass burning pollution regularly and significantly impacts the composition of the TTL, LS, and LMS. Carbon monoxide (CO) in the LS in our simulation and data from the Aura Microwave Limb Sounder (MLS) shows an annual oscillation in its composition that results from the interaction of an annual oscillation in slow ascent from the TTL to the LS and seasonal variations in sources, including a semi-annual oscillation in CO from biomass burning. The impacts of CO sources that peak when ascent is seasonally low are damped (e.g. Southern Hemisphere biomass burning) and vice-versa for sources that peak when ascent is seasonally high (e.g. extra-tropical fossil fuels). Interannual variation of CO in the UT/LS is caused primarily by year-to-year variations in biomass burning and the locations of deep convection. During our study period, 1994–1998, we find that the highest concentrations of CO in the UT/LS occurred during the strong 1997–1998 El Niño event for two reasons: i. tropical deep convection shifted to the eastern Pacific Ocean, closer to South American and African CO sources, and ii. emissions from Indonesian biomass burning were higher. This extreme event can be seen as an upper bound on the impact of biomass burning pollution on the UT/LS. We estimate that the 1997 Indonesian wildfires increased CO in the entire TTL and tropical LS (>60 mb) by more than 40% and 10%, respectively, for several months. Zonal mean ozone increased and the hydroxyl radical decreased by as much as 20%, increasing the lifetimes and, subsequently TST, of trace gases. Our results indicate that the impact of biomass burning pollution on the UT/LS is likely greatest during an El Niño event due to favorable dynamics and historically higher burning rates.

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