Analysis of Storage Effects in the Recirculation Zone Based on the Junction Angle of Channel Confluence

In this study, numerical simulations using the Environmental Fluid Dynamics Code model were conducted to elucidate the effects of flow structures in the recirculation zone on solute storage based on the junction angle. Numerical simulations were performed at a junction angle of 30° to 90° with a momentum flux ratio of 1.62. The simulation results revealed that an increase in the junction angle caused the recirculation zone length and width to increase and strengthened the development of helical motion. The helical motion increased the vertical gradient of the mixing layer and the mixing metric of the dosage curves. The recirculation zone accumulated the solute as a storage zone, which formed a long tail in the concentration curves. The interaction between the helical motion and recirculation zone affected the transverse mixing, such that the transverse dispersion had a positive relationship with the helical motion intensity and a negative relationship with the recirculation zone size. Transverse mixing exhibited an inverse relationship with the mass exchange rate of the recirculation zone. These results indicate that the transverse dispersion is replaced by mixing due to strongly developed storage zones.

Transport-driven aerosol differences above and below the canopy of a mixed deciduous forest

Exchanges of energy and mass between the surrounding air and plant surfaces occur below, within, and above a forest's vegetative canopy. The canopy also can lead to vertical gradients in light, trace gases, oxidant availability, turbulent mixing, and properties and concentrations of organic aerosol (OA). In this study, a high-resolution time-of-flight aerosol mass spectrometer was used to measure non-refractory submicron aerosol composition and concentration above (30 m) and below (6 m) a forest canopy in a mixed deciduous forest at the Program for Research on Oxidants: PHotochemistry, Emissions, and Transport tower in northern Michigan during the summer of 2016. Three OA factors are resolved using positive matrix factorization: more-oxidized oxygenated organic aerosol (MO-OOA), isoprene-epoxydiol-derived organic aerosol (IEPOX-OA), and 91Fac (a factor characterized with a distinct fragment ion at m/z 91) from both the above- and the below-canopy inlets. MO-OOA was most strongly associated with long-range transport from more polluted regions to the south, while IEPOX-OA and 91Fac were associated with shorter-range transport and local oxidation chemistry. Overall vertical similarity in aerosol composition, degrees of oxidation, and diurnal profiles between the two inlets was observed throughout the campaign, which implies that rapid in-canopy transport of aerosols is efficient enough to cause relatively consistent vertical distributions of aerosols at this scale. However, four distinct vertical gradient episodes are identified for OA, with vertical concentration differences (above-canopy minus below-canopy concentrations) in total OA of up to 0.8 µg m−3, a value that is 42 % of the campaign average OA concentration of 1.9 µg m−3. The magnitude of these differences correlated with concurrent vertical differences in either sulfate aerosol or ozone. These differences are likely driven by a combination of long-range transport mechanisms, canopy-scale mixing, and local chemistry. These results emphasize the importance of including vertical and horizontal transport mechanisms when interpreting trace gas and aerosol data in forested environments.

Raytracing Simulated GPS Radio Wave Propagation Paths Experiencing Large Disturbances When Going through the Top of the Sub-Cloud Layer

Global positioning satellite system (GPS) radio waves that reach the tropical lower troposphere are strongly affected by small-scale water vapor fluctuations. We examine along-the-ray simulations of the impact parameter at every ray integration step using the high-resolution European Centre for Medium-Range Weather Forecasts ERA5 reanalysis as the input model states. We find that disturbances to the impact parameter arise when ray paths go through the top of the sub-cloud layer, where there is a pronounced reduction with increasing height in the humidity, and wet refractivity has a strong local vertical gradient, creating multipath. Additionally, the horizontal gradients of refractivity cause the impact parameter to vary along the ray. The disturbances to the impact parameter are confined to an area about 250 km horizontally and 4 km vertically from the perigee point. Beyond 250 km from the perigee, the impact parameter remains constant. The vertical gradient of refractivity is largest at the top of the sub-cloud layer, usually between 1.5 and 3.0 km, and becomes negligibly small above 4 km.

Comparison of Linear Response Theory, Projected Initial Maximum Overlap Method, and Molecular Dynamics Based Vibronic Spectra: The Case of Methylene Blue

Simulation of optical spectra is essential to molecular characterization and, in many cases, critical for interpreting experimental spectra. The most common method for simulating vibronic absorption spectra relies on the geometry optimization and computation of normal modes for ground and excited states. In this report, we show that utilization of such a procedure within an adiabatic linear response theory framework may lead to state mixings and a breakdown of the Born-Oppenheimer approximation, resulting in a poor description of absorption spectra. In contrast, computing excited states via a self-consistent eld method in conjunction with a maximum overlap model produces states that are not subject to such mixings. We show that this latter method produces vibronic spectra much more aligned with vertical excitation procedures, such as those computed from a vertical gradient or molecular dynamics trajectory-based approach. For the methylene blue chromophore, we compare vibronic absorption spectra computed with: an adiabatic Hessian approach with linear response theory optimized structures and normal modes, a vertical gradient procedure, the Hessian and normal modes of maximum overlap method optimized structures, and excitation energy time correlation functions generated from a molecular dynamics trajectory. Due to mixing between the bright S1 and dark S2 surfaces near the S1 minimum, computing the adiabatic Hessian with linear response theory time-dependent density functional theory with the B3LYP density functional predicts a large vibronic shoulder for the absorption spectrum that is not present for any of the other methods. Spectral densities are analyzed and we compare the behavior of the key normal mode that in linear response theory strongly couples to the optical excitation while showing S1/ S2 state mixings. Overall, our study provides a note of caution in computing vibronic spectra using the excited state adiabatic Hessian of linear response theory optimized structures and also showcases three alternatives that are not as subject to adiabatic state mixing effects.

Vertical Vortex Development in Hurricane Michael (2018) during Rapid Intensification

The landfall of Hurricane Michael (2018) at category 5 intensity occurred after rapid intensification (RI) spanning much of the storm’s lifetime. Four Hurricane Hunter aircraft missions observed the RI period with tail Doppler radar (TDR). Data from each of the 14 aircraft passes through the storm were quality controlled via a combination of interactive and machine learning techniques. TDR data from each pass were synthesized using the SAMURAI variational wind retrieval technique to yield three-dimensional kinematic fields of the storm to examine inner core processes during RI. Vorticity and angular momentum increased and concentrated in the eyewall region. A vorticity budget analysis indicates the tendencies became more axisymmetric over time. In this study we focus in particular on how the eyewall vorticity tower builds vertically into the upper levels. Horizontal vorticity associated with the vertical gradient of tangential wind was tilted into the vertical by the eyewall updraft to yield a positive vertical vorticity tendency inward atop the existing vorticity tower, that is further developed locally upward and outward along the sloped eyewall through advection and stretching. Observed maintenance of thermal wind balance from a thermodynamic retrieval shows evidence of a strengthening warm core, which aided in lowering surface pressure and further contributed to the efficient intensification in the latter stages of this RI event.

Microflow-Enhanced Bubble Dynamics Along with Gradient Porous Surfaces

Boiling heat transfer has been a popular topic for decades because of its ability to remove a significant amount of thermal energy while maintaining a low wall superheat during the liquid phase change. Such boiling mechanisms can be tailored by engineering new boiling substrates through surface wettability modification and/or microscale feature installation. Here, we create new types of heterogeneous boiling surfaces that integrate vertical gradient micropores on macroscale fins by using a template-free electrodeposition method. The gradient morphology and corresponding gradient wettability simultaneously enable bubble nucleation on the top pores and capillary wicking through the bottom pores. With these unique wetting characteristics, we find that the gradient pores installed at the trench bottom demonstrate the most significant boiling enhancement in critical heat flux and heat transfer coefficients by 160% and 600%, respectively. This enhancement can be attributed to the microflow-enhanced nature of bubble departures around the fins while isolating bubble nucleation and liquid supply through gradient pores. These results provide fundamental insights into boiling mechanisms using porous media and the potential for future works that can optimize the design of multi-dimensional heterogeneous surfaces to engineer flow patterns and boiling mechanisms accordingly.