scholarly journals Comparison of ground-based FTIR and Brewer O<sub>3</sub> total column with data from two different IASI algorithms and from OMI and GOME-2 satellite instruments

2011 ◽  
Vol 4 (3) ◽  
pp. 535-546 ◽  
Author(s):  
C. Viatte ◽  
M. Schneider ◽  
A. Redondas ◽  
F. Hase ◽  
M. Eremenko ◽  
...  

Abstract. An intercomparison of ozone total column measurements derived from various platforms is presented in this work. Satellite data from Infrared Atmospheric Sounding Interferometer (IASI), Ozone Monitoring Instrument (OMI) and Global Ozone Monitoring Experiment (GOME-2) are compared with data from two ground-based spectrometers (Fourier Transform Infrared spectrometer FTIR and Brewer), located at the Network for Detection of Atmospheric Composition Change (NDACC) super-site of Izaña (Tenerife), measured during a campaign from March to June 2009. These ground-based observing systems have already been demonstrated to perform consistent, precise and accurate ozone total column measurements. An excellent agreement between ground-based and OMI/GOME-2 data is observed. Results from two different algorithms for deriving IASI ozone total column are also compared: the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT/ESA) operational algorithm and the LISA (Laboratoire Inter-universitaire des Systèmes Atmosphériques) algorithm. A better agreement was found with LISA's analytical approach based on an altitude-dependent Tikhonov-Philips regularization: correlations are 0.94 and 0.89 compared to FTIR and Brewer, respectively; while the operational IASI ozone columns (based on neural network analysis) show correlations of 0.90 and 0.85, respectively, compared to the O3 columns obtained from FTIR and Brewer.

2010 ◽  
Vol 3 (6) ◽  
pp. 5833-5865
Author(s):  
C. Viatte ◽  
M. Schneider ◽  
A. Redondas ◽  
F. Hase ◽  
M. Eremenko ◽  
...  

Abstract. An intercomparison of ozone total column measurements derived from various platforms is presented in this work. Satellite data from Infrared Atmospheric Sounding Interferometer (IASI), Ozone Monitoring Instrument (OMI) and Global Ozone Monitoring Experiment (GOME-2) are compared with data from two ground-based spectrometers (Fourier Transform Infrared spectrometer FTIR and Brewer), located at the Network for Detection of Atmospheric Composition Change (NDACC) super-site of Izaña (Tenerife), measured during a campaign from March to June 2009. These ground-based observing systems have already been demonstrated to perform consistent, precise and accurate ozone total column measurements. An excellent agreement between ground-based and OMI/GOME-2 data is observed. Results from two different algorithms for deriving IASI ozone total column are also compared: the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT/ESA) operational algorithm and the LISA (Laboratoire Interuniversitaire des Systèmes Atmosphériques) algorithm. A better agreement was found with LISA's analytical approach based on an altitude-dependent Tikhonov-Philips regularization: correlations are 0.94 and 0.89 compared to FTIR and Brewer, respectively; while the operational IASI ozone columns (based on neural network analysis) show correlations of 0.90 and 0.85, respectively, compared to the O3 columns obtained from FTIR and Brewer.


2016 ◽  
Vol 9 (9) ◽  
pp. 4471-4485 ◽  
Author(s):  
Cristina Robles-Gonzalez ◽  
Mónica Navarro-Comas ◽  
Olga Puentedura ◽  
Matthias Schneider ◽  
Frank Hase ◽  
...  

Abstract. A 13-year analysis (2000–2012) of the NO2 vertical column densities derived from ground-based (GB) instruments and satellites has been carried out over the Izaña NDACC (Network for the Detection of the Atmospheric Composition Change) subtropical site. Ground-based DOAS (differential optical absorption spectroscopy) and FTIR (Fourier transform infrared spectroscopy) instruments are intercompared to test mutual consistency and then used for validation of stratospheric NO2 from OMI (Ozone Monitoring Instrument) and SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY). The intercomparison has been carried out taking into account the various differences existing in instruments, namely temporal coincidence, collocation, sensitivity, field of view, etc. The paper highlights the importance of considering an “effective solar zenith angle” instead of the actual one when comparing direct-sun instruments with zenith sky ones for a proper photochemical correction. Results show that NO2 vertical column densities mean relative difference between FTIR and DOAS instruments is 2.8 ± 10.7 % for a.m. data. Both instruments properly reproduce the NO2 seasonal and the interannual variation. Mean relative difference of the stratospheric NO2 derived from OMI and DOAS is −0.2 ± 8.7 % and from OMI and FTIR is −1.6 ± 6.7 %. SCIAMACHY mean relative difference is of 3.7 ± 11.7 and −5.7 ± 11.0 % for DOAS and FTIR, respectively. Note that the days used for the intercomparison are not the same for all the pairs of instruments since it depends on the availability of data. The discrepancies are found to be seasonally dependent with largest differences in winter and excellent agreement in the spring months (AMJ). A preliminary analysis of NO2 trends has been carried out with the available data series. Results show increases in stratospheric NO2 columns in all instruments but larger values in those that are GB than that expected by nitrous oxide oxidation. The possible reasons for the discrepancy between instruments and the positive trends are discussed in the text.


2019 ◽  
Vol 19 (6) ◽  
pp. 3939-3962 ◽  
Author(s):  
Antje Inness ◽  
Johannes Flemming ◽  
Klaus-Peter Heue ◽  
Christophe Lerot ◽  
Diego Loyola ◽  
...  

Abstract. The TROPOspheric Monitoring Instrument (TROPOMI) on board the Sentinel-5 Precursor (S5P) satellite launched in October 2017 yields a wealth of atmospheric composition data, including retrievals of total column ozone (TCO3) that are provided in near-real-time (NRT) and off-line. The NRT TCO3 retrievals (v1.0.0–v1.1.2) have been included in the data assimilation system of the Copernicus Atmosphere Monitoring Service (CAMS), and tests to monitor the data and to carry out first assimilation experiments with them have been performed for the period 26 November 2017 to 30 November 2018. The TROPOMI TCO3 data agree to within 2 % with the CAMS analysis over large parts of the globe between 60∘ N and 60∘ S and also with TCO3 retrievals from the Ozone Monitoring Instrument (OMI) and the Global Ozone Monitoring Experiment-2 (GOME-2) that are routinely assimilated by CAMS. However, the TCO3 NRT data from TROPOMI show some retrieval anomalies at high latitudes, at low solar elevations and over snow/ice (e.g. Antarctica and snow-covered land areas in the Northern Hemisphere), where the differences with the CAMS analysis and the other data sets are larger. These differences are particularly pronounced over land in the NH during winter and spring (when they can reach up to 40 DU) and come mainly from the surface albedo climatology that is used in the NRT TROPOMI TCO3 retrieval. This climatology has a coarser horizontal resolution than the TROPOMI TCO3 data, which leads to problems in areas where there are large changes in reflectivity from pixel to pixel, e.g. pixels covered by snow/ice or not. The differences between TROPOMI and the CAMS analysis also show some dependency on scan position. The assimilation of TROPOMI TCO3 has been tested in the CAMS system for data between 60∘ N and 60∘ S and for solar elevations greater than 10∘ and is found to have a small positive impact on the ozone analysis compared to Brewer TCO3 data and an improved fit to ozone sondes in the tropical troposphere and to IAGOS aircraft profiles at West African airports. The impact of the TROPOMI data is relatively small because the CAMS analysis is already well constrained by several other ozone retrievals that are routinely assimilated. When averaged over the periods February–April and September–October 2018, differences between experiments with and without assimilation of TROPOMI data are less than 2 % for TCO3 and less than 3 % in the vertical for seasonal mean zonal mean O3 mixing ratios, with the largest relative differences found in the troposphere.


2016 ◽  
Author(s):  
Cristina Robles-Gonzalez ◽  
Mónica Navarro-Comas ◽  
Olga Puentedura ◽  
Matthias Schneider ◽  
Frank Hase ◽  
...  

Abstract. A 13-years analysis (2000–2012) of the NO2 vertical column densities (VCD) derived from ground-based (GB) instruments and satellites has been carried out over the Izaña NDACC (Network for the Detection of the Atmospheric Composition Change) subtropical site. Ground-based DOAS (Differential Optical Absorption Spectroscopy) and FTIR (Fourier Transform InfraRed spectroscopy) instruments are intercompared to test mutual consistency and then use for validation of stratospheric NO2 from OMI (Ozone Monitoring Instrument) and SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY). The intercomparison has been carried out taking into account the various differences existing in instruments, namely temporal coincidence, collocation, sensitivity, field of view, etc. The paper highlights the importance of considering an "effective solar zenith angle" instead of the actual one when comparing direct sun instruments with zenith sky ones for a proper photochemical correction. Results show that NO2 vertical column densities mean relative difference between FTIR and DOAS instruments is 2.8 ± 10.7 % for AM data. Both instruments properly reproduce the NO2 seasonal and the interannual variation. Mean relative difference of the stratospheric NO2 derived from OMI and DOAS is −0.2 ± 8.7 % and from OMI and FTIR is −1.6 ± 6.7. SCIAMACHY mean relative difference is of 3.7 ± 11.7 % and −5.7 ± 11.0 % for DOAS and FTIR, respectively. Note that the days used for the intercomparison are not the same for all the pairs of instruments since it depends on the availability of data. The discrepancies are found to be seasonally dependent with largest differences in winter and excellent agreement in the spring months (AMJ). A preliminary analysis of NO2 trends has been carried out with the available data series. Results show positive values in all instruments but larger values on the ground-based than that expected by nitrous oxide oxidation. The possible reasons of the discrepancy between instruments and the positive trends are discussed in the text.


2017 ◽  
Vol 10 (10) ◽  
pp. 3677-3695 ◽  
Author(s):  
Kang Sun ◽  
Xiong Liu ◽  
Guanyu Huang ◽  
Gonzalo González Abad ◽  
Zhaonan Cai ◽  
...  

Abstract. The Ozone Monitoring Instrument (OMI) has been successfully measuring the Earth's atmospheric composition since 2004, but the on-orbit behavior of its slit functions has not been thoroughly characterized. Preflight measurements of slit functions have been used as a static input in many OMI retrieval algorithms. This study derives on-orbit slit functions from the OMI irradiance spectra assuming various function forms, including standard and super-Gaussian functions and a stretch to the preflight slit functions. The on-orbit slit functions in the UV bands show U-shaped cross-track dependences that cannot be fully represented by the preflight ones. The full widths at half maximum (FWHM) of the stretched preflight slit functions for detector pixels at large viewing angles are up to 30 % larger than the nadir pixels for the UV1 band, 5 % larger for the UV2 band, and practically flat in the VIS band. Nonetheless, the on-orbit changes of OMI slit functions are found to be insignificant over time after accounting for the solar activity, despite of the decaying of detectors and the occurrence of OMI row anomaly. Applying the derived on-orbit slit functions to ozone-profile retrieval shows substantial improvements over the preflight slit functions based on comparisons with ozonesonde validations.


2014 ◽  
Vol 7 (10) ◽  
pp. 3337-3354 ◽  
Author(s):  
M. Pastel ◽  
J.-P. Pommereau ◽  
F. Goutail ◽  
A. Richter ◽  
A. Pazmiño ◽  
...  

Abstract. Long time series of ozone and NO2 total column measurements in the southern tropics are available from two ground-based SAOZ (Système d'Analyse par Observation Zénithale) UV-visible spectrometers operated within the Network for the Detection of Atmospheric Composition Change (NDACC) in Bauru (22° S, 49° W) in S-E Brazil since 1995 and Reunion Island (21° S, 55° E) in the S-W Indian Ocean since 1993. Although the stations are located at the same latitude, significant differences are observed in the columns of both species, attributed to differences in tropospheric content and equivalent latitude in the lower stratosphere. These data are used to identify which satellites operating during the same period, are capturing the same features and are thus best suited for building reliable merged time series for trend studies. For ozone, the satellites series best matching SAOZ observations are EP-TOMS (1995–2004) and OMI-TOMS (2005–2011), whereas for NO2, best results are obtained by combining GOME version GDP5 (1996–2003) and SCIAMACHY – IUP (2003–2011), displaying lower noise and seasonality in reference to SAOZ. Both merged data sets are fully consistent with the larger columns of the two species above South America and the seasonality of the differences between the two stations, reported by SAOZ, providing reliable time series for further trend analyses and identification of sources of interannual variability in the future analysis.


2016 ◽  
Vol 9 (2) ◽  
pp. 577-585 ◽  
Author(s):  
Matthias Buschmann ◽  
Nicholas M. Deutscher ◽  
Vanessa Sherlock ◽  
Mathias Palm ◽  
Thorsten Warneke ◽  
...  

Abstract. High-resolution solar absorption spectra, taken within the Network for the Detection of Atmospheric Composition Change Infrared Working Group (NDACC-IRWG) in the mid-infrared spectral region, are used to infer partial or total column abundances of many gases. In this paper we present the retrieval of a column-averaged mole fraction of carbon dioxide from NDACC-IRWG spectra taken with a Fourier transform infrared (FTIR) spectrometer at the site in Ny-Ålesund, Spitsbergen. The retrieved time series is compared to colocated standard TCCON (Total Carbon Column Observing Network) measurements of column-averaged dry-air mole fractions of CO2 (denoted by xCO2). Comparing the NDACC and TCCON retrievals, we find that the sensitivity of the NDACC retrieval is lower in the troposphere (by a factor of 2) and higher in the stratosphere, compared to TCCON. Thus, the NDACC retrieval is less sensitive to tropospheric changes (e.g., the seasonal cycle) in the column average.


2010 ◽  
Vol 10 (23) ◽  
pp. 11501-11517 ◽  
Author(s):  
G. Curci ◽  
P. I. Palmer ◽  
T. P. Kurosu ◽  
K. Chance ◽  
G. Visconti

Abstract. Emission of non-methane Volatile Organic Compounds (VOCs) to the atmosphere stems from biogenic and human activities, and their estimation is difficult because of the many and not fully understood processes involved. In order to narrow down the uncertainty related to VOC emissions, which negatively reflects on our ability to simulate the atmospheric composition, we exploit satellite observations of formaldehyde (HCHO), an ubiquitous oxidation product of most VOCs, focusing on Europe. HCHO column observations from the Ozone Monitoring Instrument (OMI) reveal a marked seasonal cycle with a summer maximum and winter minimum. In summer, the oxidation of methane and other long-lived VOCs supply a slowly varying background HCHO column, while HCHO variability is dominated by most reactive VOC, primarily biogenic isoprene followed in importance by biogenic terpenes and anthropogenic VOCs. The chemistry-transport model CHIMERE qualitatively reproduces the temporal and spatial features of the observed HCHO column, but display regional biases which are attributed mainly to incorrect biogenic VOC emissions, calculated with the Model of Emissions of Gases and Aerosol from Nature (MEGAN) algorithm. These "bottom-up" or a-priori emissions are corrected through a Bayesian inversion of the OMI HCHO observations. Resulting "top-down" or a-posteriori isoprene emissions are lower than "bottom-up" by 40% over the Balkans and by 20% over Southern Germany, and higher by 20% over Iberian Peninsula, Greece and Italy. We conclude that OMI satellite observations of HCHO can provide a quantitative "top-down" constraint on the European "bottom-up" VOC inventories.


Author(s):  
R. McPeters ◽  
M. Kroon ◽  
G. Labow ◽  
E. Brinksma ◽  
D. Balis ◽  
...  

2020 ◽  
Author(s):  
Ka Lok Chan ◽  
Pieter Valks ◽  
Sander Slijkhuis ◽  
Claas Köhler ◽  
Diego Loyola

Abstract. We present a new total column water vapor (TCWV) retrieval algorithm in the visible blue spectral band for the Global Ozone Monitoring Experience 2 (GOME-2) instruments on board the EUMETSAT MetOp satellites. The blue band algorithm allows retrieval of water vapor from sensors which do not cover longer wavelengths, such as Ozone Monitoring Instrument (OMI) and the Copernicus atmospheric composition missions Sentinel-5 Precursor (S5P), Sentinel-4 (S4) and Sentinel-5 (S5). The blue band algorithm uses the differential optical absorption spectroscopic (DOAS) technique to retrieve water vapor slant columns. The measured water vapor slant columns are converted to vertical column using air mass factors (AMFs). The new algorithm has an iterative optimization module to dynamically find the optimal a priori water vapor profile. This makes it better suited for climate studies than usual satellite retrievals with static a priori or vertical profile information from chemistry transport model (CTM). The dynamic a priori algorithm makes use of the fact that the vertical distribution of water vapor is strongly correlated to the total column. The new algorithm is applied to GOME-2A and GOME-2B observations to retrieve TCWV. The data set is validated by comparing to the operational product retrieved in the red spectral band, sun-photometer and radiosonde measurements. Water vapor columns retrieved in the blue band are in good agreement with the other data sets, indicating that the new algorithm derives precise results, and can be used for the current and forthcoming Copernicus Sentinel missions S4 and S5.


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