Impacts of mineralogy on micro-scale pore structure and fluid flow capacity of deeply buried sandstone reservoirs

Author(s):  
Juncheng Qiao ◽  
Jianhui Zeng ◽  
Xiao Feng

<p>Hydrocarbon exploration is extending from the shallowly buried to deeply buried strata with increasing demands for fossil fuels. The variable storage and percolation capacities that intrinsically depend on the pore geometry restrict the hydrocarbon recovery and displacement efficiency and trigger studies on the micro-scale pore structure, fluid flow capacity, and their controlling factors. Minerals within sandstone are the results of the coupling control of depositional factors and diagenetic alternations, which determine the microscopic pore geometry and subsequently affect the fluid flow capacity. In order to investigate the impacts of mineralogy on the pore structure and fluid flow capacity, integrated analyses including porosity and permeability measurements, casting thin section (CTS), scanning electron microscopy (SEM), pressure-controlled mercury porosimetry (PCP), rate-controlled mercury porosimetry (RCP), nuclear magnetic resonance (NMR), and X-ray diffraction (XRD) are conducted on the deeply buried sandstone samples in the Jurassic Sangonghe Formation of the Junggar Basin. Microscopic pore structure is characterized by the combination of SEM, CTS, PCP, and RCP and fractal theory. Fluid flow capacity is evaluated by the innovative application of film bound water model in NMR and mineralogy is quantitatively measured by XRD. The results indicate that the deeply buried sandstone is rich in quartz (54.2%), feldspar (25.1%), and clay (14.2%), with dominant kaolinite (5.04%) and chlorite (5.38%) cementation. The reservoir has a wide pore-throat diameter distribution with three peaks in the ranges 0.01–1, 10–80, and 200–1000 μm. Pores are tri-fractal and can be divided into micropores, mesopores, and macropores, with average porosity contributions of 50.11, 21.83, and 28.04%, respectively. The movable porosity of deeply buried sandstone ranges from 1.75 to 8.24%, primarily contributed by intergranular (avg. 2.34%) and intragranular pores (avg. 2.56%). Most of the fluids are movable in intergranular pores but are irreducible in intragranular pores. Correlation analyses between mineralogy and pore structure suggest that quartz provides preservation to intergranular porosity, which increases pore size and macropores porosity and reduces heterogeneity of the pore system. The influence of feldspar reverses and becomes poor owing to the simultaneous clay precipitation and complex roles of feldspar dissolution in microporosity. Chlorite, kaolinite, and illite, all act as destructions to intergranular porosity. They enhance the mesopores and micropores porosities, reduce the pore size, and increase the microscopic heterogeneities of the macropores, micropores, and whole pore system. The relationships between mineralogy and fluid flow capacity indicate that quartz is favorable for the fluid flow capacity, but feldspar and clay play negative roles. The reversed impacts of quartz and feldspar lay in their opposite controls on pore size. However, both pore size and hydrophilia should be taken into account when considering the effects of clay minerals. These negative effects are associated with types, contents, and hydrophilic degrees of clay minerals, in which I/S and illite exhibit the strongest negative impacts. The fluid flow in the intergranular and intragranular pores is generally enhanced by higher quartz content, but reduced by higher clay content. Irreducible fluids in the intergranular and intragranular pores are determined by chlorite and kaolinite contents, respectively.</p>

2016 ◽  
Vol 10 (8) ◽  
pp. 117 ◽  
Author(s):  
Suryo Prakoso ◽  
Pudji Permadi ◽  
Sonny Winardhie

The behavior of compressional or P-wave velocity passing through natural porous rocks with heterogeneous and irregular shapes of the pore system is not well understood. The present study implemented a modified Kozeny equation to characterize pore attributes, pore geometry and structure, in an attempt to investigate factors influencing the velocity. This equation is in the form of a power law one from which a concept of similarity in pore attributes can be derived. Employing a large number of data of porous sandstones, the results show that a similarity in the pore attribute plays an important role in relating the velocity with the details of geometry and structure of the pores system. For a given group of rocks having similar pore structure, an increase in the pore geometry variable, (k/f)0.5, tends to increase the velocity provided that the increase in the geometry is due to an increase in permeability followed by a decrease in porosity. Overall, the prediction of P-wave velocity is best obtained when the rocks are grouped according to pore structure similarity.


1988 ◽  
Vol 137 ◽  
Author(s):  
Yahia Abdel-Jawad ◽  
Will Hansen

AbstractThe pore structure (i.e. total pore volume, surface area and pore-size distribution curves) was measured using mercury porosimetry and nitrogen sorption. Hydrated portland cement (type I) of water-cement (w/c) ratios 0.3, 0.4 and 0.6 by weight was analyzed at three degrees of hydration (i.e., 30%, 50% and 80%; 70% for the 0.3 w/c system) corresponding to low, intermediate and high levels of hydration. The effect of curing temperature (3°, 23°, and 43°C) on pore structure was also studied. The two techniques were evaluated as well on porous Vycor glass, which has a narrow pore size distribution in the size range accessible to both. Results obtained by both techniques on porous Vycor glass agreed well. However neither technique can be used alone to study the entire pore structure in well-hydrated cement due to the wide range in pore sizes and the presence of micropores. Due to the unstable pore structure in cement a specimen treatment procedure such as methanol replacement, combined with volume-thickness (V-t) analysis, is necessary in order to measure the micropores. At low hydration values the pore structure can be estimated by mercury intrusion porosimetry (MIP). At higher hydration values, however, this technique underestimates total pore volume and surface area due to the presence of micropores which MIP cannot determine. In the pore size range of overlap, higher pore volumes were obtained with MIP. Nitrogen V-t analysis shows that micropores are more pronounced with lower w/c ratios. This finding is consistent with pore size distribution curves obtained by MIP. For a given w/c ratio and degree of hydration the total pore volume measured by MIP was found to be independent of curing temperature in the temperature range studied. At any w/c ratio, capillary porosity is controlled by degree of hydration alone.


Author(s):  
Yubin Bai ◽  
Jingzhou Zhao ◽  
Delin Zhao ◽  
Hai Zhang ◽  
Yong Fu

AbstractThis study applied vacuum-impregnated casting thin sections, fluorescence slices, scanning electron microscopy (SEM), pressure-controlled mercury porosimetry (PCP), rate-controlled mercury porosimetry (RCP), X-ray diffraction of clay minerals, overburden pressure, and conventional physical property strategies to determine the microscopic characteristics of the Chang 6 member, a typical tight sandstone reservoir in the Jingbian oilfield in the Ordos Basin, China. We also analyzed the controlling effects of pore structure on reservoir quality and oiliness. The results showed that the pore types of the Chang 6 sandstone reservoir can be divided into four categories: residual intergranular pores, dissolution pores, intercrystalline pores between clay minerals, and microfractures. The pore size of the Chang 6 sandstone reservoir ranged from 20 to 50 μm. We employed PCP and RCP strategies to characterize the pore structure of the Chang 6 reservoir. The pore radius was less than 2 μm, and on average, the throat radius was less than 0.3 μm. The reservoir physical properties were affected by diagenesis, particularly compaction, and the average porosity failure rate was 56.3%. Cementation made the reservoir more compact, dissolution improved the physical properties of the reservoir locally, and fracturing effectively improved the reservoir seepage ability; however, its influence on porosity was limited. The pore structure controlled the quality of the reservoir. The physical properties of the reservoir were closely related to the oil-bearing properties. The lower limits of porosity and permeability of industrial oil flow in the reservoir were 7.5% and 0.15 mD, respectively. These results provide an additional resource for the exploration and development of tight oil in the Ordos Basin.


1972 ◽  
Vol 12 (04) ◽  
pp. 289-296 ◽  
Author(s):  
F.A.L. Dullien ◽  
G.K. Dhawan ◽  
Nur Gurak ◽  
L. Babjak

Abstract Photomicrography and mercury porosimetry have been used jointly to determine the pore-size distributions of various sandstone samples. The two curves differed drastically from each other for all samples. Two unconsolidated packs consisting of uniform 250u glass beads and mixed 44-250u beads, respectively, as well as the sinters prepared from them, were also investigated. An index, D, measuring the difficulty of recovering waterflood residuals in tertiary surfactant floods has been constructed from the two different porosimetry curves. Reasonably good correlation porosimetry curves. Reasonably good correlation bas been obtained between D and residual oil saturations found in tertiary surfactant floods. Introduction This paper presents our first results in a continuing study of pore structure and oil recovery. The problem of how pore structure might influence oil recovery has been discussed by several authors. There is, however, no known method whereby one could rank various porous media (e.g., different sandstones) on the basis of pore structure in the order of decreasing amounts of expected residual oil saturations assuming identical conditions of flooding (identical oil, water, wetting and pressure gradient for the various sands. In this pressure gradient for the various sands. In this work we have taken an initial step toward this ideal objective. The prime target of the treatment has been the problem of correlating the extent of recovery of waterflood residuals by tertiary surfactant floods with the pore structure. The degree of difficulty presented by the pore structure in the way of recovering the isolated oil masses left behind by a waterflood has been expressed in the form of an index that is calculated from a mercury porosimetry and a photomicrographic pore-size distribution curve obtained on the sample. pore-size distribution curve obtained on the sample. The degree of correlation obtained amounts to a promising start in the case of tertiary surfactant promising start in the case of tertiary surfactant floods, and there also appears to be some correlation between the residual oil saturations found in the waterfloods and the pore structure. In this paper we are considering only the case of water-wet formations and moderate viscosity ratios. THEORY The term "pore structure" ordinarily means the distribution of pore volume by some linear pore dimension (pore-size distribution) and the topographical sequence of pores. Pore-size distributions have been determined by various methods. However, for reservoir rocks the most popular method has been mercury porosimetry. In a typical reservoir rock pore necks alternate with bulges. As the meniscus of penetrating mercury advances past a pore neck, it continues to advance in a nonequilibrium manner, until it comes to an even narrower neck. Since the capillary pressure of penetration of mercury into the pore pressure of penetration of mercury into the pore space between the two necks is determined by the size of the first neck, the pore diameters corresponding to the space between the two necks remain undetected by this method. Let us consider an arbitrary pore segment in the sample and approach it from the outside surface of the sample. Somewhere between the pore segment and the outside, there is a controlling cross-section in the pore space that is defined as follows: once the meniscus of the invading mercury has passed that cross-section, there is no narrower neck in its path all the way to the segment considered. The path all the way to the segment considered. The pore neck is the segment considered the controlling pore neck is the segment considered the controlling cross-section as defined above, even if the pore neck is far removed from the controlling crosssection. Denoting the radius of the pore segment by re and that of the controlling pore neck by r'e we have re greater than r'e. JPT P. 289


2014 ◽  
Vol 17 (03) ◽  
pp. 414-424 ◽  
Author(s):  
H.. Singh ◽  
F.. Javadpour ◽  
A.. Ettehadtavakkol ◽  
H.. Darabi

Summary Physics of fluid flow in shale reservoirs cannot be predicted from standard flow or mass-transfer models because of the presence of nanopores, ranging in size from one to hundreds of nanometers, in shales. Conventional continuum-flow equations, such as Darcy's law, greatly underestimate the fluid-flow rate when applied to nanopore-bearing shale reservoirs. As a result of the existence of nanopores in shales, the molecular mean free path becomes comparable with the characteristic geometric scale, and we hypothesize that under this condition, Knudsen diffusion, in addition to correction for the slip boundary condition, becomes the dominant mechanism. Recently, a few models have been developed that use various empirical parameters to account for these modifications (Javadpour 2009; Civan 2010; Darabi et al. 2012). This paper aims to provide a different approach to modeling apparent permeability in shale reservoirs. The proposed model is analytical, free of any empirical coefficients, and has been derived without invoking the assumption of slip flow at the pore wall. Our model of apparent permeability represented by a single analytical equation, depends only on pore size, pore geometry, temperature, gas properties, and average reservoir pressure. The proposed model is valid for Knudsen numbers less than unity and it stands up under the complete operating conditions of a shale reservoir. Our model reasonably predicts results as reported by other models. Finally, the model shows that pore-surface roughness and mineralogy have a negligible influence on gas-flow rate, whereas pore geometry and pore size play a significant role in the proportion of diffusion in total flow rate. Our study shows that a combination of Darcy flow and Knudsen flow—ignoring the Klinkenberg effect—can describe gas flow for a range of Knudsen flow applicable to a shale-gas system.


2021 ◽  
Vol 11 (5) ◽  
pp. 2113-2125
Author(s):  
Chenzhi Huang ◽  
Xingde Zhang ◽  
Shuang Liu ◽  
Nianyin Li ◽  
Jia Kang ◽  
...  

AbstractThe development and stimulation of oil and gas fields are inseparable from the experimental analysis of reservoir rocks. Large number of experiments, poor reservoir properties and thin reservoir thickness will lead to insufficient number of cores, which restricts the experimental evaluation effect of cores. Digital rock physics (DRP) can solve these problems well. This paper presents a rapid, simple, and practical method to establish the pore structure and lithology of DRP based on laboratory experiments. First, a core is scanned by computed tomography (CT) scanning technology, and filtering back-projection reconstruction method is used to test the core visualization. Subsequently, three-dimensional median filtering technology is used to eliminate noise signals after scanning, and the maximum interclass variance method is used to segment the rock skeleton and pore. Based on X-ray diffraction technology, the distribution of minerals in the rock core is studied by combining the processed CT scan data. The core pore size distribution is analyzed by the mercury intrusion method, and the core pore size distribution with spatial correlation is constructed by the kriging interpolation method. Based on the analysis of the core particle-size distribution by the screening method, the shape of the rock particle is assumed to be a more practical irregular polyhedron; considering this shape and the mineral distribution, the DRP pore structure and lithology are finally established. The DRP porosity calculated by MATLAB software is 32.4%, and the core porosity measured in a nuclear magnetic resonance experiment is 29.9%; thus, the accuracy of the model is validated. Further, the method of simulating the process of physical and chemical changes by using the digital core is proposed for further study.


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