Nitrate deposition and preservation in the snowpack along a traverse
from coast to the ice sheet summit (Dome A) in East Antarctica
Abstract. The Antarctic ice core nitrate (NO3−) can provide a unique record of the atmospheric reactive nitrogen cycle. However, the factors influencing the deposition and preservation of NO3− at the ice sheet surface must first be understood. Therefore, an intensive program of snow sample collections was made on a traverse from the coast to the ice sheet summit, Dome A, East Antarctica. Snow samples in this observation include 120 surface snow samples (top ~ 3 cm), 20 snowpits with depths of 150 to 300 cm, and 6 crystal ice samples (the topmost needle like layer on Dome A plateau), and NO3− concentrations in these samples were determined. The main purpose of this investigation is to characterize the distribution pattern and preservation of NO3− in the snow in different environments. Results show that an increasing trend of NO3− concentrations with distance inland is present in surface snow, and NO3− is extremely enriched in the crystal ice (with a maximum of 16.1 μeq L−1). NO3− concentration profiles for snowpits vary between coastal and inland sites. On the coast, the deposited NO3− was largely preserved, and the archived NO3− fluxes are dominated by snow accumulation. The relationship between the archived NO3− and snow accumulation rate can be well depicted by a linear model, suggesting a homogeneity of atmospheric NO3− levels. It is estimated that dry deposition contributes 27−44 % of the archived NO3− fluxes, and the dry deposition velocity and scavenging ratio for NO3− was relatively constant near the coast. Compared to the coast, the inland snow shows a relatively weak association between archived NO3− and snow accumulation, and the archived NO3− fluxes were more concentration dependent. The association between NO3− and the coexisting ions (nssSO42−, Na+ and Cl−) was assessed, and nssSO42− (the fine aerosol particles) could potentially influence NO3− concentrations, while the correlation between NO3− and Na+ (mainly associated with coarse aerosol particles) is not significant. In inland snow, there were no significant relationships found between NO3− and the coexisting ions, suggesting a dominant role of NO3− recycling in the concentration.