scholarly journals Photoresponse characteristics from vacuum deposited thin film of copper phthalocyanine: dependence on grain size

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Arka Mandal ◽  
◽  
Biswanath Mukherjee

An organic photodetector (PD) is fabricated with single layer thin film of copper phthalocyanine (CuPc) on glass substrate. The thermal deposition of CuPc film on the substrate was realized under high vacuum and at different substrate temperature (room temperature, 40 ◦C, 70 ◦C, 100 ◦C). The comparison of photoresponse characteristics of CuPc thin film deposited under different conditions showed good improvement with increase in the substrate temperature, and the best performances being observed for the film deposited at substrate temperature of 100 ◦C. The thin film of CuPc characterized through X-ray diffraction (XRD) spectroscopy and atomic force microscopy (AFM) clearly indicated that with increase in substrate temperature, the grain size of CuPc film increased, which improved the crystallinity and hence the photoconductivity of the device. The CuPc thin film based PD displayed stable and reproducible photoswitching characteristics under white light irradiation, with photocurrent modulation by varying in input optical power. The highest photo to dark current ratio and responsitivity of the devices was calculated to be, ca. 6.5 and 7.1 mA-W−1 at low optical power, ca. 14.5 mW-cm−2.

2008 ◽  
Vol 93 (8) ◽  
pp. 083308 ◽  
Author(s):  
K. Celebi ◽  
P. J. Jadhav ◽  
K. M. Milaninia ◽  
M. Bora ◽  
M. A. Baldo

2020 ◽  
Author(s):  
Zhonglin Ji ◽  
Franklin L. Duan ◽  
Haotian Weng ◽  
Ziyi Xie ◽  
Baowen Zhang ◽  
...  

2011 ◽  
Vol 347-353 ◽  
pp. 3481-3484
Author(s):  
Xue Hua Li ◽  
Dong Sheng Wang ◽  
Jian Zhou Du

Based on the single-layer thin film theory, we calculated transmittance of ITO thin film. The reflectivity arrive a maximum or a minimum according to whether the refractive index of film is greater or smaller than the refractive index of the glass substrate. we obtain the same maximum of transparence which is above 95% and the minimum value which decrease to 76.5% with the increase of refractive index.


2019 ◽  
Vol 10 ◽  
pp. 1-5 ◽  
Author(s):  
Hiroaki Kikuchi ◽  
Taisei Umezaki ◽  
Takuya Shima ◽  
Chihiro Sumida ◽  
Suguru Oe

Author(s):  
Tae Hwan Jang ◽  
Tae Gyu Kim ◽  
Mun Ki Bae ◽  
Kyuseok Kim ◽  
Jaegu Choi

In this study, we developed a nanoscale emitter having a multi-layer thin-film nanostructure in an effort to maximize the field-emission effect with a low voltage difference. The emitter was a sapphire board on which tungsten–DLC multi-player thin film was deposited using PVD and CVD processes. This multi-layer thin-film emitter was examined in a high-vacuum X-ray tube system. Its field-emission efficiency according to the applied voltage was then analyzed.


2018 ◽  
Vol 1082 ◽  
pp. 012024
Author(s):  
Fasih Ud Din ◽  
Abdul Halim Shaari ◽  
Chen Soo Kien ◽  
Zainal Abidin Talib ◽  
Amad Ud Din ◽  
...  

Author(s):  
Mi-Ra Kim ◽  
Won Suk Shin ◽  
Sung-Ho Jin ◽  
Kastuhiko Fujida ◽  
Testuo Tsutsui ◽  
...  

Organic solar cells made from bi-layer thin-film heterojunctions having poly((2-methoxy-5-(2′-ethylhexyloxy)-p-phenylene)vinylene) (MEH-PPV) as an electron donor and fulleropyrrolidine derivatives as an electron acceptor were investigated. We synthesized soluble fulleropyrrolidine derivatives substituted different chain lengths for the organic solar cell. Due to the high solubility and sufficiently long chain length of fulleropyrrolidine derivatives, though those are monomers, a thin film (about 50 nm) could be fabricated individually by the spin-coating method. The fill factor of the bi-layer device was achieved to be 0.40, which is higher than that of the single-layer device by a polymer/fulleropyrrolidine derivative blend film of 0.29, due to the decrease of the recombination.


2011 ◽  
Vol 403-408 ◽  
pp. 5097-5101 ◽  
Author(s):  
Theerasak Juagwon ◽  
Tanakorn Osotchan

Microstructure of heterojunction usually has strong influence on its electrical characteristic. In order to study the effect of microstructure, the layers of copper phthalocyanine (CuPc) and tetracyanoquinodimethane (TCNQ) are deposited on indium tin oxide (ITO) coated glass substrate by thermal evaporation method. The modification of microstructure in the organic semiconductor layer with varied underneath layer is studied in the heterojunction between CuPc and TCNQ. Then the effect on its electrical characteristic is examined between ITO and aluminum (Al) electrodes in these alternative structures. By determining the microstructure by atomic force microscope (AFM), the CuPc and TCNQ thin films provide very tiny and large grain, respectively. These large grains in TCNQ thin film connect into line pattern probably due to the slow grain growth. Therefore the CuPc film is deposited on this TCNQ layer, the larger gain size of CuPc film can be achieved. However, the TCNQ layer grown on top of tiny grain of CuPc exhibits relatively small grain size. The variation of X-ray diffraction (XRD) peaks of these alternative structures support the microstructure extracted from AFM image very well. The optical absorption of these various structures exhibits the combination of absorption peaks from each layer. The electrical characteristics of these structures strongly depend on junction between ITO electrode and organic layer. The heterojunction structures of ITO/CuPc/Al and ITO/CuPc/TCNQ/Al show rectifier characteristics while the structures of ITO/TCNQ/Al and ITO/TCNQ/CuPc/Al exhibit similar IV characteristic for both polarities. However the effect of larger grain size in TCNQ layer leads to very much higher current than those other structures. By measuring current down to temperature of 50 K, it is found that the structures with rectifier junction indicate the current decreasing more than five orders of magnitude while the junctions with no rectifier characteristic exhibit only slightly current change even the measured temperature is reduced to very low temperature.


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