scholarly journals Determination of Polycyclic Aromatic Hydrocarbons in Cigarettes and Cigarette Smoke

2016 ◽  
Vol 5 (2) ◽  
pp. 15 ◽  
Author(s):  
Haruki Shimazu

<p>The present study examines the concentrations of polycyclic aromatic hydrocarbons (PAHs) in cigarettes and sidestream cigarette smoke. Nine PAHs were determined in sidestream cigarette smokes for five types of cigarettes. The volume of the experimental room is approximately 66 m<sup>3</sup>. The air samples in the room were collected before and after smoking. The total PAH concentrations were approximately 1.0 ng/m<sup>3</sup> before smoking, but the median concentration and the range of PAHs were 29.1 ng/m<sup>3</sup> and from 7.62 to 57.6 ng/m<sup>3</sup> after smoking. The relationship between suspended particulate matter (SPM) and total PAHs after smoking is significant and proportional. This may indicate that the SPM formation is associated with PAH formation during smoking. Furthermore, nine PAHs were determined in the cigarettes. Median PAH contents in the five brands of cigarettes ranged from 221 to 936 ng per cigarette before smoking and from 66.9 to 266 ng per cigarette after smoking. Mean PAH emissions from cigarettes while smoking ranged from 257 to 1490 ng per cigarette. The results show that PAHs in the cigarettes, and those generated during smoking, were emitted into the air.</p>

2013 ◽  
Vol 291-294 ◽  
pp. 837-842
Author(s):  
Li Ping Zhang ◽  
Qing Hai Deng ◽  
Nan Jiang ◽  
Jia Yuan Cao

The study of relationship between PAHs(Polycyclic Aromatic Hydrocarbons) and macerals contributes to understand the occurrence and distribution of PAHs in coal. Ten coal samples were collected and then tested macerals and 15 PAHs quantitatively. The concentration of total PAHs, single PAH and every-ring of PAHs tend to increase with and reduce with the increasing inertinite, vitrinite and liptinite contents. The higher the PAHs ring number is, the more obvious the effect of macerals exert on them. Higher H/C, O/C atomic ratios and higher aromaticity in inertinite groups are the main reasons for the positive relationship between inertinite and PAHs. Degree of coalification had a significant effect on the relationship between PAHs and maceral groups in coal.


Author(s):  
A Rodgman ◽  
TA Perfetti

AbstractClassified as toxicants in many of the substances to which humans are exposed are the polycyclic aromatic hydrocarbons (PAHs). Such exposures include air pollutants from a variety of sources, foodstuffs and beverages, and tobacco smoke. Since the early 1950s, the composition of the latter has been more completely defined than that of any other consumer product. Nearly 4800 components have been identified in tobacco smoke and among these are over 500 PAHs either completely or partially identified. Because of the tumorigenicity of many PAHs, much research has been conducted in attempts to define the relationship between the PAH structures and their specific tumorigenicities in laboratory animals. None of the theories to date completely answers all the questions.As a prelude to an attempt to develop a more reasonable PAH structure-tumorigenicity relationship, the PAHs completely or partially identified in cigarette smoke have been catalogued. In the catalogue, they are categorized as bicyclic, tricyclic, tetracyclic, etc. with each group subdivided into all-benzenoid PAHs and cyclopentanoid-benzenoid PAHs. Another tabulation includes the PAHs considered in several previous studies on structure-tumorigenicity relationships, studies that dealt primarily with all-benzenoid PAHs.


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