CORRECTION OF THE CHEMICAL COMPOSITION OF THE WASHING WATERS RECEIVED AS A RESULT OF H CATION EXCHANGE OF ION- EXCHANGE RESIN

Author(s):  
Irina Bejanidze
2014 ◽  
Vol 955-959 ◽  
pp. 2230-2233 ◽  
Author(s):  
Yong Gang Zeng ◽  
Long Li

This paper used the ion exchange resin method to treat the heavy metal ion Cu2+ of a chemical wastewater and studied the flow velocity, pH and the temperature’s effect on Cu2+ removal effect by macroporous strongly acidic styrene type cation exchange resin D001. The results shown that: when the flow velocity was 1.5 mL/min, pH was 6.0 and the temperature was 30°C, the removal rate of Cu2+ by D001 reached 99.8%. The chemical wastewater could achieve the wastewater’s discharge standard.


Author(s):  
О. S. Baigenzhenov ◽  
◽  
А. М. Toishybek ◽  
А. Т. Khabiyev ◽  
I.O. Aimbetova ◽  
...  

This article presents the technology of niobium recovery by processing of chloride residues generated during the chlorination of titanium slags. For waste processing, a two-stage leaching technology is proposed. Water is used at the first stage of leaching and hydrochloric acid 4.0 M is used at the second stage. For the purpose of sorption of niobium from the solution composition obtained during leaching, cation-exchange sorbents Purolite-C104 and KU-2-8 H were used. By the usage of Purolite-C104 ion exchange resin the sorption efficiency of niobium from a solution with a concentration of 2 g/l was about 71.0 % (0.071 g/g) in 3.5 hours, while for KU-2-8 H ion exchange resin, sorption efficiency was about 89.0 % (0.089 g/g).


2019 ◽  
Vol 20 (14) ◽  
pp. 3579 ◽  
Author(s):  
Lucie Vobecká ◽  
Tomáš Belloň ◽  
Zdeněk Slouka

Electrodialysis and electrodeionization are separation processes whose performance depends on the quality and properties of ion-exchange membranes. One of the features that largely affects these properties is heterogeneity of the membranes both on the macroscopic and microscopic level. Macroscopic heterogeneity is an intrinsic property of heterogeneous ion-exchange membranes. In these membranes, the functional ion-exchange component is dispersed in a non-conductive binder. The functional component is finely ground ion-exchange resin particles. The understanding of the effect of structure on the heterogeneous membrane properties and behavior is thus of utmost importance since it does not only affect the actual performance but also the cost and therefore competitiveness of the aforementioned separation processes. Here we study the electrokinetic behavior of cation-exchange resin particle systems with well-defined geometrical structure. This approach can be understood as a bottom up approach regarding the membrane preparation. We prepare a structured cation-exchange membrane by using its fundamental component, which is the ion exchange resin. We then perform an experimental study with four different experimental systems in which the number of used cation-exchange particles changes from 1 to 4. These systems are studied by means of basic electrochemical characterization measurements, such as measurement of current–voltage curves and direct optical observation of phenomena that occur at the interface between the ion-exchange system and the adjacent electrolyte. Our work aims at better understanding of the relation between the structure and the membrane properties and of how structure affects electrokinetic behavior of these systems.


2012 ◽  
Author(s):  
Mahadevan. M. ◽  
Lay Pee Lin ◽  
Zainal Abidin M. Y. ◽  
Mohamad Roji Sarmidi

Elektrodialisis merupakan suatu proses yang menggunakan perbezaan keupayaan elektrik sebagai daya penggerak yang menyebabkan pergerakan ion-ion dalam sesuatu elektronit. Membran yang digunakan dalam proses ini akan membenarkan sama ada cas-cas positif atau negatif sahaja melaluinya bergantung kepada kumpulan berfungsi yang terikat pada membran. Objektif projek penyelidikan ini adalah untuk menghasilkan membran pertukaran kation yang digunakan dalam proses elektrodialisis. Membran-membran pertukaran kation yang dihasilkan terbahagi kepada lima jenis, dan diberi nama sebagai BERL–30, 40, 50, 60, dan 70. Kelima-lima jenis membran ini berbeza dari segi kandungan resin yang berfungsi sebagai vektor pertukaran cas kation. Di samping penyediaan membran, penyelidikan ini juga meliputi aspek pencirian membran tersebut serta perbandingan dengan membran komersial. Kriteria yang dikaji adalah ketebalan membran, sifat kebolehtelapan membran, kapasiti pertukaran ion, kapasiti kepekatan ion kumpulan berfungsi, morfologi struktur membran, ujian kestabilan kimia dan kandungan air membran. Secara keseluruhannya, didapati peratus kandungan resin yang tinggi boleh meningkatkan kapasiti pertukaran ion, peratus kebolehtelapan membran serta kapasiti kepekatan ion kumpulan berfungsi. Antara membran yang dihasilkan, membran pertukaran kation jenis BERL–70 merupakan membran yang berpotensi dalam penggunaan proses elektrodialisis. Kata kunci: Membran pertukaran kation, polisulfona, resin pertukaran ion, ciri-ciri membran, elekrodialisis The objective of this work is to prepare an anion exchange membrane from polysulfone binder–ion exchange resin, which can be used in electrodialysis process. The cation exchange membranes were prepared by the solution casting method. The prepared anion exchange membranes are different from the conventional cation exchange membranes because its functional group is not derived from chlorosulfonic acid but from the absorption of anion exchange resins. The content of resins in each set of the prepared cation exchange membrane varied and were named as BERL–30, 40, 50, 60, and 70. In addition, the performance and behaviour of the prepared anion exchange membrane were evaluated and compared with the commercial cation exchange membranes. The physico-chemical properties of anion exchange membrane were determined by measuring the membrane thickness, permselectivity, and concentration of ion exchange capacity, chemical stability, water content, and scanning electron microscope (SEM). It was found that the increase in the quantity of resin (%) would increase the capacity of ion exchange, percentage of permselectivity, and capacity concentration of ion exchange group. The experimental results showed that cation exchange membrane has the potential to be used in electrodialysis process. Keywords: Cation exchange membrane, electrodialysis, polysulfone, ion exchange resin, membrane characterisation


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