Concentration of copper, zinc, lead and cadmium in plants cultivated in the surroundings of Żelazny Most copper ore tailings impoundment

Author(s):  
Agnieszka Medyńska-Juraszek ◽  
Cezary Kabała ◽  
Tadeusz Chodak ◽  
Paweł Jezierski
2009 ◽  
Vol 7 (4) ◽  
pp. 945-954 ◽  
Author(s):  
Nagwa Burham ◽  
Sami Azeem ◽  
Mohamed El-Shahat

AbstractA new solid — phase extraction sorbent was developed based on stepwise anchoring of two ligand molecules for the determination of copper, zinc, lead and cadmium in drinking water by flame AAS. Amberlite XAD-2 functionalized with 4′-(2-hydroxyphenylazo)-3′-methyl-1′-phenyl-2′-pyrazolin-5′-one (HPAPyr) was utilized for preconcentration/separation of these elements. The sorbent was prepared by two successive azo coupling reactions. First, 2-aminophenol was anchored to the amino groups in the resin resulted from nitration followed by reduction. Then, the resulted 2-aminophenol functionalized resin was further diazotized and coupled to the pyrazolone compound and the final product HPAPyr-XAD-2 was characterized by IR and elemental analysis. The optimum pH range for sorption, shaking time, exchange capacity, sample flow rate, preconcentration factor and interference from co-existing ions were investigated. All metal ions were quantitatively desorbed from the resin by 4.5 mol L−1 nitric acid solution. The sorbent provides limit of detection within the range 0.9–3.3 µg L−1 and concentration factor up to 250. The procedure was validated by analysis of certified material NIST-SRM 1577b. Application to drinking water showed satisfactory results with relative standard deviation RSD ≤ 8.5%.


2013 ◽  
Vol 78 (7) ◽  
pp. 933-945 ◽  
Author(s):  
Mirjana Bonic ◽  
Vele Tesevic ◽  
Ninoslav Nikicevic ◽  
Jelena Cvejic ◽  
Slobodan Milosavljevic ◽  
...  

Seven elements, namely, arsenic, lead, cadmium, copper, zinc, iron and manganese were determined in 31 samples of Serbian plum brandies by applying atomic spectrometry techniques. Flame atomic absorption spectrometry was used for quantification of copper, iron, zinc, manganese, lead and cadmium; and hydride generation atomic spectrometry absorption for arsenic quantification. Measured concentrations of heavy metals and arsenic was assessed according to the Serbian regulations, official regulations of some other countries and in respect of microelements content in other similar distilled alcoholic beverages. Amounts of microelements in maximal recommended daily and weekly intake of plum brandy were determined. The influence of production (home made and industrial), type of wooden barrel (oak and mulberry), and duration of ageing process on the content of Zn, Cu, Fe and Mn in plum brandies, as well as coefficient of correlation between Cu content and pH value were also studied.


2004 ◽  
Vol 21 (7) ◽  
pp. 649-657 ◽  
Author(s):  
G. Dugo * ◽  
L. La Pera ◽  
V. Lo Turco ◽  
D. Giuffrida ◽  
S. Restuccia

Author(s):  
A. Ilinskiy

Under the conditions of a lysimetric experiment on podzolic chernozem, it was found that the use of dolomite flour contributed to a decrease in the mobility of metals and their translocation into crop products, which was reflected in a decrease in their removal relative to the background. The use of mineral fertilizers by increasing the yield of phytomass contributed to an increase in the removal of copper, zinc, lead and cadmium from the soil. The largest total removal of copper, zinc, lead and cadmium with the phytomass of annual grasses (8,035 mg/m2) is observed when using a mineral fertilizer system, and the smallest removal of the indicated metals is observed when using lime without manure (5,092 mg/m2).


2020 ◽  
Vol 6 (2(71)) ◽  
pp. 9-12
Author(s):  
Andrey Ilinskiy

The results of a field lysimetric experiment on podzolized сhernozem to study the coefficients of biological absorption of heavy metals and trace elements for root crops and tops of fodder beets using various systems of mineral fertilizers are presented. Analysis of the empirical series of accumulation of elements in the main and byproducts of fodder beet plants showed that the level of accumulation of zinc, lead and cadmium in root crops is significantly lower than in the tops, and the copper content is relatively evenly distributed between the main and by-products according to the variants of the experiment. In the variant with an increased agrochemical background, there was a decrease in the content of copper, zinc and lead in the main and by-products of feed beets, which may be due to the effect of biological dilution when using mineral fertilizers.


Author(s):  
L. S. Ribnikova ◽  
P. A. Ribnikov

The hydrosphere of catchments, which are disturbed by mining, is formed under the influence of not only natural, but also, to a large extent, man-made factors over a long period, sometimes tens or even hundreds of years. After the cessation of production, the return of the mining territory to a state as close to natural as possible is possible, as world experience shows, in exceptional cases, provided that the process of reclamation and revitalization is planned at the design stage of mining. In old industrial areas, the selfhealing processes of the hydrosphere are of great importance, which determine the time during which the territory should be considered as an object of accumulated environmental damage. At present, the total removal of metal compounds by mine waters in the discharge zones at flooded copper-ore mines of the Sverdlovsk region amounts to hundreds (manganese, zinc) and even thousands of tons per year (iron). The duration of self-rehabilitation of the hydrosphere of mining areas at the post-operational stage, i.e. the duration of the period during which the content of the main polluting components (copper, zinc, iron, sulfate ion) is reduced to the maximum permissible or background values, is tens or even hundreds of years. During this time, in order to prevent pollution of the underground and surface hydrosphere, expensive measures are required to implement a system of purification of underground and surface waters of the old industrial territory. The research was carried out on the basis of observations of the chemical composition of water bodies in the territory of the abandoned Levikhinsky mine since the beginning of the 2000s.


Geoderma ◽  
2014 ◽  
Vol 230-231 ◽  
pp. 318-328 ◽  
Author(s):  
Joëlle Duplay ◽  
Khadija Semhi ◽  
Emna Errais ◽  
Gwenaël Imfeld ◽  
Izabella Babcsanyi ◽  
...  

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