As a model of unconventional fuels combustible mass composition and properties, averages of municipal solid waste (MSW), components of their morphological structure and their derivatives RDF, SRF Ukrainian origin and different world regions are selected. The reference data array: adiabatic equilibrium products state indicators of oxygen and steam-oxygen gasification of municipal solid waste components morphological composition, averages combustible mass of solid waste MSW, RDF, SRF for a given equilibrium parameters: T = 298.15 K, p = 0.1 MPa, depending on the ratio of «combustible mass : oxidant mass» is calculated. Coefficient a value for different by Qнр solid waste groups and other low grade fuels optimally gasification mode is determined. Bibl. 22, Fig. 3, Tab. 9.