Crystal Growth and Characterization of (Bi0.5Na0.5)TiO3–BaTiO3Single Crystals Obtained by a Top-Seeded Solution Growth Method under High-Pressure Oxygen Atmosphere

2011 ◽  
Vol 50 (9S2) ◽  
pp. 09NE07 ◽  
Author(s):  
Hiroaki Onozuka ◽  
Yuuki Kitanaka ◽  
Yuji Noguchi ◽  
Masaru Miyayama
2013 ◽  
Vol 566 ◽  
pp. 25-28
Author(s):  
Hiroaki Onozuka ◽  
Yuuki Kitanaka ◽  
Yuji Noguchi ◽  
Masaru Miyayama

A single crystal of ferroelectric 0.88(Bi,Na)TiO30.12BaTiO3 (BNTBT) solid solution with tetragonal P4mm structure was grown by the top-seeded solution growth (TSSG) method at a high oxygen pressure (PO2) of 0.9 MPa. The crystals grown by the high-PO2 TSSG method exhibited a large remanent polarization (Pr) of 54 μC/cm2, which leads to a spontaneous polarization of 54 μC/cm2. The large Pr compared with that of crystals grown at PO2 = 0.1 MPa is suggested to originate from a low oxygen vacancy concentration for the crystals grown at a higher PO2. The high-PO2 TSSG method was demonstrated to be effective for obtaining BNTBT crystals with superior polarization and piezoelectric properties.


CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4544-4551
Author(s):  
Zeng Luo ◽  
Jian Zhuang ◽  
Zenghui Liu ◽  
Nan Zhang ◽  
Wei Ren ◽  
...  

BiScO3–Pb(Cd1/3Nb2/3)O3–PbTiO3 single crystals with high quality have been successfully grown by the top-seeded solution growth method and the single ferroelastic domain structures and ferroelectric behaviors have also been reviewed.


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