Fluids as primary carriers of sulphur and copper in magmatic assimilation

Magmas readily react with their wall-rocks forming metamorphic contact aureoles. Sulphur and possibly metal mobilization within these contact aureoles is essential in the formation of economic magmatic sulphide deposits. We performed heating and partial melting experiments on a black shale sample from the Paleoproterozoic Virginia Formation, which is the main source of sulphur for the world-class Cu-Ni sulphide deposits of the 1.1 Ga Duluth Complex, Minnesota. These experiments show that an autochthonous devolatilization fluid effectively mobilizes carbon, sulphur, and copper in the black shale within subsolidus conditions (≤ 700 °C). Further mobilization occurs when the black shale melts and droplets of Cu-rich sulphide melt and pyrrhotite form at ∼1000 °C. The sulphide droplets attach to bubbles of devolatilization fluid, which promotes buoyancy-driven transportation in silicate melt. Our study shows that devolatilization fluids can supply large proportions of sulphur and copper in mafic–ultramafic layered intrusion-hosted Cu-Ni sulphide deposits.

Thermogenic carbon release from the Central Atlantic magmatic province caused major end-Triassic carbon cycle perturbations

The Central Atlantic magmatic province (CAMP), the end-Triassic mass extinction (ETE), and associated major carbon cycle perturbations occurred synchronously around the Triassic–Jurassic (T–J) boundary (201 Ma). Negative carbon isotope excursions (CIEs) recorded in marine and terrestrial sediments attest to the input of isotopically light carbon, although the carbon sources remain debated. Here, we explore the effects of mantle-derived and thermogenic carbon released from the emplacement of CAMP using the long-term ocean–atmosphere–sediment carbon cycle reservoir (LOSCAR) model. We have tested a detailed emission scenario grounded by numerous complementary boundary conditions, aiming to model the full extent of the carbon cycle perturbations around the T–J boundary. These include three negative CIEs (i.e., Marshi/Precursor, Spelae/Initial, Tilmanni/Main) with sharp positive CIEs in between. We show that a total of ∼24,000 Gt C (including ∼12,000 Gt thermogenic C) replicates the proxy data. These results indicate that thermogenic carbon generated from the contact aureoles around CAMP sills represents a credible source for the negative CIEs. An extremely isotopically depleted carbon source, such as marine methane clathrates, is therefore not required. Furthermore, we also find that significant organic carbon burial, in addition to silicate weathering, is necessary to account for the positive δ13C intervals following the negative CIEs.

U-Pb monazite ages of the Kabanga mafic-ultramafic intrusions and contact aureoles, central Africa: Geochronological and tectonic implications

Mafic-ultramafic rocks of the Kabanga-Musongati alignment in the East African nickel belt occur as Bushveld-type layered intrusions emplaced in metasedimentary sequences. The age of the mafic-ultramafic intrusions remains poorly constrained, though they are regarded to be part of ca. 1375 Ma bimodal magmatism dominated by voluminous S-type granites. In this study, we investigated igneous monazite and zircon from a differentiated layered intrusion and metamorphic monazite from the contact aureole. The monazite shows contrasting crystal morphology, chemical composition, and U-Pb ages. Monazite that formed by contact metamorphism in response to emplacement of mafic-ultramafic melts is characterized by extremely high Th and U and yielded a weighted mean 207Pb/206Pb age of 1402 ± 9 Ma, which is in agreement with dates from the igneous monazite and zircon. The ages indicate that the intrusion of ultramafic melts was substantially earlier (by ∼25 m.y., 95% confidence) than the prevailing S-type granites, calling for a reappraisal of the previously suggested model of coeval, bimodal magmatism. Monazite in the metapelitic rocks also records two younger growth events at ca. 1375 Ma and ca. 990 Ma, coeval with metamorphism during emplacement of S-type granites and tin-bearing granites, respectively. In conjunction with available geologic evidence, we propose that the Kabanga-Musongati mafic-ultramafic intrusions likely heralded a structurally controlled thermal anomaly related to Nuna breakup, which culminated during the ca. 1375 Ma Kibaran event, manifested as extensive intracrustal melting in the adjoining Karagwe-Ankole belt, producing voluminous S-type granites. The Grenvillian-aged (ca. 990 Ma) tin-bearing granite and related Sn mineralization appear to be the far-field record of tectonothermal events associated with collision along the Irumide belt during Rodinia assembly. Since monazite is a ubiquitous trace phase in pelitic sedimentary rocks, in contact aureoles of mafic-ultramafic intrusions, and in regional metamorphic belts, our study highlights the potential of using metamorphic monazite to determine ages of mafic-ultramafic intrusions, and to reconstruct postemplacement metamorphic history of the host terranes.

Spatially overlapping episodes of deformation, metamorphism, and magmatism in the southern Omineca Belt, southeastern British Columbia

The southeastern Omineca Belt of the Canadian Cordillera preserves a record of overlapping Barrovian and Buchan metamorphism spanning 180–50 Ma. This paper documents the timing, character, and spatial relationships that define separate domains of Middle Jurassic, Early Cretaceous, and Late Cretaceous deformation and metamorphism, and the nature of the geological interfaces that exist between them. A domain of Early Jurassic deformation (D1) and regional greenschist-facies metamorphism (M1) is cross-cut by Middle Jurassic (174–161 Ma) intrusions. Associated contact aureoles are divided into lower pressure (cordierite-dominated; ∼2.5–3.3 kbar; 1 kbar = 100 MPa) and higher pressure (staurolite-bearing; 3.5–4.2 kbar) subtypes; contact metamorphic kyanite occurs rarely in some staurolite-bearing aureoles. Jurassic structures are progressively overprinted northwards by Early Cretaceous deformation and metamorphism (D2M2), manifested in a tightening of Jurassic structures, development of more pervasive ductile fabrics, and Barrovian metamorphism. The D2M2 domain is the southerly continuation of the 600 km long Selkirk–Monashee–Cariboo metamorphic belt. Mid-Cretaceous intrusions (118–90 Ma) were emplaced throughout the D2M2 domain, the earliest of which contain D2 fabrics, but cut M2 isograds. The D2M2 domain makes a continuous, southeasterly transition into a domain of Late Cretaceous regional Barrovian metamorphism and deformation (D3M3; 94–76 Ma). The interface between these two domains is obscured by the coaxial nature of the deformation and the apparent continuity of the metamorphic zones, resulting in a complex and cryptic interface. Similarities between the D3M3 domain and the Selkirk Crest of Idaho and Washington suggest that this domain is the northerly continuation of the northward-plunging Priest River Complex.