Identification And Characterization Of Geoheritage Resources At Hulu Langat, Selangor

Identification and characterization of geodiversity for sites need more systematic approach for the purpose of conserving site with high geoheritage value. The present of igneous and metamorphic rock at Hulu Langat creates diversity in rock, features and geomorphological features includes hot spring, waterfall, hill and mountain that hold potential as a protected geosite of heritage value. Besides, the previous tin mining activities created by the contact metamorphism, left series of lakes and ponds while the nearby mountain is susceptible area as watershed that turn into dams around the area. Analysis on topographical maps, satellite image and aerial photograph interpretation aided in identification potential geosite based on geomorphological diversity. A total of 31 potential geosites with geological-scientific value have been identified in this study compare to 10 from the previous study. The potential geosite have been classified into rock diversity, natural landscape diversity and anthropogenic landscape diversity. Characterisation recognise 6 of these potential geosite are best example or tip location to illustrate the geological element, 4 of these geosites are the only occurrence of the geological element, 27 of the potential geosites are well preserved and 4 hold the scientific knowledge written in the international journal. The identification and characterisation of geoheritage resources are crucial steps before evaluation or assessment, ranking and conservation or development being propose, while strengthen the conservation geology approach.

Geology of Zagros metamorphosed volcaniclastic sandstones: a key for changing the Mawat Ophiolite Complex to a metamorphic core complex, Kurdistan Region, NE-Iraq

Mawat Ophiolite Complex is located about 36 km to the northeast of Sulaimani city and directly to the east-northeast of Mawat town near the border of Iran in the northeastern Iraq. The complex has about 600-km2 surface area and consists of high mountain terrains that subjected to intense geological investigations from the fiftieth of previous century till now. According to previous studies, the complex contains tens of igneous rocks such as basalt, metabasalt, tuff, diabase, metadiabase, diorite dykes, periodotite, serpentinite, serpentinite-matrix mélange, gabbro, metagabbro, harzbergite, pyroxenite, plagiogranite, pegmatite, granitiod rocks and dunite. They added occurrences of the volcanic and subvolcanic rocks in the form of dykes or basaltic flows. The present study tries to change the petrology and tectonics of whole complex from Ophiolite Complex to Metamorphic Core Complex. The revision includes refusal of all the above igneous rocks, instead they considered as medium grade regional metamorphism of different types of volcaniclastic sandstones (volcanic wackes), arenites and greywackes (impure sandstones) which sourced predominantly from remote volcanic source area inside Iran. The revision depended on several conjugate field and laboratory evidences inside the complex. These evidences such as absence of pillow basalt, volcanic flows, glass shards, volcanic cones, dykes, sills, contact metamorphism, dilatational structures and flow structures. Other evidences are presence of cross beddings, erosional surfaces, lensoidal channel fills, metamorphosed conglomerate, exposures of thousands of laminated planar beds and transition from fresh volcaniclastic sandstones to its medium grade metamorphosed counterparts, which previously considered as igneous rocks of ophiolite types. Another, evidence, in contrast to ophiolite section, the basalt location is at the base of the claimed ophiolite section while plutonic (dunite and peridotite) rocks located at its top. These locations of the two rocks contradict the definition of ophiolites. Accordingly, the present study changed the geological map of the whole Mawat area from igneous outcrops to metamorphosed volcaniclastic sandstones, arenites and greywackes that belong to Walash-Naoperdan Series. The parent rocks of the series transformed to different types of regionally metamorphosed rocks by deep burial during Eocene. During the burial, diageneses and metamorphisms enhanced by complex mixture of materials from different source areas and seawaters environments. Later, they uplifted, unroofed and exhumed during Pliocene as a core complex.

Marbles from Castagneto Carducci Area (Tuscany, Italy)

In this work, marbles from Castagneto Carducci (Livorno province, Tuscany), which originated by contact metamorphism of the Calcare Massiccio Fm., an Early Jurassic limestone belonging to the Tuscan Sequence, were studied for determining their chemical, mineralogical and petrographic characteristics, and the main physical and mechanical properties. Forty marble samples were sampled and analysed; they are from two inactive quarries on the NW and NE slopes of the Mt. Romitorino, and from natural outcrops in the vicinity of the quarries. The analysed rocks are marbles with high calcite content (> 98% by weight). Optical microscopy observations showed Castagneto Carducci marbles generally have a heteroblastic/granoblastic texture with crystal boundaries from curved-right to lobate. The maximum grain size of the calcite crystals ranges from 0.2 mm to 0.6 mm. The determination of the main physical and mechanical properties of the analysed marbles showed that these rocks are characterised by low porosity and, in general, good physical and mechanical properties.

Halogen Enrichment of Siberian Traps Magmas During Interaction With Evaporites

Volatile emissions to the atmosphere associated with the Siberian Traps eruptions at the Permian-Triassic boundary were sourced from the outgassing of primary magmas and the sedimentary host rocks into which they were intruded. Halogens in volcanic gases may have played an important role in environmental degradation and in stratospheric ozone destruction. Here we investigate how halogens behave during the interaction between salts and basalt magma emplaced as sills and erupted as lava. We present whole-rock, trace, and halogen concentrations for a suite of samples from three locations in the Siberian Traps Large Igneous Province, including basalt lavas erupted, and dolerites intruded into both organic-bearing shales and evaporites. Dolerites are enriched in Cl, Br, and I; their enrichment in Cl is similar to MORB and OIB that have been inferred to have assimilated seawater. The dolerites exhibit halogen compositional systematics, which extend towards both evaporites and crustal brines. Furthermore, all analyzed samples show enrichment in Rb/Nb; with the dolerites also showing enrichment in Cl/K similar to MORB and OIB that have been inferred to have assimilated seawater. We infer that samples from all three locations have assimilated fluids derived from evaporites, which are components of crustal sedimentary rocks. We show that up to 89% of the chlorine in the dolerites may have been assimilated as a consequence of the contact metamorphism of evaporites. We show, by thermal modeling, that halogen transfer may occur via assimilation of a brine phase derived from heating evaporites. Halogen assimilation from subcropping evaporites may be pervasive in the Siberian Traps Large Igneous Province and is expected to have enhanced emissions of Cl and Br into the atmosphere from both intrusive and extrusive magmatism.

A High-Pressure Thermal Aureole of the Bayan-Kol Gabbro–Monzodiorite Intrusion (Western Sangilen, Southeastern Tuva): Evidence for Lower-Crust Mafic Magma Chambers

—Thermal metamorphism produced an aureole near the early Paleozoic Bayan-Kol gabbro–monzodiorite intrusion in the Erzin shear zone of western Sangilen (Tuva–Mongolia microcontinent, Central Asian Orogenic Belt). Field observation of intrusive contact, structure–textural and mineral transformations of metamorphic rocks, regular changes in the chemical composition of minerals with approaching the intrusive contact, and high temperature gradient from intrusive to wallrocks verified the occurrence of a contact aureole near the Bayan-Kol intrusion. The high-gradient thermal metamorphism (M2) affected garnet–staurolite–kyanite schists that formed during earlier regional metamorphism (M1) at 6.2–7.9 kbar and 600–670 ºC. The 0.5 km wide M2 metamorphic aureole mapped along the northwestern intrusion margin consists of a muscovite–sillimanite zone adjacent to the sedimentary country rocks and a cordierite–K-feldspar zone on the side of the intrusion. The M2 metamorphic reactions occurred within the granulite facies temperature range 880–910 ºC along the contact with monzodiorites and at ~950 ºC along the boundary with gabbronorites; the temperature on the aureole periphery was about 640 ºC. Pressure estimates indicate deep-seated high-grade metamorphism at 6.9–7.8 kbar, while the intrusion itself crystallized at 7.7–7.8 kbar. The suggested numerical model implying the formation of a thermal aureole at a depth of 26 km (7 kbar) in the lower crust is consistent with the temperature pattern determined by geothermobarometry for several key points of the metamorphic zoning and confirms its deep-level origin. Thus, the aureole near the Bayan-Kol intrusion represents a rare case of contact metamorphism in the lower continental crust. The obtained results, along with published petrological and geochronological evidence, reveal two depth levels of the early Paleozoic M2 metamorphism in the Sangilen area: upper (7–15 km, 2–4 kbar) and lower (26–30 km, 7–8 kbar) crust. The Bayan-Kol gabbro–monzodiorite intrusion is likely a small apophysis or a fragment of a deep-crust intermediate magma chamber, while the moderate-pressure (7–8 kbar) M2 granulites in the Erzin shear zone are products of high-gradient metamorphism related to the Cambrian–Ordovician collisional mafic magmatism in the Sangilen area.

Sulphide Globules in a Porcellanite–Buchite Composite Xenolith from Stromboli Volcano (Aeolian Islands, Southern Italy): Products of Open-System Igneous Pyrometamorphism

Pyrometamorphism is the highest temperature end-member of the sanidinite facies (high-temperature, low-pressure contact metamorphism) and comprises both subsolidus and partial melting reactions which may locally lead to cryptocrystalline-glassy rocks (i.e., porcellanites and buchites). A wide range of pyrometamorphic ejecta, with different protoliths from Stromboli volcano, have been investigated over the last two decades. Among these, a heterogeneous (composite) glassy sample (B1) containing intimately mingled porcellanite and buchite lithotypes was selected to be studied through new FESEM–EDX and QEMSCAN™ mineral mapping investigations, coupled with the already available bulk rock composition data. This xenolith was chosen because of the unique and intriguing presence of abundant Cu–Fe sulphide globules within the buchite glass in contrast with the well-known general absence of sulphides in Stromboli basalts or their subvolcanic counterparts (dolerites) due to the oxygen fugacity of NNO + 0.5–NNO + 1 (or slightly lower) during magma crystallization. The investigated sample was ejected during the Stromboli paroxysm of 5 April 2003 when low porphyritic (LP) and high porphyritic (HP) basalts were erupted together. Both types of magmas are present as coatings of the porcellanite–buchite sample and were responsible for the last syn-eruptive xenoliths’s rim made of a thin crystalline-glassy selvage. The complex petrogenetic history of the B1 pyrometamorphic xenolith is tentatively explained in the framework of the shallow subvolcanic processes and vent system dynamics occurred shortly before (January–March 2003) the 5 April 2003 paroxysm. A multistep petrogenesis is proposed to account for the unique occurrence of sulphide globules in this composite pyrometamorphic xenolith. The initial stage is the pyrometamorphism of an already hydrothermally leached extrusive/subvolcanic vent system wall rock within the shallow volcano edifice. Successively, fragments of this wall rock were subject to further heating by continuous gas flux and interaction with Stromboli HP basalt at temperatures above 1000 °C to partially melt the xenolith. This is an open system process involving continuous exchange of volatile components between the gas flux and the evolving silicate melt. It is suggested that the reaction of plagioclase and ferromagnesian phenocrysts with SO2 and HCl from the volcanic gas during diffusion into the melt led to the formation of molecular CaCl in the melt, which then was released to the general gas flux. Sulphide formation is the consequence of the reaction of HCl dissolved into the melt from the gas phase, resulting in the release of H2 into the melt and lowering of fO2 driving reduction of the dissolved SO2.

Diagenetic Modifications and Reservoir Heterogeneity Associated with Magmatic Intrusions in the Devonian Khyber Limestone, Peshawar Basin, NW Pakistan

In the present study, an attempt has been made to establish the relationship between diagenetic alterations resulting from magmatic intrusions and their impact on the reservoir properties of the Devonian Khyber Limestone (NW Pakistan). Field observations, petrographic studies, mineralogical analyses, porosity-permeability data, and computed tomography were used to better understand the diagenetic history and petrophysical property evolution. Numerous dolerite intrusions are present in the studied carbonate successions, where the host limestone was altered to dolomite and marble, and fractures and faults developed due to the upwelling of the magmatic/hydrothermal fluids along pathways. Petrographic studies show an early phase of coarse crystalline saddle dolomite (Dol. I), which resulted from Mg-rich hydrothermal fluids originated from the dolerite dykes. Coarse crystalline marble formed due to contact metamorphism at the time of dolerite emplacement. The second phase of dolomitisation (Dol. II) postdates the igneous intrusions and was followed by dedolomitisation, dissolution, and cementation by meteoric calcite. Stable isotope studies likewise confirm two distinct dolomite phases. Dol. I exhibits more depleted δ18O (-15.8 to -9.1‰ V-PDB) and nondepleted δ13C (-2.05 to +1.85‰ V-PDB), whereas Dol. II shows a relatively narrow range of depleted δ18O (-13.9 to -13.8‰) signatures and nondepleted δ13C (+1.58 to +1.89‰ V-PDB). Dolomitic marble shows a marked depletion in δ18O and δ13C (-13.7 to -8.5‰ and -2.3 to 1.95‰, respectively). The initial phase of dolomitisation (Dol. I) did not alter porosity (5.4-6.6%) and permeability (0.0-0.1 mD) with respect to the unaltered limestone (5.6-6.9%; 0.1-0.2 mD). Contact metamorphism resulted in a decrease in porosity and permeability (3.3-4.7%; 0.1 mD). In contrast, an increase in porosity and permeability in Dol. II (7.7-10.5%; 0.8-2.5 mD) and dolomitic marble (6.6-14.7%; 8.2-13.3 mD) is linked to intercrystalline porosity and retainment of fracture porosity in dolomitic marble. Late-stage dissolution and dedolomitization also positively affected the reservoir properties of the studied successions. In conclusion, the aforementioned results reveal the impact of various diagenetic processes resulting from magmatic emplacement and their consequent reservoir heterogeneity.

Earth’s Nitrogen and Carbon Cycles

Understanding the Earth’s geological nitrogen (N) and carbon (C) cycles is fundamental for assessing the distribution of these volatiles between solid Earth (core, mantle and crust), oceans and atmosphere. This Special Communication about the Earth’s N and C cycles contains material that is relevant for researchers who are interested in the Topical Collection on planetary evolution “Reading Terrestrial Planet Evolution in Isotopes and Element Measurements”. Variations in the fluxes of N and C between these major reservoirs through geological time influenced the evolution and determined the unique composition of the Earth’s atmosphere. Here we review several key geological aspects of the N and C cycles of which our understanding has significantly advanced during the last decade through field-based, experimental and theoretical studies. Subduction zones are the most important pathway of both N and C from the Earth’s surface into the deep Earth. A key question in the flux quantification is how much of the volatile elements is stored in the downgoing slab and introduced into the mantle and how much is returned back to the surface and the atmosphere through arc magmatism. For N, the retention of N as $\text{NH}_{4}^{+}$ NH 4 + in minerals has a major influence on fluxes between reservoirs. The temperature-dependent stability of $\text{NH}_{4}^{+}$ NH 4 + -bearing minerals determines whether N is predominantly retained in the slab to mantle depths (in subduction zones with a low geothermal gradient) or devolatilized (in subduction zones with a high geothermal gradient). Several lines of evidence suggest that the mantle is regassing with respect to N due to a net influx of subducted N over time, but this issue is highly debated and evidence to the contrary also exists. Nevertheless, there is consensus that the majority of the planetary N budget is stored in the Earth’s mantle, with the continental crust also constituting a significant N reservoir. For C, release from the subducting slab occurs through decarbonation reactions, dissolution and formation of carbonatitic liquids, but reprecipitation of C in the slab or the forearc mantle wedge may limit the effectiveness of direct return of C into the atmosphere. Carbon release through regional metamorphism in collision zone orogens also has potentially profound effects on C release into the atmosphere and consensus has emerged that such orogens are sources rather than sinks of atmospheric CO2. On shorter timescales, contact metamorphism through interaction of mantle-derived magmas with C-bearing country rocks, and the resulting release of large quantities of CH4 and/or CO2, has been linked to global warming events.

Widespread hydrothermal vents and associated volcanism record prolonged Cenozoic magmatism in the South China Sea

The continental margin of the northern South China Sea is considered to be a magma-poor rifted margin. This work uses new seismic, bathymetric, gravity, and magnetic data to reveal how extensively magmatic processes have reshaped the latter continental margin. Widespread hydrothermal vent complexes and magmatic edifices such as volcanoes, igneous sills, lava flows, and associated domes are confirmed in the broader area of the northern South China Sea. Newly identified hydrothermal vents have crater- and mound-shaped surface expressions, and occur chiefly above igneous sills and volcanic edifices. Detailed stratigraphic analyses of volcanoes and hydrothermal vents suggest that magmatic activity took place in discrete phases between the early Miocene and the Quaternary. Importantly, the occurrence of hydrothermal vents close to the present seafloor, when accompanied by shallow igneous sills, suggest that fluid seepage is still active, well after main phases of volcanism previously documented in the literature. After combining geophysical and geochemical data, this study postulates that the extensive post-rift magmatism in the northern South China Sea is linked to the effect of a mantle plume over a long time interval. We propose that prolonged magmatism resulted in contact metamorphism in carbon-rich sediments, producing large amounts of hydrothermal fluid along the northern South China Sea. Similar processes are expected in parts of magma-poor margins in association with CO2/CH4 and heat flow release into sea water and underlying strata.