Coercive force of double layer ferromagnetic materials

Peculiarities of the coercive force (CF) measuring of inhomogeneous ferromagnetic materials, in particular layered ones, are considered. The concept of effective CF of layered ferromagnetic materials is introduced. The analysis of the magnetic fluxes distribution in a double layer ferro-magnetic material during its reversal magnetization by an attachable transducer with a U-shaped core made of soft magnetic material is carried out. An analytical expression of the effective CF for such class of materials for the case of the same layers’ thickness and linear approximation of their demagnetization curves is obtained. It was found that the effective CF of a double layer ferromagnetic material is determined not only by the CF of its individual layers, but also by the values of their residual induction. Experimental verification of the obtained results was performed on experimental samples, which were collected from steel 08kp (sample # 1) and steel St3 (sample # 2) plates. Each of the samples was a stack of 6 plates each measuring 87×50×1 mm. With tight compression of the plates and complete elimination of the gaps between them, these samples can be considered as single layer ferromagnetic structures with a thickness of 6 mm. To model a double layer ferromagnetic material with the same layer thickness, sample № 3 was used. Its the upper part consisted of the three steel 08kp plates and the lower part – of the three steel St3 plates. To measure the magnetic parameters of these samples the KRM-Ts-MA type magnetic analyzer was used. The device permit to measure the CF, residual induction and other parameters of the hysteresis loops of ferromagnetic materials in the closed magnetic circuit by attachable type transducers with U-shaped core. The transducer used with the magnetic analyzer during the experiments had poles with an area of 16×32 mm and the distance between the edges of the poles: inner – 32 mm, outer – 64 mm. It is shown that the discrepancy between the calculated value of the effective CF of the double layer ferromagnetic material (sample # 3) from steel 08kp and St3 according to the obtained expression and the measurement results is about 3%. This confirms the adequacy of the proposed model of reversal magnetization of double layer ferromagnetic material and the correctness of analytical calculations.

Selective laser sintering of bonded anisotropic permanent magnets using an in situ alignment fixture

Purpose Additive manufacturing (AM) techniques have been developed to rapidly produce custom designs from a multitude of materials. Bonded permanent magnets (PMs) have been produced via several AM techniques to allow for rapid manufacture of complex geometries. These magnets, however, tend to suffer from lower residual induction than the industry standard of injection moulding primarily due to the lower packing density of the magnetic particles and secondly due to the feedstock consisting of neodymium-iron-boron (Nd-Fe-B) powder with isotropic magnetic properties. As there is no compaction during most AM processes, increasing the packing density is very difficult and therefore the purpose of this study was to increase the magnetic properties of the PMs without increasing the part density. Design/methodology/approach Accordingly, this research investigates the use of anisotropic NdFeB feedstock coupled with an in-situ alignment fixture into an AM process known as selective laser sintering (SLS) to increase the magnetic properties of AM magnets. A Helmholtz coil array was added to an SLS machine and used to expose each powder layer during part fabrication to a near-uniform magnetic field of 20.4 mT prior to consolidation by the laser. Findings Permeagraph measurements of the parts showed that the alignment field introduced residual induction anisotropy of up to 46.4 ± 2.2% when measured in directions parallel and perpendicular to the alignment field. X-ray diffraction measurements also demonstrated a convergence of the orientation of the crystals when the magnets were processed in the presence of the alignment field. Originality/value A novel active alignment fixture for SLS was introduced and was experimentally shown to induce anisotropy in bonded PMs. Thus demonstrating a new method for the enhancement in energy density of PMs produced via AM methods.

Synthesis and properties of na nomagnetite for the preparation of biocomposites

Magnetite powder (FeO·Fe2O3 or Fe3O4) is obtained by the chemical precipitation method, using FeCl3·6H2O and FeCl2·4H2O as a starting materials in the presence of hydrazine N2H4 at a temperature of 80 °C. X-ray diffraction analysis, infrared spectroscopy, and scanning electron microscopy are used for the study of the phase composition and morphology of the synthesized powder. Its specific surface area and magnetic properties such as, in particular, the specific saturation magnetization, coercive force and residual induction are investigated. It is established that the composition of the synthesized powder is represented by magnetite as the main phase with a small admixture of hematite. It is shown that the particles of the obtained magnetite have sizes of 33-84 nm and tend to the agglomeration. The prepared powder has superparamagnetic properties (specific magnetization — 35 A · m2/kg, coercive force — 0.24 kA/m, residual induction — 0.009 T) and is promising for the biocomposite creation.

Electro-discharge sintering of nanocrystalline NdFeB magnets: process parameters, microstructure, and the resulting magnetic properties

This study investigates the compaction of nanocrystalline NdFeB magnet powder by electro-discharge sintering (EDS). On this account, process parameters, microstructure, and the associated magnetic properties of the EDS-densified nanocrystalline NdFeB specimens were investigated by varying the discharge energy EEDS and compression load pEDS. Although optimized process parameters could be evaluated, three different microstructures (fully densified zone, insufficiently densified zone, and melted zone) are present in the EDS-compacted specimens. Thereby, volume fractions of these formed three different microstructures determine the resulting mechanical and magnetic properties of the specimens. For all specimens, the intrinsic coercivity Hc,J deteriorates with increasing discharge energy, as the generated Joule heat leads to microstructural changes (grain growth, dissolution of magnetic phases), which reduces the magnetic properties. The compression load has less influence on the coercivity Hc,J, as it only affects the initial resistance of the pre-compacted powder loose. The residual induction Br deteriorates with increasing the discharge energy due to microstructural changes. An increase in the compression load pEDS results in an increase in the specimens’ density and thus promotes the residual induction Br.

Влияние отжига в постоянном магнитном поле на магнитные свойства сплавов железо--галлий

The concentration dependence of the magnetic properties of iron alloys with 3 – 25 at.% gallium has been studied. It is shown that with increasing gallium content, saturation induction decreases monotonically, but coercive force shows a stepped increase with a jump from 85 to 135 A/m between 12 and 15 at.% Ga. The effect of annealing in a dc magnetic field (magnetic field annealing (MFA)) on the behavior of residual induction and coercive force in samples containing from 3 to 18 at.% of gallium was investigated. After the MFA, in the alloy a magnetic anisotropy is induced: magnetic hysteresis loops become narrower, the residual induction increases and the coercive force decreases. The MFA efficiency reaches a maximum when the gallium content is at 15 – 18 at.%. The features of the structural state in iron-gallium alloys and their role in the formation of the magnetic properties during annealing in the dc magnetic field are discussed.

Multiparameter method of surface hardening quality testing

Measurements of the magnetic characteristics (coercive force, residual induction, induction of saturation) of objects that had different thicknesses of the hardened layer were made. The influence of an unstressed core on the measurement results, as well as the depth of the strengthened layer on the shape of the hysteresis loop, is investigated. The conclusion is made that it is possible to estimate the properties of a hardened layer by means of a single measurement with the help of the hardware-software system DIUS-1.15M